Influence of temperature on the spectral-luminescent properties of rhodamine-dye solutions
This paper presents the results of studies of the influence of temperature on the spectral-luminescent characteristics of dilute solutions of 14 rhodamine dyes (unsubstituted rhodamine and its derivatives). The influence of temperature on the position and form of the absorption and flourescence spec...
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| Veröffentlicht in: | J. Appl. Spectrosc. (Engl. Transl.); (United States) 1985-01, Vol.42 (1), p.49-53 |
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| container_title | J. Appl. Spectrosc. (Engl. Transl.); (United States) |
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| creator | Yuzhakov, V. I. |
| description | This paper presents the results of studies of the influence of temperature on the spectral-luminescent characteristics of dilute solutions of 14 rhodamine dyes (unsubstituted rhodamine and its derivatives). The influence of temperature on the position and form of the absorption and flourescence spectra and on the absorptive power and luminescence yield of these solutions was investigated. The solvent used was ethanol, which vitrifies on freezing. To eliminate the influence of dye-molecule association on the optical characteristics measured, solutions of low concentration were used. The absorption and luminescence spectra at low temperature were studied using special cryostats. The temperature varied from 20 to -196C. The investigations show that even a slight change in molecular structure may lead to pronounced changes in the temperature dependences of their spectralluminescent properties. |
| doi_str_mv | 10.1007/BF00661111 |
| format | Article |
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The investigations show that even a slight change in molecular structure may lead to pronounced changes in the temperature dependences of their spectralluminescent properties.</description><identifier>ISSN: 0021-9037</identifier><identifier>EISSN: 1573-8647</identifier><identifier>DOI: 10.1007/BF00661111</identifier><language>eng</language><publisher>United States</publisher><subject>420300 - Engineering- Lasers- (-1989) ; ABSORPTION SPECTRA ; ALCOHOLS ; AMINES ; CARBOXYLIC ACIDS ; DILUTION ; DYES ; EMISSION SPECTROSCOPY ; ENGINEERING ; ETHANOL ; FLUORESCENCE ; FLUORESCENCE SPECTROSCOPY ; FREEZING ; HETEROCYCLIC ACIDS ; HETEROCYCLIC COMPOUNDS ; HYDROXY COMPOUNDS ; LOW TEMPERATURE ; LUMINESCENCE ; MEDIUM TEMPERATURE ; MOLECULAR STRUCTURE ; OPTICAL PROPERTIES ; ORGANIC ACIDS ; ORGANIC COMPOUNDS ; ORGANIC OXYGEN COMPOUNDS ; PHYSICAL PROPERTIES ; REAGENTS ; RHODAMINES ; SPECTRA ; SPECTROSCOPY ; STRUCTURAL CHEMICAL ANALYSIS ; TEMPERATURE EFFECTS ; VITRIFICATION</subject><ispartof>J. Appl. 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Transl.); (United States)</title><description>This paper presents the results of studies of the influence of temperature on the spectral-luminescent characteristics of dilute solutions of 14 rhodamine dyes (unsubstituted rhodamine and its derivatives). The influence of temperature on the position and form of the absorption and flourescence spectra and on the absorptive power and luminescence yield of these solutions was investigated. The solvent used was ethanol, which vitrifies on freezing. To eliminate the influence of dye-molecule association on the optical characteristics measured, solutions of low concentration were used. The absorption and luminescence spectra at low temperature were studied using special cryostats. The temperature varied from 20 to -196C. 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I.