New phospholipid fatty acids from the marine sponge Cinachyrella alloclada uliczka
The fatty acid composition of phospholipids from the Senegalese sponge Cinachyrella alloclada was examined. Two new fatty acids not hitherto found in nature, namely 10,13‐octadecadienoic acid and 16‐tricosenoic acid, were identified. 8‐Hexadecenoic, 13‐nonadecenoic and 5,9,13‐trimethyltretradecanoic...
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| Veröffentlicht in: | Lipids 1992-10, Vol.27 (10), p.779-784 |
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| creator | BARNATHAN, G MIRALLES, J GAYDOU, E. M BOURY-ESNAULT, N KORNPROBST, J.-M |
| description | The fatty acid composition of phospholipids from the Senegalese sponge
Cinachyrella alloclada
was examined. Two new fatty acids not hitherto found in nature, namely 10,13‐octadecadienoic acid and 16‐tricosenoic acid, were identified. 8‐Hexadecenoic, 13‐nonadecenoic and 5,9,13‐trimethyltretradecanoic fatty acids were also found for the first time in sponges. The latter compound (1.4% of the total fatty acid mixture), an isoprenoid fatty acid, accompanies the major fatty acid 4,8,12‐trimethyltridecanoic acid (19.7%). The monomethyl branched fatty acids (22%) identified include 23‐methylpentacosanoic acid (anteiso‐26∶0), not previously observed in sponged. The major long‐chain fatty acids encountered were the known 17‐tetracosenoic 19‐heptacosadienoic and 5,9,23‐tricontatrienoic acid. Some sixty fatty acids were identified as methyl esters and
N
‐acyl pyrrolidides by gas chromatography and gas chromatography/mass spectrometry. |
| doi_str_mv | 10.1007/BF02535849 |
| format | Article |
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Cinachyrella alloclada
was examined. Two new fatty acids not hitherto found in nature, namely 10,13‐octadecadienoic acid and 16‐tricosenoic acid, were identified. 8‐Hexadecenoic, 13‐nonadecenoic and 5,9,13‐trimethyltretradecanoic fatty acids were also found for the first time in sponges. The latter compound (1.4% of the total fatty acid mixture), an isoprenoid fatty acid, accompanies the major fatty acid 4,8,12‐trimethyltridecanoic acid (19.7%). The monomethyl branched fatty acids (22%) identified include 23‐methylpentacosanoic acid (anteiso‐26∶0), not previously observed in sponged. The major long‐chain fatty acids encountered were the known 17‐tetracosenoic 19‐heptacosadienoic and 5,9,23‐tricontatrienoic acid. Some sixty fatty acids were identified as methyl esters and
N
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Cinachyrella alloclada
was examined. Two new fatty acids not hitherto found in nature, namely 10,13‐octadecadienoic acid and 16‐tricosenoic acid, were identified. 8‐Hexadecenoic, 13‐nonadecenoic and 5,9,13‐trimethyltretradecanoic fatty acids were also found for the first time in sponges. The latter compound (1.4% of the total fatty acid mixture), an isoprenoid fatty acid, accompanies the major fatty acid 4,8,12‐trimethyltridecanoic acid (19.7%). The monomethyl branched fatty acids (22%) identified include 23‐methylpentacosanoic acid (anteiso‐26∶0), not previously observed in sponged. The major long‐chain fatty acids encountered were the known 17‐tetracosenoic 19‐heptacosadienoic and 5,9,23‐tricontatrienoic acid. Some sixty fatty acids were identified as methyl esters and
N
