Microwave-Assisted Preparation, Morphological, and Photoacoustic Studies of the Na4SnSe4, K4Sn2Se6, and K4Sn3Se8, Zintl Molecular Sn–Se Oligomers

The Zintl compounds Na4SnSe4, K4Sn2Se6, and K4Sn3Se8 were prepared for the first time using the microwave-assisted solid-state reaction method. The heteroanions of these phases represent oligomeric group of (zero-dimensional) molecular anions: [SnSe4]4−, [Sn2Se6]4−, [Sn3Se8]4−. The compounds were ch...

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Veröffentlicht in:	Journal of solid state chemistry 2002-04, Vol.165 (1), p.125-130
Hauptverfasser:	Palchik, O., Gedanken, A., Palchik, V., Slifkin, M.A., Weiss, A.M.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Condensed matter: structure, mechanical and thermal properties Coordination compounds Exact sciences and technology Inorganic chemistry and origins of life Inorganic compounds Metal complexes Physics Preparations and properties Structure of solids and liquids crystallography Structure of specific crystalline solids
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