A New Polymorph of VO2Prepared by Soft Chemical Methods

A novel polymorph of VO2, designated VO2(C), has been prepared by dehydration of the new layered vanadium oxide hydrate, VO2·1/2 H2O. The hydrate is prepared in high yield as a single phase from the hydrothermal reaction of the hydrolyzate of VCl4and NaOH in a molar ratio of 1:4.5 for 96 hours at 20...

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Veröffentlicht in:Journal of solid state chemistry 1998-06, Vol.138 (1), p.178-182
Hauptverfasser: Hagrman, Douglas, Zubieta, Jon, Warren, Christopher J., Meyer, Linda M., Treacy, Michael M.J., Haushalter, Robert C.
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Sprache:eng
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