The Crystal Structure of Dimethylamino Titanium Trichloride

The Crystal Structure of Dimethylamino Titanium Trichloride

Green crystals of Me2NTiCl3 associate to a chain polymer via four Ti‐Cl‐Ti bonds and generation of hexacoordinated Ti atoms. Like Et2NTiCl3 its amino group is not involved into forming Ti‐N‐Ti bridges. This is due to a short Ti‐N bond to the planar coordinated N atom of the Me2N group.

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Bibliographische Detailangaben
Veröffentlicht in:Zeitschrift für anorganische und allgemeine Chemie (1950) 2008-02, Vol.634 (2), p.234-236
Hauptverfasser: Günther, Bernd, Nöth, Heinrich
Format: Artikel
Sprache:eng
Schlagworte:
Crystal structure
Dimethylamino titanium trichloride
Titanium
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Beschreibung
Zusammenfassung:Green crystals of Me2NTiCl3 associate to a chain polymer via four Ti‐Cl‐Ti bonds and generation of hexacoordinated Ti atoms. Like Et2NTiCl3 its amino group is not involved into forming Ti‐N‐Ti bridges. This is due to a short Ti‐N bond to the planar coordinated N atom of the Me2N group.
ISSN:0044-2313
1521-3749
DOI:10.1002/zaac.200700418