Interaction of sodium with sodium hydroxide due to interloop leakage in a steam generator

The authors construct a model depicting the process by which chemical equilibrium is reached in the heterogeneous system formed by sodium and sodium hydroxide under accident conditions in a sodium-water steam generator. The results of the calculations demonstrate the following conclusions: that the...

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Veröffentlicht in:Sov. At. Energy (Engl. Transl.); (United States) 1987-01, Vol.62 (1), p.5-10
Hauptverfasser: Bocharin, P. P., Sroelov, V. S., Privalov, Yu. V.
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container_issue 1
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container_title Sov. At. Energy (Engl. Transl.); (United States)
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creator Bocharin, P. P.
Sroelov, V. S.
Privalov, Yu. V.
description The authors construct a model depicting the process by which chemical equilibrium is reached in the heterogeneous system formed by sodium and sodium hydroxide under accident conditions in a sodium-water steam generator. The results of the calculations demonstrate the following conclusions: that the rate of the homogeneous reaction of sodium and sodium hydroxide has an insignificant effect on the concentration of the components in sodium so that in evaluating the effectiveness of emergency detection the equilibrium values of the concentration of sodium oxide and sodium hydride must be used; and the solidification of the drops occurs at a temperature higher than the melting point of pure sodium hydroxide at 30 degrees K. Solid drops can therefore settle on the surface of the steam generator.
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Transl.); (United States)</jtitle><date>1987-01-01</date><risdate>1987</risdate><volume>62</volume><issue>1</issue><spage>5</spage><epage>10</epage><pages>5-10</pages><issn>0038-531X</issn><eissn>1573-8205</eissn><abstract>The authors construct a model depicting the process by which chemical equilibrium is reached in the heterogeneous system formed by sodium and sodium hydroxide under accident conditions in a sodium-water steam generator. The results of the calculations demonstrate the following conclusions: that the rate of the homogeneous reaction of sodium and sodium hydroxide has an insignificant effect on the concentration of the components in sodium so that in evaluating the effectiveness of emergency detection the equilibrium values of the concentration of sodium oxide and sodium hydride must be used; and the solidification of the drops occurs at a temperature higher than the melting point of pure sodium hydroxide at 30 degrees K. Solid drops can therefore settle on the surface of the steam generator.</abstract><cop>United States</cop><doi>10.1007/BF01127406</doi><tpages>6</tpages></addata></record>
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1573-8205
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subjects 210300 - Power Reactors, Nonbreeding, Graphite Moderated
220900 - Nuclear Reactor Technology- Reactor Safety
ACCIDENTS
ALKALI METAL COMPOUNDS
ALKALI METALS
BOILERS
CHALCOGENIDES
CHEMICAL REACTION KINETICS
DETECTION
DIAGRAMS
DISSOLUTION
DROPLETS
ELEMENTS
EQUATIONS
EQUILIBRIUM
FLUID MECHANICS
FLUID-STRUCTURE INTERACTIONS
GENERAL STUDIES OF NUCLEAR REACTORS
HYDRAULICS
HYDROGEN
HYDROGEN COMPOUNDS
HYDROXIDES
KINETIC EQUATIONS
KINETICS
LEAKS
LIQUID METAL COOLED REACTORS
LOSS OF COOLANT
MATHEMATICAL MODELS
MECHANICS
METALS
NONMETALS
OXIDES
OXYGEN COMPOUNDS
PARTICLES
PHASE DIAGRAMS
REACTION KINETICS
REACTOR ACCIDENTS
REACTORS
SODIUM
SODIUM COMPOUNDS
SODIUM COOLED REACTORS
SODIUM HYDROXIDES
SODIUM OXIDES
SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS
STEAM GENERATORS
VAPOR GENERATORS
WATER
title Interaction of sodium with sodium hydroxide due to interloop leakage in a steam generator
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