Rotational motion under pressure in the solid molecular hydrogen isotopes
Rotational states as functions of pressure for H$sub 2$, D$sub 2$, T$sub 2$, HD, and HT molecules are calculated in the corresponding molecular solids. Sudden transitions from spherically symmetric rotational states occur in para- H$sub 2$, para-T$sub 2$, ortho-D$sub 2$, and in HD and HT as the pres...
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Veröffentlicht in: | J. Low Temp. Phys., v. 22, no. 1/2, pp. 213-222 v. 22, no. 1/2, pp. 213-222, 1976-01, Vol.22 (1-2), p.213-222 |
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container_title | J. Low Temp. Phys., v. 22, no. 1/2, pp. 213-222 |
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creator | England, Walter Raich, John C. Etters, Richard D. |
description | Rotational states as functions of pressure for H$sub 2$, D$sub 2$, T$sub 2$, HD, and HT molecules are calculated in the corresponding molecular solids. Sudden transitions from spherically symmetric rotational states occur in para- H$sub 2$, para-T$sub 2$, ortho-D$sub 2$, and in HD and HT as the pressure increases. Only the predicted T$sub 2$ transition pressure of about 24 kbar lies within current experimentally accessible ranges. All other transitions occur in the region 150-300 kbar. (auth) |
doi_str_mv | 10.1007/BF00655222 |
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Sudden transitions from spherically symmetric rotational states occur in para- H$sub 2$, para-T$sub 2$, ortho-D$sub 2$, and in HD and HT as the pressure increases. Only the predicted T$sub 2$ transition pressure of about 24 kbar lies within current experimentally accessible ranges. All other transitions occur in the region 150-300 kbar. (auth)</description><identifier>ISSN: 0022-2291</identifier><identifier>EISSN: 1573-7357</identifier><identifier>DOI: 10.1007/BF00655222</identifier><language>eng</language><publisher>United States</publisher><subject><![CDATA[640302 -Physics Research-Atomic, Molecular & Chemical Physics-Atomic & Molecular Properties ; DEUTERIUM- ROTATIONAL STATES ; HYDROGEN DEUTERIDE- ROTATIONAL STATES ; HYDROGEN TRITIDE ; HYDROGEN- ROTATIONAL STATES ; N40210 -Chemistry-Inorganic, Organic, & Physical Chemistry-Chemical & Physiochemical Properties ; N60200 -Physics (Atomic & Molecular)-Atomic & Molecular Properties ; PRESSURE DEPENDENCE ; SOLIDS ; TRITIUM- ROTATIONAL STATES ; VERY HIGH PRESSURE]]></subject><ispartof>J. Low Temp. 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Low Temp. Phys., v. 22, no. 1/2, pp. 213-222</title><description>Rotational states as functions of pressure for H$sub 2$, D$sub 2$, T$sub 2$, HD, and HT molecules are calculated in the corresponding molecular solids. Sudden transitions from spherically symmetric rotational states occur in para- H$sub 2$, para-T$sub 2$, ortho-D$sub 2$, and in HD and HT as the pressure increases. Only the predicted T$sub 2$ transition pressure of about 24 kbar lies within current experimentally accessible ranges. All other transitions occur in the region 150-300 kbar. (auth)</description><subject>640302 -Physics Research-Atomic, Molecular & Chemical Physics-Atomic & Molecular Properties</subject><subject>DEUTERIUM- ROTATIONAL STATES</subject><subject>HYDROGEN DEUTERIDE- ROTATIONAL STATES</subject><subject>HYDROGEN TRITIDE</subject><subject>HYDROGEN- ROTATIONAL STATES</subject><subject>N40210 -Chemistry-Inorganic, Organic, & Physical Chemistry-Chemical & Physiochemical Properties</subject><subject>N60200 -Physics (Atomic & Molecular)-Atomic & Molecular Properties</subject><subject>PRESSURE DEPENDENCE</subject><subject>SOLIDS</subject><subject>TRITIUM- ROTATIONAL STATES</subject><subject>VERY HIGH