Cyclic Tribismuthide as a Piano Stool Complex Ligand – Synthesis and Crystal Structure of (η 3 ‐Bi 3 ) M (CO) 3 3– ( M = Cr, Mo)
The reactions between K 5 Bi 4 , [(C 6 H 6 )Cr(CO) 3 ] or [(C 7 H 8 )Mo(CO) 3 ], and [2.2.2]crypt in liquid ammonia yielded the compounds [K([2.2.2]crypt)] 3 (η 3 ‐Bi 3 ) M (CO) 3 · 10NH 3 ( M = Cr, Mo), which crystallize isostructurally in P 2 1 / n . Both contain an 18 valence electron piano‐stool...
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| Veröffentlicht in: | Zeitschrift für anorganische und allgemeine Chemie (1950) 2019-02, Vol.645 (3), p.146-148 |
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| container_title | Zeitschrift für anorganische und allgemeine Chemie (1950) |
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| creator | Kaas, Marina Korber, Nikolaus |
| description | The reactions between K
5
Bi
4
, [(C
6
H
6
)Cr(CO)
3
] or [(C
7
H
8
)Mo(CO)
3
], and [2.2.2]crypt in liquid ammonia yielded the compounds [K([2.2.2]crypt)]
3
(η
3
‐Bi
3
)
M
(CO)
3
·
10NH
3
(
M
= Cr, Mo), which crystallize isostructurally in
P
2
1
/
n
. Both contain an 18 valence electron piano‐stool complex with a η
3
‐coordinated Bi
3
‐ring ligand. The Bi–Bi distances range from 2.9560(5) to 2.9867(3) Å and are slightly shorter than known Bi–Bi single bonds but longer than Bi–Bi double bonds. The newly found compounds complete the family of similar complexes with
E
3
‐ring ligands (
E
= P‐Bi). |
| doi_str_mv | 10.1002/zaac.201800390 |
| format | Article |
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5
Bi
4
, [(C
6
H
6
)Cr(CO)
3
] or [(C
7
H
8
)Mo(CO)
3
], and [2.2.2]crypt in liquid ammonia yielded the compounds [K([2.2.2]crypt)]
3
(η
3
‐Bi
3
)
M
(CO)
3
·
10NH
3
(
M
= Cr, Mo), which crystallize isostructurally in
P
2
1
/
n
. Both contain an 18 valence electron piano‐stool complex with a η
3
‐coordinated Bi
3
‐ring ligand. The Bi–Bi distances range from 2.9560(5) to 2.9867(3) Å and are slightly shorter than known Bi–Bi single bonds but longer than Bi–Bi double bonds. The newly found compounds complete the family of similar complexes with
E
3
‐ring ligands (
E
= P‐Bi).</description><identifier>ISSN: 0044-2313</identifier><identifier>EISSN: 1521-3749</identifier><identifier>DOI: 10.1002/zaac.201800390</identifier><language>eng</language><ispartof>Zeitschrift für anorganische und allgemeine Chemie (1950), 2019-02, Vol.645 (3), p.146-148</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c840-46ec81c0bc991be2678f6241fd640fd734a7be3734dccca0fb9542cdcd7954bd3</citedby><cites>FETCH-LOGICAL-c840-46ec81c0bc991be2678f6241fd640fd734a7be3734dccca0fb9542cdcd7954bd3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Kaas, Marina</creatorcontrib><creatorcontrib>Korber, Nikolaus</creatorcontrib><title>Cyclic Tribismuthide as a Piano Stool Complex Ligand – Synthesis and Crystal Structure of (η 3 ‐Bi 3 ) M (CO) 3 3– ( M = Cr, Mo)</title><title>Zeitschrift für anorganische und allgemeine Chemie (1950)</title><description>The reactions between K
5
Bi
4
, [(C
6
H
6
)Cr(CO)
3
] or [(C
7
H
8
)Mo(CO)
3
], and [2.2.2]crypt in liquid ammonia yielded the compounds [K([2.2.2]crypt)]
3
(η
3
‐Bi
3
)
M
(CO)
3
·
10NH
3
(
M
= Cr, Mo), which crystallize isostructurally in
P
2
1
/
n
. Both contain an 18 valence electron piano‐stool complex with a η
3
‐coordinated Bi
3
‐ring ligand. The Bi–Bi distances range from 2.9560(5) to 2.9867(3) Å and are slightly shorter than known Bi–Bi single bonds but longer than Bi–Bi double bonds. The newly found compounds complete the family of similar complexes with
E
3
‐ring ligands (
E
