Densities of (water + methane) in the temperature range 430 K to 699 K and at pressures up to 30 MPa

New measurements of the amount-of-substance densities ρ of nine mixtures of (water + methane) are reported in the temperature range 430 K to 699 K at pressures from 7.5 MPa to 30 MPa. The results have been obtained by using a fully automated isochoric instrument. The uncertainty in the experimental...

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Veröffentlicht in:The Journal of chemical thermodynamics 1996-04, Vol.28 (4), p.447-458
Hauptverfasser: Fenghour, A., Wakeham, W.A., Watson, J.T.R.
Format: Artikel
Sprache:eng
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Zusammenfassung:New measurements of the amount-of-substance densities ρ of nine mixtures of (water + methane) are reported in the temperature range 430 K to 699 K at pressures from 7.5 MPa to 30 MPa. The results have been obtained by using a fully automated isochoric instrument. The uncertainty in the experimental results is estimated to be about ± 0.0008·ρ at the lowest water content and ± 0.0014·ρ at the highest water content. Comparisons with independent sources of experimental information through a model based on the two-fluid corresponding states principle are presented. The dew points of the mixtures studied have also been determined and compared with predicted values from the Peng-Robinson equation of state.
ISSN:0021-9614
1096-3626
DOI:10.1006/jcht.1996.0044