PRESSURE</subject><issn>0022-2291</issn><issn>1573-7357</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1976</creationdate><recordtype>article</recordtype><recordid>eNpFkEFLxDAUhIMoWFcv_oLgUai-JE3SHHVxdWFBED2XNnm1kW6zJNnD_nu7rOBphuFjGIaQWwYPDEA_Pq8AlJSc8zNSMKlFqYXU56QA4Lzk3LBLcpXSDwCYWomCrD9CbrMPUzvSbTgaup8cRrqLmNI-IvUTzQPSFEbvZmREux_bSIeDi-EbJ-pTyGGH6Zpc9O2Y8OZPF-Rr9fK5fCs376_r5dOmtFyqXGpdWdEzIbkTvZOiY0xZK5gBV3PoamOsskrPeedkXSmsOuP0PBwr57gGsSB3p96Qsm-S9RntYMM0oc1NBVVttJqh-xNkY0gpYt_sot-28dAwaI5PNf9PiV-9hVrA</recordid><startdate>197601</startdate><enddate>197601</enddate><creator>England, Walter</creator><creator>Raich, John C.</creator><creator>Etters, Richard D.</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>197601</creationdate><title>Rotational motion under pressure in the solid molecular hydrogen isotopes</title><author>England, Walter ; Raich, John C. ; Etters, Richard D.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c256t-774c3f1352d3fd53b116cc3190d820b899c6c673b1bd5846e4b9d7291e4dd2703</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1976</creationdate><topic>640302 -Physics Research-Atomic, Molecular & Chemical Physics-Atomic & Molecular Properties</topic><topic>DEUTERIUM- ROTATIONAL STATES</topic><topic>HYDROGEN DEUTERIDE- ROTATIONAL STATES</topic><topic>HYDROGEN TRITIDE</topic><topic>HYDROGEN- ROTATIONAL STATES</topic><topic>N40210 -Chemistry-Inorganic, Organic, & Physical Chemistry-Chemical & Physiochemical Properties</topic><topic>N60200 -Physics (Atomic & Molecular)-Atomic & Molecular Properties</topic><topic>PRESSURE DEPENDENCE</topic><topic>SOLIDS</topic><topic>TRITIUM- ROTATIONAL STATES</topic><topic>VERY HIGH PRESSURE</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>England, Walter</creatorcontrib><creatorcontrib>Raich, John C.</creatorcontrib><creatorcontrib>Etters, Richard D.</creatorcontrib><creatorcontrib>Argonne National Lab., IL</creatorcontrib><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>J. Low Temp. Phys., v. 22, no. 1/2, pp. 213-222</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>England, Walter</au><au>Raich, John C.</au><au>Etters, Richard D.</au><aucorp>Argonne National Lab., IL</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Rotational motion under pressure in the solid molecular hydrogen isotopes</atitle><jtitle>J. Low Temp. Phys., v. 22, no. 1/2, pp. 213-222</jtitle><date>1976-01</date><risdate>1976</risdate><volume>22</volume><issue>1-2</issue><spage>213</spage><epage>222</epage><pages>213-222</pages><issn>0022-2291</issn><eissn>1573-7357</eissn><abstract>Rotational states as functions of pressure for H$sub 2$, D$sub 2$, T$sub 2$, HD, and HT molecules are calculated in the corresponding molecular solids. Sudden transitions from spherically symmetric rotational states occur in para- H$sub 2$, para-T$sub 2$, ortho-D$sub 2$, and in HD and HT as the pressure increases. Only the predicted T$sub 2$ transition pressure of about 24 kbar lies within current experimentally accessible ranges. All other transitions occur in the region 150-300 kbar. (auth)</abstract><cop>United States</cop><doi>10.1007/BF00655222</doi><tpages>10</tpages></addata></record> |
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subjects | 640302 -Physics Research-Atomic, Molecular & Chemical Physics-Atomic & Molecular Properties DEUTERIUM- ROTATIONAL STATES HYDROGEN DEUTERIDE- ROTATIONAL STATES HYDROGEN TRITIDE HYDROGEN- ROTATIONAL STATES N40210 -Chemistry-Inorganic, Organic, & Physical Chemistry-Chemical & Physiochemical Properties N60200 -Physics (Atomic & Molecular)-Atomic & Molecular Properties PRESSURE DEPENDENCE SOLIDS TRITIUM- ROTATIONAL STATES VERY HIGH PRESSURE |
title | Rotational motion under pressure in the solid molecular hydrogen isotopes |
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