= P‐Bi).</description><issn>0044-2313</issn><issn>1521-3749</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNo9kL1OwzAUhS0EEqWwMt-xlUi5jp2_gQEi_qRWRWr3yLEdapQ0lZ1KhImNFYmH4S14CJ4EVyCm79yjc89wCDmlOKGI4fmLEHISIk0RWYZ7ZECjkAYs4dk-GSByHoSMskNy5NwTIlKMogF5y3tZGwlLa0rjmm23MkqDcCDgwYh1C4uubWvI22ZT62eYmkexVvD9-gGLft2ttDM-6p3c9q4TtY_brey2VkNbwejrE5gPv18ZzzHMYJTPx16yXcHI3xf-8Qxm7fiYHFSidvrkj0OyvLle5nfBdH57n19OA5lyDHisZUolljLLaKnDOEmrOOS0UjHHSiWMi6TUzFNJKQVWZRbxUCqpEi9KxYZk8lsrbeuc1VWxsaYRti8oFrsVi92Kxf-K7AdipGW9</recordid><startdate>20190215</startdate><enddate>20190215</enddate><creator>Kaas, Marina</creator><creator>Korber, Nikolaus</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20190215</creationdate><title>Cyclic Tribismuthide as a Piano Stool Complex Ligand – Synthesis and Crystal Structure of (η 3 ‐Bi 3 ) M (CO) 3 3– ( M = Cr, Mo)</title><author>Kaas, Marina ; Korber, Nikolaus</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c840-46ec81c0bc991be2678f6241fd640fd734a7be3734dccca0fb9542cdcd7954bd3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kaas, Marina</creatorcontrib><creatorcontrib>Korber, Nikolaus</creatorcontrib><collection>CrossRef</collection><jtitle>Zeitschrift für anorganische und allgemeine Chemie (1950)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kaas, Marina</au><au>Korber, Nikolaus</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Cyclic Tribismuthide as a Piano Stool Complex Ligand – Synthesis and Crystal Structure of (η 3 ‐Bi 3 ) M (CO) 3 3– ( M = Cr, Mo)</atitle><jtitle>Zeitschrift für anorganische und allgemeine Chemie (1950)</jtitle><date>2019-02-15</date><risdate>2019</risdate><volume>645</volume><issue>3</issue><spage>146</spage><epage>148</epage><pages>146-148</pages><issn>0044-2313</issn><eissn>1521-3749</eissn><abstract>The reactions between K
5
Bi
4
, [(C
6
H
6
)Cr(CO)
3
] or [(C
7
H
8
)Mo(CO)
3
], and [2.2.2]crypt in liquid ammonia yielded the compounds [K([2.2.2]crypt)]
3
(η
3
‐Bi
3
)
M
(CO)
3
·
10NH
3
(
M
= Cr, Mo), which crystallize isostructurally in
P
2
1
/
n
. Both contain an 18 valence electron piano‐stool complex with a η
3
‐coordinated Bi
3
‐ring ligand. The Bi–Bi distances range from 2.9560(5) to 2.9867(3) Å and are slightly shorter than known Bi–Bi single bonds but longer than Bi–Bi double bonds. The newly found compounds complete the family of similar complexes with
E
3
‐ring ligands (
E
= P‐Bi).</abstract><doi>10.1002/zaac.201800390</doi><tpages>3</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0044-2313 |
| ispartof | Zeitschrift für anorganische und allgemeine Chemie (1950), 2019-02, Vol.645 (3), p.146-148 |
| issn | 0044-2313 1521-3749 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_zaac_201800390 |
| source | Wiley Journals |
| title | Cyclic Tribismuthide as a Piano Stool Complex Ligand – Synthesis and Crystal Structure of (η 3 ‐Bi 3 ) M (CO) 3 3– ( M = Cr, Mo) |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-03T05%3A56%3A44IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-crossref&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Cyclic%20Tribismuthide%20as%20a%20Piano%20Stool%20Complex%20Ligand%20%E2%80%93%20Synthesis%20and%20Crystal%20Structure%20of%20(%CE%B7%203%20%E2%80%90Bi%203%20)%20M%20(CO)%203%203%E2%80%93%20(%20M%20=%20Cr,%20Mo)&rft.jtitle=Zeitschrift%20f%C3%BCr%20anorganische%20und%20allgemeine%20Chemie%20(1950)&rft.au=Kaas,%20Marina&rft.date=2019-02-15&rft.volume=645&rft.issue=3&rft.spage=146&rft.epage=148&rft.pages=146-148&rft.issn=0044-2313&rft.eissn=1521-3749&rft_id=info:doi/10.1002/zaac.201800390&rft_dat=%3Ccrossref%3E10_1002_zaac_201800390%3C/crossref%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |