N-(2-Hydroxyethyl)-N-methyldithiocarbamato Complexes of Nickel(II) with Phosphorus Donor Ligands
Planar nickel(II) complexes involving N‐(2‐Hydroxyethyl)‐N‐methyldithiocarbamate, such as [NiX(nmedtc)(PPh3)] (X = Cl, NCS; PPh3 = triphenylphosphine), and [Ni(nmedtc)(P‐P)]ClO4(P‐P = 1,1‐bis(diphenylphosphino)methane(dppm); 1,3‐bis(diphenylphosphino)propane (1,3‐dppp); 1,4‐bis(diphenylphosphino)but...
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| Veröffentlicht in: | Zeitschrift für anorganische und allgemeine Chemie (1950) 2006-02, Vol.632 (3), p.461-464 |
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| container_title | Zeitschrift für anorganische und allgemeine Chemie (1950) |
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| creator | Manohar, A. Ramalingam, K. Thiruneelakandan, R. Bocelli, G. Righi, L. |
| description | Planar nickel(II) complexes involving N‐(2‐Hydroxyethyl)‐N‐methyldithiocarbamate, such as [NiX(nmedtc)(PPh3)] (X = Cl, NCS; PPh3 = triphenylphosphine), and [Ni(nmedtc)(P‐P)]ClO4(P‐P = 1,1‐bis(diphenylphosphino)methane(dppm); 1,3‐bis(diphenylphosphino)propane (1,3‐dppp); 1,4‐bis(diphenylphosphino)butane(1,4‐dppb) have been synthesized. The complexes have been characterized by elemental analyses, IR and electronic spectroscopies. The increased νC–N value in all the complexes is due to the mesomeric drift of electrons from the dithiocarbamate ligands to the metal atom. Single crystal X‐ray structure of [Ni(nmedtc)(1,3‐dppp)]ClO4·H2O is reported. In the present 1,3‐dppp chelate, the P–Ni–P angle is higher than that found in 1,2‐bis(diphenylphosphino)ethane‐nickel chelates and lower than 1,4‐bis(diphenylphosphino)butane‐nickel chelates, as a result of presence of the flexible propyl back bone connecting the two phosphorus atoms of the complex. |
| doi_str_mv | 10.1002/zaac.200500282 |
| format | Article |
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The complexes have been characterized by elemental analyses, IR and electronic spectroscopies. The increased νC–N value in all the complexes is due to the mesomeric drift of electrons from the dithiocarbamate ligands to the metal atom. Single crystal X‐ray structure of [Ni(nmedtc)(1,3‐dppp)]ClO4·H2O is reported. In the present 1,3‐dppp chelate, the P–Ni–P angle is higher than that found in 1,2‐bis(diphenylphosphino)ethane‐nickel chelates and lower than 1,4‐bis(diphenylphosphino)butane‐nickel chelates, as a result of presence of the flexible propyl back bone connecting the two phosphorus atoms of the complex.</description><identifier>ISSN: 0044-2313</identifier><identifier>EISSN: 1521-3749</identifier><identifier>DOI: 10.1002/zaac.200500282</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>1,3‐Bis(diphenylphosphino)propane ; 3-Bis(diphenylphosphino)propane ; Dithiocarbamate ; Thioureide</subject><ispartof>Zeitschrift für anorganische und allgemeine Chemie (1950), 2006-02, Vol.632 (3), p.461-464</ispartof><rights>Copyright © 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3272-cffeea56e293cbd91a683c0ed16760841008a3c772f7548c47b309b8cdeebbbb3</citedby><cites>FETCH-LOGICAL-c3272-cffeea56e293cbd91a683c0ed16760841008a3c772f7548c47b309b8cdeebbbb3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fzaac.200500282$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,777,781,1412,27905,27906,45556</link.rule.ids></links><search><creatorcontrib>Manohar, A.</creatorcontrib><creatorcontrib>Ramalingam, K.</creatorcontrib><creatorcontrib>Thiruneelakandan, R.</creatorcontrib><creatorcontrib>Bocelli, G.</creatorcontrib><creatorcontrib>Righi, L.</creatorcontrib><title>N-(2-Hydroxyethyl)-N-methyldithiocarbamato Complexes of Nickel(II) with Phosphorus Donor Ligands</title><title>Zeitschrift für anorganische und allgemeine Chemie (1950)</title><addtitle>Z. anorg. allg. Chem</addtitle><description>Planar nickel(II) complexes involving N‐(2‐Hydroxyethyl)‐N‐methyldithiocarbamate, such as [NiX(nmedtc)(PPh3)] (X = Cl, NCS; PPh3 = triphenylphosphine), and [Ni(nmedtc)(P‐P)]ClO4(P‐P = 1,1‐bis(diphenylphosphino)methane(dppm); 1,3‐bis(diphenylphosphino)propane (1,3‐dppp); 1,4‐bis(diphenylphosphino)butane(1,4‐dppb) have been synthesized. The complexes have been characterized by elemental analyses, IR and electronic spectroscopies. The increased νC–N value in all the complexes is due to the mesomeric drift of electrons from the dithiocarbamate ligands to the metal atom. Single crystal X‐ray structure of [Ni(nmedtc)(1,3‐dppp)]ClO4·H2O is reported. In the present 1,3‐dppp chelate, the P–Ni–P angle is higher than that found in 1,2‐bis(diphenylphosphino)ethane‐nickel chelates and lower than 1,4‐bis(diphenylphosphino)butane‐nickel chelates, as a result of presence of the flexible propyl back bone connecting the two phosphorus atoms of the complex.