The Synthesis of Anatase TiO 2 Nanoparticles by Solvothermal Method using Ionic Liquid as Additive
The solvothermal reactions of Ti(O i Pr) 4 in alcohol using ionic liquid as additive were investigated. In the presence of [BMIM][Cl], [BMIM][Br], [BMIM][NTf 2 ], [BMIM][SO 3 Me], [BMIM][SO 4 Me], or [BMIM][OTf] (BMIM = 1‐Butyl‐3‐methylimidazolium), pure anatase nanoparticles were obtained. The cont...
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| Veröffentlicht in: | Zeitschrift für anorganische und allgemeine Chemie (1950) 2010-09, Vol.636 (11), p.1947-1954 |
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| Sprache: | eng |
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| container_end_page | 1954 |
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| container_issue | 11 |
| container_start_page | 1947 |
| container_title | Zeitschrift für anorganische und allgemeine Chemie (1950) |
| container_volume | 636 |
| creator | Lin, Hechun de Oliveira, Peter W. Grobelsek, Ingrid Haettich, Aude Veith, Michael |
| description | The solvothermal reactions of Ti(O
i
Pr)
4
in alcohol using ionic liquid as additive were investigated. In the presence of [BMIM][Cl], [BMIM][Br], [BMIM][NTf
2
], [BMIM][SO
3
Me], [BMIM][SO
4
Me], or [BMIM][OTf] (BMIM = 1‐Butyl‐3‐methylimidazolium), pure anatase nanoparticles were obtained. The controlled hydrolysis of Ti(O
i
Pr)
4
in the presence of ionic liquids to form titanium oxo clusters plays a key role in the formation of anatase nanostructures, and ionic liquids can be repeatedly used to synthesise anatase nanoparticles. However, in the presence of [BMIM][PF
6
], [BMIM]
2
[Ti(OH)
6
] was obtained by an anion exchange reaction. |
| doi_str_mv | 10.1002/zaac.201000073 |
| format | Article |
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i
Pr)
4
in alcohol using ionic liquid as additive were investigated. In the presence of [BMIM][Cl], [BMIM][Br], [BMIM][NTf
2
], [BMIM][SO
3
Me], [BMIM][SO
4
Me], or [BMIM][OTf] (BMIM = 1‐Butyl‐3‐methylimidazolium), pure anatase nanoparticles were obtained. The controlled hydrolysis of Ti(O
i
Pr)
4
in the presence of ionic liquids to form titanium oxo clusters plays a key role in the formation of anatase nanostructures, and ionic liquids can be repeatedly used to synthesise anatase nanoparticles. However, in the presence of [BMIM][PF
6
], [BMIM]
2
[Ti(OH)
6
] was obtained by an anion exchange reaction.</description><identifier>ISSN: 0044-2313</identifier><identifier>EISSN: 1521-3749</identifier><identifier>DOI: 10.1002/zaac.201000073</identifier><language>eng</language><ispartof>Zeitschrift für anorganische und allgemeine Chemie (1950), 2010-09, Vol.636 (11), p.1947-1954</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c843-3941bf4e4b3fd835c681db792f12813e7c00b5cb376e789b172680de23ceb33e3</citedby><cites>FETCH-LOGICAL-c843-3941bf4e4b3fd835c681db792f12813e7c00b5cb376e789b172680de23ceb33e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,781,785,27929,27930</link.rule.ids></links><search><creatorcontrib>Lin, Hechun</creatorcontrib><creatorcontrib>de Oliveira, Peter W.</creatorcontrib><creatorcontrib>Grobelsek, Ingrid</creatorcontrib><creatorcontrib>Haettich, Aude</creatorcontrib><creatorcontrib>Veith, Michael</creatorcontrib><title>The Synthesis of Anatase TiO 2 Nanoparticles by Solvothermal Method using Ionic Liquid as Additive</title><title>Zeitschrift für anorganische und allgemeine Chemie (1950)</title><description>The solvothermal reactions of Ti(O
i
Pr)
4
in alcohol using ionic liquid as additive were investigated. In the presence of [BMIM][Cl], [BMIM][Br], [BMIM][NTf
2
], [BMIM][SO
3
Me], [BMIM][SO
4
