Multiband Transport in CoSb 3 Prepared by Rapid Solidification

Nano-grained CoSb was prepared by melt-spinning and subsequent spark plasma sintering. The phonon thermal conductivity of skutterudites is known to be sensitive to the kind and the amount of guest atoms. Thus, unfilled CoSb can serve as model compound to study the impact of a nanostructure on the th...

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Veröffentlicht in:Zeitschrift für anorganische und allgemeine Chemie (1950) 2015-09, Vol.641 (11), p.2020-2028
Hauptverfasser: Ikeda, Matthias, Tomeš, Petr, Prochaska, Lukas, Eilertsen, James, Populoh, Sascha, Löffler, Stefan, Svagera, Robert, Waas, Monika, Sassik, Herbert, Weidenkaff, Anke, Paschen, Silke
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container_end_page 2028
container_issue 11
container_start_page 2020
container_title Zeitschrift für anorganische und allgemeine Chemie (1950)
container_volume 641
creator Ikeda, Matthias
Tomeš, Petr
Prochaska, Lukas
Eilertsen, James
Populoh, Sascha
Löffler, Stefan
Svagera, Robert
Waas, Monika
Sassik, Herbert
Weidenkaff, Anke
Paschen, Silke
description Nano-grained CoSb was prepared by melt-spinning and subsequent spark plasma sintering. The phonon thermal conductivity of skutterudites is known to be sensitive to the kind and the amount of guest atoms. Thus, unfilled CoSb can serve as model compound to study the impact of a nanostructure on the thermoelectric properties, especially the phonon thermal conductivity. Therefore, a series of materials was prepared differing only by the cooling speed during the quenching procedure. In contrast to clathrates, the microstructure of meltspun CoSb was found to be sensitive to the cooling speed. Although the phonon thermal conductivity, studied by means of Flash and 3 measurements, was found to be correlated with the grain size, the bulk density of the sintered materials had an even stronger impact. Interestingly, the reduced bulk density did not result in an increased electrical resistivity. The influence of Sb and CoSb as foreign phase on the electronic properties of CoSb was revealed by a multi-band Hall effect analysis. While CoSb increases the charge carrier density, the influence of the highly mobile charge carriers introduced by elemental Sb on the thermoelectric properties of the composite offer an interesting perspective for the preparation of efficient thermoelectric composite materials.
doi_str_mv 10.1002/zaac.201500179
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title Multiband Transport in CoSb 3 Prepared by Rapid Solidification
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