Synthesis of Polyoxovanadates from Aqueous Solutions

Polyoxovanadates have been synthesized from aqueous solutions of VV in the presence of inorganic Na+ and organic [N(CH3)4]+ cations. Decavanadate crystals are precipitated at room temperature around pH 7, whereas layered compounds Na[V3O8].H2O and N(CH3)4[V4O10] are formed at the same pH under hydro...

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Veröffentlicht in:	Journal of solid state chemistry 2001-12, Vol.162 (2), p.315-321
Hauptverfasser:	Bouhedja, L., Steunou, N., Maquet, J., Livage, J.
Format:	Artikel
Sprache:	eng
Schlagworte:	51V NMR spectroscopy hydrothermal synthesis polyoxovanadates
Online-Zugang:	Volltext
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