Me], or [BMIM][OTf] (BMIM = 1‐Butyl‐3‐methylimidazolium), pure anatase nanoparticles were obtained. The controlled hydrolysis of Ti(O
i
Pr)
4
in the presence of ionic liquids to form titanium oxo clusters plays a key role in the formation of anatase nanostructures, and ionic liquids can be repeatedly used to synthesise anatase nanoparticles. However, in the presence of [BMIM][PF
6
], [BMIM]
2
[Ti(OH)
6
] was obtained by an anion exchange reaction.</description><issn>0044-2313</issn><issn>1521-3749</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNo9kEtPwkAURidGExHdur5_oDgzd8q0S0J8kKAs6L6Zx62MKR3sFBL89UIwrr5vcXIWh7FHwSeCc_n0Y4ybSH76nGu8YiORS5GhVuU1G3GuVCZR4C27S-nrhAie5yNmqw3B-tgNG0ohQWxg1pnBJIIqrEDCh-nizvRDcC0lsEdYx_YQT3S_NS2807CJHvYpdJ-wiF1wsAzf--DBJJh5H4ZwoHt205g20cPfjln18lzN37Ll6nUxny0zVyjMsFTCNoqUxcYXmLtpIbzVpWyELASSdpzb3FnUU9JFaYWW04J7kujIIhKO2eSidX1Mqaem3vVha_pjLXh9DlSfA9X_gfAXKmFZUA</recordid><startdate>201009</startdate><enddate>201009</enddate><creator>Lin, Hechun</creator><creator>de Oliveira, Peter W.</creator><creator>Grobelsek, Ingrid</creator><creator>Haettich, Aude</creator><creator>Veith, Michael</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>201009</creationdate><title>The Synthesis of Anatase TiO 2 Nanoparticles by Solvothermal Method using Ionic Liquid as Additive</title><author>Lin, Hechun ; de Oliveira, Peter W. ; Grobelsek, Ingrid ; Haettich, Aude ; Veith, Michael</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c843-3941bf4e4b3fd835c681db792f12813e7c00b5cb376e789b172680de23ceb33e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lin, Hechun</creatorcontrib><creatorcontrib>de Oliveira, Peter W.</creatorcontrib><creatorcontrib>Grobelsek, Ingrid</creatorcontrib><creatorcontrib>Haettich, Aude</creatorcontrib><creatorcontrib>Veith, Michael</creatorcontrib><collection>CrossRef</collection><jtitle>Zeitschrift für anorganische und allgemeine Chemie (1950)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lin, Hechun</au><au>de Oliveira, Peter W.</au><au>Grobelsek, Ingrid</au><au>Haettich, Aude</au><au>Veith, Michael</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The Synthesis of Anatase TiO 2 Nanoparticles by Solvothermal Method using Ionic Liquid as Additive</atitle><jtitle>Zeitschrift für anorganische und allgemeine Chemie (1950)</jtitle><date>2010-09</date><risdate>2010</risdate><volume>636</volume><issue>11</issue><spage>1947</spage><epage>1954</epage><pages>1947-1954</pages><issn>0044-2313</issn><eissn>1521-3749</eissn><abstract>The solvothermal reactions of Ti(O
i
Pr)
4
in alcohol using ionic liquid as additive were investigated. In the presence of [BMIM][Cl], [BMIM][Br], [BMIM][NTf
2
], [BMIM][SO
3
Me], [BMIM][SO
4
Me], or [BMIM][OTf] (BMIM = 1‐Butyl‐3‐methylimidazolium), pure anatase nanoparticles were obtained. The controlled hydrolysis of Ti(O
i
Pr)
4
in the presence of ionic liquids to form titanium oxo clusters plays a key role in the formation of anatase nanostructures, and ionic liquids can be repeatedly used to synthesise anatase nanoparticles. However, in the presence of [BMIM][PF
6
], [BMIM]
2
[Ti(OH)
6
] was obtained by an anion exchange reaction.</abstract><doi>10.1002/zaac.201000073</doi><tpages>8</tpages></addata></record> |
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| ispartof | Zeitschrift für anorganische und allgemeine Chemie (1950), 2010-09, Vol.636 (11), p.1947-1954 |
| issn | 0044-2313 1521-3749 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_zaac_201000073 |
| source | Access via Wiley Online Library |
| title | The Synthesis of Anatase TiO 2 Nanoparticles by Solvothermal Method using Ionic Liquid as Additive |
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