Detecting the Transient ENDOR Response
Free radicals at low temperature are sometimes difficult to study by electron-nuclear double-resonance spectroscopy with the commonly available detection schemes. In some cases, slow nuclear spin relaxation limits the steady-state ENDOR response. A detection scheme optimized for transient signals is...
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| Veröffentlicht in: | Journal of magnetic resonance. Series A 1995-02, Vol.112 (2), p.220-224 |
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| container_end_page | 224 |
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| container_issue | 2 |
| container_start_page | 220 |
| container_title | Journal of magnetic resonance. Series A |
| container_volume | 112 |
| creator | Hoganson, C.W. Babcock, G.T. |
| description | Free radicals at low temperature are sometimes difficult to study by electron-nuclear double-resonance spectroscopy with the commonly available detection schemes. In some cases, slow nuclear spin relaxation limits the steady-state ENDOR response. A detection scheme optimized for transient signals is described that circumvents this limitation on signal amplitude. The apparatus employs pulsed radiofrequency fields with advance of the radiofrequency between pulses. Some spectra of semiquinone and tyrosine radicals are presented to illustrate the utility of the technique. |
| doi_str_mv | 10.1006/jmra.1995.1034 |
| format | Article |
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Series A</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hoganson, C.W.</au><au>Babcock, G.T.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Detecting the Transient ENDOR Response</atitle><jtitle>Journal of magnetic resonance. Series A</jtitle><date>1995-02-01</date><risdate>1995</risdate><volume>112</volume><issue>2</issue><spage>220</spage><epage>224</epage><pages>220-224</pages><issn>1064-1858</issn><eissn>1096-0864</eissn><abstract>Free radicals at low temperature are sometimes difficult to study by electron-nuclear double-resonance spectroscopy with the commonly available detection schemes. In some cases, slow nuclear spin relaxation limits the steady-state ENDOR response. A detection scheme optimized for transient signals is described that circumvents this limitation on signal amplitude. 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| identifier | ISSN: 1064-1858 |
| ispartof | Journal of magnetic resonance. Series A, 1995-02, Vol.112 (2), p.220-224 |
| issn | 1064-1858 1096-0864 |
| language | eng |
| recordid | cdi_crossref_primary_10_1006_jmra_1995_1034 |
| source | Alma/SFX Local Collection |
| subjects | Atomic and molecular physics Exact sciences and technology Molecular properties and interactions with photons Multiple resonances (including double and higher-order resonance processes, such as double nuclear magnetic resonance, electron double resonance and microwave optical double resonance) Physics |
| title | Detecting the Transient ENDOR Response |
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