Syntheses, Structures, and Luminescent Properties of Two Novel Coordination Polymers with Dipicolinate and Diimidazole Ligands

Syntheses, Structures, and Luminescent Properties of Two Novel Coordination Polymers with Dipicolinate and Diimidazole Ligands

Two novel coordination polymers, [Zn(dpc)(bmix)0.5]n (1), [Pb(dpc)(bmix)0.5]n (2), [dpc = dipicolinate, bmix = 1,4‐bis(2‐methylimidazole‐1‐ylmethyl)benzene], were hydrothermally synthesized and characterized by elemental analyses, IR spectroscopy, TGA, and X‐ray single crystal diffraction. In both c...

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Veröffentlicht in:ZAAC - Journal of Inorganic and General Chemistry 2011-01, Vol.637 (1), p.148-153
Hauptverfasser: Liu, Tong-Fei, Wu, Wan-Fei, Zhang, Wei-Guo, Cui, Guang-Hua
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Coordination polymers
Diimidazole
Dipicolinate
Fluorescence
Lead
Zinc
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Wu, Wan-Fei
Zhang, Wei-Guo
Cui, Guang-Hua
description Two novel coordination polymers, [Zn(dpc)(bmix)0.5]n (1), [Pb(dpc)(bmix)0.5]n (2), [dpc = dipicolinate, bmix = 1,4‐bis(2‐methylimidazole‐1‐ylmethyl)benzene], were hydrothermally synthesized and characterized by elemental analyses, IR spectroscopy, TGA, and X‐ray single crystal diffraction. In both complexes, the dipicolinate and bmix ligands act as spacers to link metal ions to give a 2D corrugated (6,3) network of 1 and a 3D microporous framework of 2, respectively. The difference in the architectures is due to a diverging coordination mode of the carboxylate function. Furthermore, solid state fluorescence properties of the two complexes were investigated at room temperature.
doi_str_mv 10.1002/zaac.201000270
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subjects Coordination polymers
Diimidazole
Dipicolinate
Fluorescence
Lead
Zinc
title Syntheses, Structures, and Luminescent Properties of Two Novel Coordination Polymers with Dipicolinate and Diimidazole Ligands
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