Electrochemical and Chemical Syntheses of Trifluoromethylating Reagents and Trifluoromethyl Substituted Compounds

The electroreduction of the halofluoromethanes CF3Br, CF2Br2 and CF2BrCl has been studied in high‐pressure stainless steel autoclaves at different cathodes [Pt, steel (V2A, V4A), glassy carbon (GC)] and in various solvent‐supporting electrolyte systems (SSE), e.g. DMF/[Bu4N]Br, NMP/[Bu4N]BF4 etc. Th...

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Veröffentlicht in:	Zeitschrift für anorganische und allgemeine Chemie (1950) 2008-09, Vol.634 (11), p.1975-1990
Hauptverfasser:	Grobe, Joseph, Hegge, Joachim
Format:	Artikel
Sprache:	eng
Schlagworte:	germanium In tin compounds Trifluoromethyl metal reagents (Zn Trifluoromethyl metal reagents (Zn, Cd, Ga, In) Trifluoromethyl silicon Trifluoromethyl silicon, ‐germanium, ‐tin compounds Trifluoromethylation(electrochemical/chemical)
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