Photochemical reaction of phosphine hydride complexes of molybdenum and tungsten with molecular nitrogen

Nitrogen complexes of molybdenum and tungsten react (rapidly when illuminated but slowly in the dark) with halogen-containing organic compounds to form products containing N-C bonds. Phosphine hydride complexes of type MH/sub 4/L/sub 4/ (M = Mo, W; L = PMePh/sub 2/, PEtPh/sub 2/, PEt/sub 2/Ph, PPrPh...

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Veröffentlicht in:	Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Div. Chem. Sci. (Engl. Transl.); (United States), 1981-06, Vol.30 (6), p.947-952
Hauptverfasser:	Pivovarov, A. P., Gak, Yu. V., Doronina, T. N., Makhaev, V. D., Borisov, A. P., Borod'ko, Yu. G.
Format:	Artikel
Sprache:	eng
Schlagworte:	400201 - Chemical & Physicochemical Properties 400500 - Photochemistry CHEMICAL ANALYSIS CHEMICAL REACTION KINETICS CHEMICAL REACTION YIELD CHEMICAL REACTIONS COMPLEXES DATA ELEMENTS EXPERIMENTAL DATA HYDRAZINE HYDRIDES HYDROGEN COMPOUNDS INFORMATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY KINETICS MOLYBDENUM COMPLEXES NITROGEN NITROGEN COMPLEXES NITROGEN COMPOUNDS NONMETALS NUMERICAL DATA ORGANIC COMPOUNDS ORGANIC HALOGEN COMPOUNDS PHOSPHINES PHOSPHORUS COMPOUNDS PHOTOCHEMICAL REACTIONS QUANTITATIVE CHEMICAL ANALYSIS REACTION KINETICS SPECTRA TRANSITION ELEMENT COMPLEXES TUNGSTEN COMPLEXES YIELDS
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