Degenerate rearrangements of 1H- and L-CHLORO-(1,2),(3,4),(5,6)-tripropanobenzenonium carbocations: Unexpected differences in the behavior of the migrants
The authors attempt to clarify whether the free energy values of the degenerate 1,2-shifts of the same migrants in the beta-type ions of arenonium containing a cyclic polymethylene fragment of C /SUB alpha/ and C /SUB beta/ satisfy the activation free energies of degenerate 1,2 hydrogen and chlorine...
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| Veröffentlicht in: | Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Div. Chem. Sci. (Engl. Transl.); (United States), 1986-03, Vol.35 (3), p.637-639 |
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| container_title | Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) |
| container_volume | 35 |
| creator | Loktev, V. F. Shakirov, M. M. Shubin, V. G. |
| description | The authors attempt to clarify whether the free energy values of the degenerate 1,2-shifts of the same migrants in the beta-type ions of arenonium containing a cyclic polymethylene fragment of C /SUB alpha/ and C /SUB beta/ satisfy the activation free energies of degenerate 1,2 hydrogen and chlorine atom shifts in the ions to the chemical shift of the carbonium center in the C 13 NMR spectra. For this purpose the authors studied the rearrangement of 1-R-(1,2), (3,4), (5,6)-tripropanobenzenonium cations. |
| doi_str_mv | 10.1007/BF00953247 |
| format | Article |
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F. ; Shakirov, M. M. ; Shubin, V. G.</creator><creatorcontrib>Loktev, V. F. ; Shakirov, M. M. ; Shubin, V. G. ; Institute of Organic Chemistry, Acad. of Sci., Novosibisk</creatorcontrib><description>The authors attempt to clarify whether the free energy values of the degenerate 1,2-shifts of the same migrants in the beta-type ions of arenonium containing a cyclic polymethylene fragment of C /SUB alpha/ and C /SUB beta/ satisfy the activation free energies of degenerate 1,2 hydrogen and chlorine atom shifts in the ions to the chemical shift of the carbonium center in the C 13 NMR spectra. 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G.</creatorcontrib><creatorcontrib>Institute of Organic Chemistry, Acad. of Sci., Novosibisk</creatorcontrib><title>Degenerate rearrangements of 1H- and L-CHLORO-(1,2),(3,4),(5,6)-tripropanobenzenonium carbocations: Unexpected differences in the behavior of the migrants</title><title>Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)</title><description>The authors attempt to clarify whether the free energy values of the degenerate 1,2-shifts of the same migrants in the beta-type ions of arenonium containing a cyclic polymethylene fragment of C /SUB alpha/ and C /SUB beta/ satisfy the activation free energies of degenerate 1,2 hydrogen and chlorine atom shifts in the ions to the chemical shift of the carbonium center in the C 13 NMR spectra. 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F.</creatorcontrib><creatorcontrib>Shakirov, M. M.</creatorcontrib><creatorcontrib>Shubin, V. G.</creatorcontrib><creatorcontrib>Institute of Organic Chemistry, Acad. of Sci., Novosibisk</creatorcontrib><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Loktev, V. F.</au><au>Shakirov, M. M.</au><au>Shubin, V. G.</au><aucorp>Institute of Organic Chemistry, Acad. of Sci., Novosibisk</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Degenerate rearrangements of 1H- and L-CHLORO-(1,2),(3,4),(5,6)-tripropanobenzenonium carbocations: Unexpected differences in the behavior of the migrants</atitle><jtitle>Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)</jtitle><date>1986-03</date><risdate>1986</risdate><volume>35</volume><issue>3</issue><spage>637</spage><epage>639</epage><pages>637-639</pages><issn>0568-5230</issn><eissn>1573-9171</eissn><abstract>The authors attempt to clarify whether the free energy values of the degenerate 1,2-shifts of the same migrants in the beta-type ions of arenonium containing a cyclic polymethylene fragment of C /SUB alpha/ and C /SUB beta/ satisfy the activation free energies of degenerate 1,2 hydrogen and chlorine atom shifts in the ions to the chemical shift of the carbonium center in the C 13 NMR spectra. For this purpose the authors studied the rearrangement of 1-R-(1,2), (3,4), (5,6)-tripropanobenzenonium cations.</abstract><cop>United States</cop><doi>10.1007/BF00953247</doi><tpages>3</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0568-5230 |
| ispartof | Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), 1986-03, Vol.35 (3), p.637-639 |
| issn | 0568-5230 1573-9171 |
| language | eng |
| recordid | cdi_crossref_primary_10_1007_BF00953247 |
| source | SpringerLink Journals - AutoHoldings |
| subjects | 400201 - Chemical & Physicochemical Properties ACTIVATION ENERGY CARBON 13 CARBON COMPOUNDS CARBON ISOTOPES CARBONIUM COMPOUNDS CATIONS CHARGED PARTICLES CHEMICAL SHIFT CHLORINE CHLORINE COMPOUNDS ELEMENTS ENERGY EVEN-ODD NUCLEI HALOGEN COMPOUNDS HALOGENS HYDROGEN HYPERFINE STRUCTURE INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY IONS ISOTOPES LIGHT NUCLEI LOW TEMPERATURE NMR SPECTRA NONMETALS NUCLEI SPECTRA STABLE ISOTOPES TEMPERATURE EFFECTS |
| title | Degenerate rearrangements of 1H- and L-CHLORO-(1,2),(3,4),(5,6)-tripropanobenzenonium carbocations: Unexpected differences in the behavior of the migrants |
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