‐acyl pyrrolidides by gas chromatography and gas chromatography/mass spectrometry.</description><subject>Analytical, structural and metabolic biochemistry</subject><subject>Biological and medical sciences</subject><subject>Fatty acids</subject><subject>Fundamental and applied biological sciences. Psychology</subject><subject>Lipids</subject><subject>Other biological molecules</subject><issn>0024-4201</issn><issn>1558-9307</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1992</creationdate><recordtype>article</recordtype><recordid>eNpFUEtLxDAYDKLgunrxF-TgSajm2SZHXVwVFgXRc_mah41m25JUpP56Kyt6GIaBmWEYhE4puaCEVJfXa8Ikl0roPbSgUqpCc1LtowUhTBSCEXqIjnJ-myUVWi7Q04P7xEPb5xkxDMFiD-M4YTDBZuxTv8Vj6_AWUugczkPfvTq8Ch2YdkouRsAQY28iWMAfMZivdzhGBx5idie_vEQv65vn1V2xeby9X11tCsOkGgtvrG2YV4414GRjAErCta5E1VjduIp4pZUiWoKXgkFJObUWeCm1B2uY4Ut0vus1qc85OV8PKcxDp5qS-ueN-v-N2Xy2Mw-QDUSfoDMh_yWEkIxLwr8BoKVgJA</recordid><startdate>19921001</startdate><enddate>19921001</enddate><creator>BARNATHAN, G</creator><creator>MIRALLES, J</creator><creator>GAYDOU, E. M</creator><creator>BOURY-ESNAULT, N</creator><creator>KORNPROBST, J.-M</creator><general>Springer</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19921001</creationdate><title>New phospholipid fatty acids from the marine sponge Cinachyrella alloclada uliczka</title><author>BARNATHAN, G ; MIRALLES, J ; GAYDOU, E. M ; BOURY-ESNAULT, N ; KORNPROBST, J.-M</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c258t-fcddb2f8e2bae5bcaa60399747bd9be70f8988095af542a6131dda3659fadc2c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1992</creationdate><topic>Analytical, structural and metabolic biochemistry</topic><topic>Biological and medical sciences</topic><topic>Fatty acids</topic><topic>Fundamental and applied biological sciences. Psychology</topic><topic>Lipids</topic><topic>Other biological molecules</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>BARNATHAN, G</creatorcontrib><creatorcontrib>MIRALLES, J</creatorcontrib><creatorcontrib>GAYDOU, E. M</creatorcontrib><creatorcontrib>BOURY-ESNAULT, N</creatorcontrib><creatorcontrib>KORNPROBST, J.-M</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Lipids</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>BARNATHAN, G</au><au>MIRALLES, J</au><au>GAYDOU, E. M</au><au>BOURY-ESNAULT, N</au><au>KORNPROBST, J.-M</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>New phospholipid fatty acids from the marine sponge Cinachyrella alloclada uliczka</atitle><jtitle>Lipids</jtitle><date>1992-10-01</date><risdate>1992</risdate><volume>27</volume><issue>10</issue><spage>779</spage><epage>784</epage><pages>779-784</pages><issn>0024-4201</issn><eissn>1558-9307</eissn><coden>LPDSAP</coden><abstract>The fatty acid composition of phospholipids from the Senegalese sponge
Cinachyrella alloclada
was examined. Two new fatty acids not hitherto found in nature, namely 10,13‐octadecadienoic acid and 16‐tricosenoic acid, were identified. 8‐Hexadecenoic, 13‐nonadecenoic and 5,9,13‐trimethyltretradecanoic fatty acids were also found for the first time in sponges. The latter compound (1.4% of the total fatty acid mixture), an isoprenoid fatty acid, accompanies the major fatty acid 4,8,12‐trimethyltridecanoic acid (19.7%). The monomethyl branched fatty acids (22%) identified include 23‐methylpentacosanoic acid (anteiso‐26∶0), not previously observed in sponged. The major long‐chain fatty acids encountered were the known 17‐tetracosenoic 19‐heptacosadienoic and 5,9,23‐tricontatrienoic acid. Some sixty fatty acids were identified as methyl esters and
N
‐acyl pyrrolidides by gas chromatography and gas chromatography/mass spectrometry.</abstract><cop>Heidelberg</cop><pub>Springer</pub><doi>10.1007/BF02535849</doi><tpages>6</tpages></addata></record> |
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| language | eng |
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| source | SpringerLink (Online service) |
| subjects | Analytical, structural and metabolic biochemistry Biological and medical sciences Fatty acids Fundamental and applied biological sciences. Psychology Lipids Other biological molecules |
| title | New phospholipid fatty acids from the marine sponge Cinachyrella alloclada uliczka |
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