Enthalpies of solution and heat capacities for some α,ω-dichloroalkanes in water

Enthalpies of solution for 1,2-dichloroethane, 1,3-dichloropropane, 1,4-dichlorobutane, and 1,5-dichloropentane in water have been determined at temperatures T = 288.15 K, 308.15 K, and 318.15 K. In the solution process the concentrations were regarded as infinitely dilute. From the enthalpies of so...

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Veröffentlicht in:	The Journal of chemical thermodynamics 1993-04, Vol.25 (4), p.519-524
1. Verfasser:	HALLEN, D
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical thermodynamics Chemistry Exact sciences and technology General and physical chemistry Mixtures Thermodynamic properties
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description	Enthalpies of solution for 1,2-dichloroethane, 1,3-dichloropropane, 1,4-dichlorobutane, and 1,5-dichloropentane in water have been determined at temperatures T = 288.15 K, 308.15 K, and 318.15 K. In the solution process the concentrations were regarded as infinitely dilute. From the enthalpies of solution at different temperatures, heat capacities of solution and partial molar heat capacities have been calculated. The results of the partial molar heat capacities showed that the additivity rules for the partial molar heat capacity are valid.
doi_str_mv	10.1006/jcht.1993.1160
format	Article
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subjects	Chemical thermodynamics Chemistry Exact sciences and technology General and physical chemistry Mixtures Thermodynamic properties
title	Enthalpies of solution and heat capacities for some α,ω-dichloroalkanes in water
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