The thermochemistry of some polycyclic compounds

The standard massic energies of combustion of eight polycyclic compounds were measured atT=298.15K by static-bomb combustion calorimetry. The standard enthalpies of vaporization and sublimation were measured in a Calvet microcalorimeter, or adiabatic vaporization calorimeter, or derived from ebullio...

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Veröffentlicht in:The Journal of chemical thermodynamics 1998-12, Vol.30 (12), p.1455-1464
Hauptverfasser: Kolesov, V.P., Pimenova, S.M., Lukyanova, V.A., Kuznetsova, T.S., Kozina, M.P.
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container_end_page 1464
container_issue 12
container_start_page 1455
container_title The Journal of chemical thermodynamics
container_volume 30
creator Kolesov, V.P.
Pimenova, S.M.
Lukyanova, V.A.
Kuznetsova, T.S.
Kozina, M.P.
description The standard massic energies of combustion of eight polycyclic compounds were measured atT=298.15K by static-bomb combustion calorimetry. The standard enthalpies of vaporization and sublimation were measured in a Calvet microcalorimeter, or adiabatic vaporization calorimeter, or derived from ebulliometric measurements of the vapour pressure as a function of temperature. The standard molar enthalpies of formation in the condensed and gaseous states were obtained from these data. The peculiarities in the strain energies of polycyclic compounds are discussed.
doi_str_mv 10.1006/jcht.1998.0413
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subjects calorimetry
enthalpies of combustion
enthalpies of formation
polycyclic compounds
thermochemistry
title The thermochemistry of some polycyclic compounds
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