N2Broadening in the13C16O 2–0 Band around 4167 cm−1

N2Broadening in the13C16O 2–0 Band around 4167 cm−1

N2broadening coefficients have been measured for 65 lines of the13C16O 2–0 band using a Fourier transform spectrometer. These lines are located in the spectral range 4011–4252 cm−1. The spectra were recorded with 99% isotopically pure13CO in a White-type cell at a resolution of 0.005 cm−1. Voigt pro...

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Veröffentlicht in:Journal of molecular spectroscopy 1996-12, Vol.180 (2), p.359-364
Hauptverfasser: Voigt, Susanne, Dreher, Sabine, Orphal, Johannes, Burrows, John P.
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creator Voigt, Susanne
Dreher, Sabine
Orphal, Johannes
Burrows, John P.
description N2broadening coefficients have been measured for 65 lines of the13C16O 2–0 band using a Fourier transform spectrometer. These lines are located in the spectral range 4011–4252 cm−1. The spectra were recorded with 99% isotopically pure13CO in a White-type cell at a resolution of 0.005 cm−1. Voigt profiles convolved with the FTS apparatus function were fitted to the experimental lineshapes using a nonlinear least-squares fit technique. From the fits the Lorentzian HWHM was determined as function of N2pressure. Pressure broadening coefficients formbetween −33 and +34 were obtained with uncertainties of 5.8%. The results are compared to earlier published N2broadening coefficients and our measurements in the 2–0 band of12C16O. To our knowledge this is the first investigation of13CO pressure broadening.
doi_str_mv 10.1006/jmsp.1996.0259
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title N2Broadening in the13C16O 2–0 Band around 4167 cm−1
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