Solid-Phase Extraction of Phenol and Chlorophenols in Water with a Chemically Modified Polymer-Supported Tetrakis(p-carboxyphenyl) Porphyrin (H2TCPP)

A chemically modified sorbent was evaluated as a preconcentration substrate in solid-phase extraction of phenol and chlorophenols. Tetrakis(p-carboxyphenyl) porphyrin (H2TCPP) was chemically bonded to porous polymeric XAD resins by ketone linkage. Breakthrough volumes, recovery values, and detection...

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Veröffentlicht in:Microchemical journal 1999-09, Vol.63 (1), p.134-139
Hauptverfasser: Kim, Do-Gyun, Jung, Min-Woo, Paeng, Insook Rhee, Rhee, Jae-Seong, Paeng, Ki-Jung
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container_end_page 139
container_issue 1
container_start_page 134
container_title Microchemical journal
container_volume 63
creator Kim, Do-Gyun
Jung, Min-Woo
Paeng, Insook Rhee
Rhee, Jae-Seong
Paeng, Ki-Jung
description A chemically modified sorbent was evaluated as a preconcentration substrate in solid-phase extraction of phenol and chlorophenols. Tetrakis(p-carboxyphenyl) porphyrin (H2TCPP) was chemically bonded to porous polymeric XAD resins by ketone linkage. Breakthrough volumes, recovery values, and detection limits were determined. The synthesized sorbent showed higher recoveries in tap water than commercially available sorbents such as XAD-2 and XAD-4.
doi_str_mv 10.1006/mchj.1999.1775
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identifier ISSN: 0026-265X
ispartof Microchemical journal, 1999-09, Vol.63 (1), p.134-139
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language eng
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source Elsevier ScienceDirect Journals
subjects Analytical chemistry
Applied sciences
chemically modified sorbent
Chemistry
chlorophenols
Chromatographic methods and physical methods associated with chromatography
Drinking water and swimming-pool water. Desalination
Exact sciences and technology
Other chromatographic methods
phenol
Pollution
solid-phase extraction
tetrakis(p-carboxyphenyl)porphyrin
Water treatment and pollution
XAD-2
XAD-4
title Solid-Phase Extraction of Phenol and Chlorophenols in Water with a Chemically Modified Polymer-Supported Tetrakis(p-carboxyphenyl) Porphyrin (H2TCPP)
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