Synthesis and some Reactions of Alkali Metal Carbamotelluroates

Synthesis and some Reactions of Alkali Metal Carbamotelluroates

Sodium and potassium carbamotelluroates [M(R2NCOTe), M = Na, K, Rb, Cs] were synthesized in moderate to good yields by reacting carbamoyl chloride with the corresponding alkali metal tellurides. The salts readily reacted with trimethylsilyl chloride to form O‐trimethylsilyl carbamotelluroate (R2NCTe...

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Veröffentlicht in:Zeitschrift für anorganische und allgemeine Chemie (1950) 2007-04, Vol.633 (4), p.635-639
Hauptverfasser: Ibi, Kazumasa, Imase, Tomohiro, Kato, Shinzi, Ando, Fumio, Koketsu, Jugo
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Sprache:eng
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Alkali metal carbamotelluroate
Dicarbamoyl telluride
O-Silyl carbamotelluroate
Te-alkyl telluroester
Te-stannyl carbamotelluroate
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container_title Zeitschrift für anorganische und allgemeine Chemie (1950)
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creator Ibi, Kazumasa
Imase, Tomohiro
Kato, Shinzi
Ando, Fumio
Koketsu, Jugo
description Sodium and potassium carbamotelluroates [M(R2NCOTe), M = Na, K, Rb, Cs] were synthesized in moderate to good yields by reacting carbamoyl chloride with the corresponding alkali metal tellurides. The salts readily reacted with trimethylsilyl chloride to form O‐trimethylsilyl carbamotelluroate (R2NCTeOSiMe3), which further reacted with RbF and CsF to lead to the corresponding heavy alkali metal carbamotelluroates. These salts reacted with alkyl iodide and carbamoyl chlorides to give the corresponding Te‐alkyl carbamotelluroates and dicarbamoyl tellurides in moderate yields.
doi_str_mv 10.1002/zaac.200600370
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The salts readily reacted with trimethylsilyl chloride to form O‐trimethylsilyl carbamotelluroate (R2NCTeOSiMe3), which further reacted with RbF and CsF to lead to the corresponding heavy alkali metal carbamotelluroates. These salts reacted with alkyl iodide and carbamoyl chlorides to give the corresponding Te‐alkyl carbamotelluroates and dicarbamoyl tellurides in moderate yields.</description><identifier>ISSN: 0044-2313</identifier><identifier>EISSN: 1521-3749</identifier><identifier>DOI: 10.1002/zaac.200600370</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Alkali metal carbamotelluroate ; Dicarbamoyl telluride ; O-Silyl carbamotelluroate ; Te-alkyl telluroester ; Te-stannyl carbamotelluroate</subject><ispartof>Zeitschrift für anorganische und allgemeine Chemie (1950), 2007-04, Vol.633 (4), p.635-639</ispartof><rights>Copyright © 2007 WILEY‐VCH Verlag GmbH &amp; Co. 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subjects Alkali metal carbamotelluroate
Dicarbamoyl telluride
O-Silyl carbamotelluroate
Te-alkyl telluroester
Te-stannyl carbamotelluroate
title Synthesis and some Reactions of Alkali Metal Carbamotelluroates
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