Well-Defined Highly Active Heterogeneous Catalyst System for the Coupling Reactions of Carbon Dioxide and Epoxides
The poly(4-vinylpyridine)-supported zinc halide catalysts, prepared from a reaction of ZnX2 and poly(4-vinylpyridine), exhibit high selectivity and activity for the coupling reaction of CO2 and ethylene oxide or propylene oxide. Solid NMR characterization of the poly(4-vinylpyridine)-supported ZnBr2...
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| Veröffentlicht in: | Journal of catalysis 2002-01, Vol.205 (1), p.226-229 |
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| container_end_page | 229 |
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| container_issue | 1 |
| container_start_page | 226 |
| container_title | Journal of catalysis |
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| creator | Kim, Hoon Sik Kim, Jai Jun Kwon, Hyeck Nam Chung, Moon Jo Lee, Byung Gwon Jang, Ho Gyeom |
| description | The poly(4-vinylpyridine)-supported zinc halide catalysts, prepared from a reaction of ZnX2 and poly(4-vinylpyridine), exhibit high selectivity and activity for the coupling reaction of CO2 and ethylene oxide or propylene oxide. Solid NMR characterization of the poly(4-vinylpyridine)-supported ZnBr2 catalyst and its reaction product with propylene oxide and/or CO2 show that a pyridinium-alkoxy ion-bridged zinc bromide complex is functioning as an active species, such as in the homogeneous catalysis with L2ZnBr2 (L = pyridine or methyl-substituted pyridine). |
| doi_str_mv | 10.1006/jcat.2001.3444 |
| format | Article |
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Solid NMR characterization of the poly(4-vinylpyridine)-supported ZnBr2 catalyst and its reaction product with propylene oxide and/or CO2 show that a pyridinium-alkoxy ion-bridged zinc bromide complex is functioning as an active species, such as in the homogeneous catalysis with L2ZnBr2 (L = pyridine or methyl-substituted pyridine).</description><identifier>ISSN: 0021-9517</identifier><identifier>EISSN: 1090-2694</identifier><identifier>DOI: 10.1006/jcat.2001.3444</identifier><identifier>CODEN: JCTLA5</identifier><language>eng</language><publisher>Amsterdam: Elsevier Inc</publisher><subject>carbon dioxide ; Catalysis ; Catalysts: preparations and properties ; Chemistry ; cyclic carbonate ; epoxide ; Exact sciences and technology ; General and physical chemistry ; heterogeneous catalyst ; Theory of reactions, general kinetics. Catalysis. 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Solid NMR characterization of the poly(4-vinylpyridine)-supported ZnBr2 catalyst and its reaction product with propylene oxide and/or CO2 show that a pyridinium-alkoxy ion-bridged zinc bromide complex is functioning as an active species, such as in the homogeneous catalysis with L2ZnBr2 (L = pyridine or methyl-substituted pyridine).</description><subject>carbon dioxide</subject><subject>Catalysis</subject><subject>Catalysts: preparations and properties</subject><subject>Chemistry</subject><subject>cyclic carbonate</subject><subject>epoxide</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>heterogeneous catalyst</subject><subject>Theory of reactions, general kinetics. Catalysis. 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| ispartof | Journal of catalysis, 2002-01, Vol.205 (1), p.226-229 |
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| subjects | carbon dioxide Catalysis Catalysts: preparations and properties Chemistry cyclic carbonate epoxide Exact sciences and technology General and physical chemistry heterogeneous catalyst Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry zinc complex |
| title | Well-Defined Highly Active Heterogeneous Catalyst System for the Coupling Reactions of Carbon Dioxide and Epoxides |
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