The Selective Monohalogenation of Dihydro- and Trihydrosilanes

The Selective Monohalogenation of Dihydro- and Trihydrosilanes

The selective monohalogenation of dihexylsilane by a number of oxidants was studied. The most selective oxidant was found to be N-bromosuccinimide, NBS, yielding products of monobromination with greater than 50:1 selectivity. Various degrees of monoselectivity were found in the bromination of other...

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Veröffentlicht in:Microchemical journal 1997-02, Vol.55 (2), p.222-234
Hauptverfasser: Gansle, Paul B., Gruber, Brian C., Jarvis, James T., Slaitas, Andis, De Jesus, SenaMarie, De Jesus, Karl
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container_end_page 234
container_issue 2
container_start_page 222
container_title Microchemical journal
container_volume 55
creator Gansle, Paul B.
Gruber, Brian C.
Jarvis, James T.
Slaitas, Andis
De Jesus, SenaMarie
De Jesus, Karl
description The selective monohalogenation of dihexylsilane by a number of oxidants was studied. The most selective oxidant was found to be N-bromosuccinimide, NBS, yielding products of monobromination with greater than 50:1 selectivity. Various degrees of monoselectivity were found in the bromination of other differentially substituted dihydro- and trihydrosilanes by NBS.
doi_str_mv 10.1006/mchj.1996.1417
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title The Selective Monohalogenation of Dihydro- and Trihydrosilanes
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