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c130t-d48a55c1dcf6362856875d7e0b574dfdf54ff2c83ba8030cbff51416afdca9973</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1985</creationdate><topic>420300 - Engineering- Lasers- (-1989)</topic><topic>ABSORPTION SPECTRA</topic><topic>ALCOHOLS</topic><topic>AMINES</topic><topic>CARBOXYLIC ACIDS</topic><topic>DILUTION</topic><topic>DYES</topic><topic>EMISSION SPECTROSCOPY</topic><topic>ENGINEERING</topic><topic>ETHANOL</topic><topic>FLUORESCENCE</topic><topic>FLUORESCENCE SPECTROSCOPY</topic><topic>FREEZING</topic><topic>HETEROCYCLIC ACIDS</topic><topic>HETEROCYCLIC COMPOUNDS</topic><topic>HYDROXY COMPOUNDS</topic><topic>LOW TEMPERATURE</topic><topic>LUMINESCENCE</topic><topic>MEDIUM TEMPERATURE</topic><topic>MOLECULAR STRUCTURE</topic><topic>OPTICAL PROPERTIES</topic><topic>ORGANIC ACIDS</topic><topic>ORGANIC COMPOUNDS</topic><topic>ORGANIC OXYGEN COMPOUNDS</topic><topic>PHYSICAL PROPERTIES</topic><topic>REAGENTS</topic><topic>RHODAMINES</topic><topic>SPECTRA</topic><topic>SPECTROSCOPY</topic><topic>STRUCTURAL CHEMICAL ANALYSIS</topic><topic>TEMPERATURE EFFECTS</topic><topic>VITRIFICATION</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yuzhakov, V. I.</creatorcontrib><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>J. Appl. Spectrosc. (Engl. Transl.); (United States)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yuzhakov, V. I.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Influence of temperature on the spectral-luminescent properties of rhodamine-dye solutions</atitle><jtitle>J. Appl. Spectrosc. (Engl. Transl.); (United States)</jtitle><date>1985-01</date><risdate>1985</risdate><volume>42</volume><issue>1</issue><spage>49</spage><epage>53</epage><pages>49-53</pages><issn>0021-9037</issn><eissn>1573-8647</eissn><abstract>This paper presents the results of studies of the influence of temperature on the spectral-luminescent characteristics of dilute solutions of 14 rhodamine dyes (unsubstituted rhodamine and its derivatives). The influence of temperature on the position and form of the absorption and flourescence spectra and on the absorptive power and luminescence yield of these solutions was investigated. The solvent used was ethanol, which vitrifies on freezing. To eliminate the influence of dye-molecule association on the optical characteristics measured, solutions of low concentration were used. The absorption and luminescence spectra at low temperature were studied using special cryostats. The temperature varied from 20 to -196C. The investigations show that even a slight change in molecular structure may lead to pronounced changes in the temperature dependences of their spectralluminescent properties.</abstract><cop>United States</cop><doi>10.1007/BF00661111</doi><tpages>5</tpages></addata></record> |
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| ispartof | J. Appl. Spectrosc. (Engl. Transl.); (United States), 1985-01, Vol.42 (1), p.49-53 |
| issn | 0021-9037 1573-8647 |
| language | eng |
| recordid | cdi_crossref_primary_10_1007_BF00661111 |
| source | SpringerLink Journals |
| subjects | 420300 - Engineering- Lasers- (-1989) ABSORPTION SPECTRA ALCOHOLS AMINES CARBOXYLIC ACIDS DILUTION DYES EMISSION SPECTROSCOPY ENGINEERING ETHANOL FLUORESCENCE FLUORESCENCE SPECTROSCOPY FREEZING HETEROCYCLIC ACIDS HETEROCYCLIC COMPOUNDS HYDROXY COMPOUNDS LOW TEMPERATURE LUMINESCENCE MEDIUM TEMPERATURE MOLECULAR STRUCTURE OPTICAL PROPERTIES ORGANIC ACIDS ORGANIC COMPOUNDS ORGANIC OXYGEN COMPOUNDS PHYSICAL PROPERTIES REAGENTS RHODAMINES SPECTRA SPECTROSCOPY STRUCTURAL CHEMICAL ANALYSIS TEMPERATURE EFFECTS VITRIFICATION |
| title | Influence of temperature on the spectral-luminescent properties of rhodamine-dye solutions |
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