</description><subject>1,3‐Bis(diphenylphosphino)propane</subject><subject>3-Bis(diphenylphosphino)propane</subject><subject>Dithiocarbamate</subject><subject>Thioureide</subject><issn>0044-2313</issn><issn>1521-3749</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><recordid>eNqFkD1PwzAQhi0EEqWwMmdsBxd_xHEylgBtpRIY-BKLcRyHhCZ1ZQe14deTUlSxccvdSe9z0j0AnGM0wgiRiy8p1YggxLolJAeghxnBkHI_OgQ9hHwfEorpMThx7gMhhBFjPfCWwAGB0zazZtPqpmirIUxg_TNlZVOURkmbylo2xotNvar0RjvP5F5SqoWuBrPZ0Ft3Oe--MG5VGPvpvCuzNNabl-9ymblTcJTLyumz394HjzfXD_EUzu8ms3g8h4oSTqDKc60lCzSJqEqzCMsgpArpDAc8QKHffRhKqjgnOWd-qHyeUhSlocq0TruifTDa3VXWOGd1Lla2rKVtBUZi60ds_Yi9nw6IdsC6rHT7T1q8jsfxXxbu2NI1erNnpV2IgFPOxHMyEcFljF9un0IR02_gBHnZ</recordid><startdate>200602</startdate><enddate>200602</enddate><creator>Manohar, A.</creator><creator>Ramalingam, K.</creator><creator>Thiruneelakandan, R.</creator><creator>Bocelli, G.</creator><creator>Righi, L.</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>200602</creationdate><title>N-(2-Hydroxyethyl)-N-methyldithiocarbamato Complexes of Nickel(II) with Phosphorus Donor Ligands</title><author>Manohar, A. ; Ramalingam, K. ; Thiruneelakandan, R. ; Bocelli, G. ; Righi, L.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3272-cffeea56e293cbd91a683c0ed16760841008a3c772f7548c47b309b8cdeebbbb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2006</creationdate><topic>1,3‐Bis(diphenylphosphino)propane</topic><topic>3-Bis(diphenylphosphino)propane</topic><topic>Dithiocarbamate</topic><topic>Thioureide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Manohar, A.</creatorcontrib><creatorcontrib>Ramalingam, K.</creatorcontrib><creatorcontrib>Thiruneelakandan, R.</creatorcontrib><creatorcontrib>Bocelli, G.</creatorcontrib><creatorcontrib>Righi, L.</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><jtitle>Zeitschrift für anorganische und allgemeine Chemie (1950)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Manohar, A.</au><au>Ramalingam, K.</au><au>Thiruneelakandan, R.</au><au>Bocelli, G.</au><au>Righi, L.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>N-(2-Hydroxyethyl)-N-methyldithiocarbamato Complexes of Nickel(II) with Phosphorus Donor Ligands</atitle><jtitle>Zeitschrift für anorganische und allgemeine Chemie (1950)</jtitle><addtitle>Z. anorg. allg. Chem</addtitle><date>2006-02</date><risdate>2006</risdate><volume>632</volume><issue>3</issue><spage>461</spage><epage>464</epage><pages>461-464</pages><issn>0044-2313</issn><eissn>1521-3749</eissn><abstract>Planar nickel(II) complexes involving N‐(2‐Hydroxyethyl)‐N‐methyldithiocarbamate, such as [NiX(nmedtc)(PPh3)] (X = Cl, NCS; PPh3 = triphenylphosphine), and [Ni(nmedtc)(P‐P)]ClO4(P‐P = 1,1‐bis(diphenylphosphino)methane(dppm); 1,3‐bis(diphenylphosphino)propane (1,3‐dppp); 1,4‐bis(diphenylphosphino)butane(1,4‐dppb) have been synthesized. The complexes have been characterized by elemental analyses, IR and electronic spectroscopies. The increased νC–N value in all the complexes is due to the mesomeric drift of electrons from the dithiocarbamate ligands to the metal atom. Single crystal X‐ray structure of [Ni(nmedtc)(1,3‐dppp)]ClO4·H2O is reported. In the present 1,3‐dppp chelate, the P–Ni–P angle is higher than that found in 1,2‐bis(diphenylphosphino)ethane‐nickel chelates and lower than 1,4‐bis(diphenylphosphino)butane‐nickel chelates, as a result of presence of the flexible propyl back bone connecting the two phosphorus atoms of the complex.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/zaac.200500282</doi><tpages>4</tpages></addata></record> |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | 1,3‐Bis(diphenylphosphino)propane 3-Bis(diphenylphosphino)propane Dithiocarbamate Thioureide |
| title | N-(2-Hydroxyethyl)-N-methyldithiocarbamato Complexes of Nickel(II) with Phosphorus Donor Ligands |
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