New Prophosphatranes: Novel intermediates to five-coordinate phosphatranes
The reaction of N(CH2CH2NHMe)3 with P(NMe2)3 or P(NMe2)2Cl yields the phosphatrane precursor N(CH2CH2NMe)2P,4. With oxydizing agents or electrophiles 4 is converted to the untransannulated four‐coordinated derivatives N(CH2CH2NMe)3PX, (X: O, S, Se, N3Ph, NPh, I CS2, 1/2 PtCl2). The structures of th...
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| Veröffentlicht in: | Zeitschrift für anorganische und allgemeine Chemie (1950) 1989, Vol.578 (1), p.75-80 |
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| container_title | Zeitschrift für anorganische und allgemeine Chemie (1950) |
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| creator | Schmidt, H. Lensink, C. Xi, S. K. Verkade, J. G. |
| description | The reaction of N(CH2CH2NHMe)3 with P(NMe2)3 or P(NMe2)2Cl yields the phosphatrane precursor N(CH2CH2NMe)2P,4. With oxydizing agents or electrophiles 4 is converted to the untransannulated four‐coordinated derivatives N(CH2CH2NMe)3PX, (X: O, S, Se, N3Ph, NPh, I CS2, 1/2 PtCl2). The structures of the compounds described are discussed by 1H, 13C, and 31P n.m.r. data.
Neue Prophosphatrane: Neuartige Zwischenstufen auf dem Wege zu pentakoordinierten Phosphatranen
Die Reaktion von N(CH2CH2NHMe)3 mit P(NMe2)3 oder P(NMe2)2Cl ergibt die Phosphatranvorstufe N(CH2CH2NMe)3P. Dessen Umsetzung mit Oxydationsmitteln ode Elektrophilen führt zu nicht‐transannular‐stabilisierten, tetrakoordinierten Derivaten N(CH2CH2NMe)3PX, (X: O, S, Se, N3Ph, NPh, CS2, 1/2 PtCl2). Die Strukturen der beschriebenen Verbindungen werden anhand ihrer 1H‐, 13C‐ und 31P‐NMR‐Daten diskutiert. |
| doi_str_mv | 10.1002/zaac.19895780109 |
| format | Article |
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Neue Prophosphatrane: Neuartige Zwischenstufen auf dem Wege zu pentakoordinierten Phosphatranen
Die Reaktion von N(CH2CH2NHMe)3 mit P(NMe2)3 oder P(NMe2)2Cl ergibt die Phosphatranvorstufe N(CH2CH2NMe)3P. Dessen Umsetzung mit Oxydationsmitteln ode Elektrophilen führt zu nicht‐transannular‐stabilisierten, tetrakoordinierten Derivaten N(CH2CH2NMe)3PX, (X: O, S, Se, N3Ph, NPh, CS2, 1/2 PtCl2). Die Strukturen der beschriebenen Verbindungen werden anhand ihrer 1H‐, 13C‐ und 31P‐NMR‐Daten diskutiert.</description><identifier>ISSN: 0044-2313</identifier><identifier>EISSN: 1521-3749</identifier><identifier>DOI: 10.1002/zaac.19895780109</identifier><identifier>CODEN: ZAACAB</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Chemistry ; Exact sciences and technology ; Organic chemistry ; Organometalloidal and organometallic compounds ; P derivatives ; Preparations and properties</subject><ispartof>Zeitschrift für anorganische und allgemeine Chemie (1950), 1989, Vol.578 (1), p.75-80</ispartof><rights>Copyright © 1989 Verlag GmbH & Co. KGaA, Weinheim</rights><rights>1990 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2799-16b5649318c9c9f7f8ea1cbb5d2466b499b314f14f7b7f9eeb85303971daeec33</citedby><cites>FETCH-LOGICAL-c2799-16b5649318c9c9f7f8ea1cbb5d2466b499b314f14f7b7f9eeb85303971daeec33</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fzaac.19895780109$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fzaac.19895780109$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,4010,27900,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=6813214$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Schmidt, H.</creatorcontrib><creatorcontrib>Lensink, C.</creatorcontrib><creatorcontrib>Xi, S. K.</creatorcontrib><creatorcontrib>Verkade, J. G.</creatorcontrib><title>New Prophosphatranes: Novel intermediates to five-coordinate phosphatranes</title><title>Zeitschrift für anorganische und allgemeine Chemie (1950)</title><addtitle>Z. anorg. allg. Chem</addtitle><description>The reaction of N(CH2CH2NHMe)3 with P(NMe2)3 or P(NMe2)2Cl yields the phosphatrane precursor N(CH2CH2NMe)2P,4. With oxydizing agents or electrophiles 4 is converted to the untransannulated four‐coordinated derivatives N(CH2CH2NMe)3PX, (X: O, S, Se, N3Ph, NPh, I CS2, 1/2 PtCl2). The structures of the compounds described are discussed by 1H, 13C, and 31P n.m.r. data.
Neue Prophosphatrane: Neuartige Zwischenstufen auf dem Wege zu pentakoordinierten Phosphatranen
Die Reaktion von N(CH2CH2NHMe)3 mit P(NMe2)3 oder P(NMe2)2Cl ergibt die Phosphatranvorstufe N(CH2CH2NMe)3P. Dessen Umsetzung mit Oxydationsmitteln ode Elektrophilen führt zu nicht‐transannular‐stabilisierten, tetrakoordinierten Derivaten N(CH2CH2NMe)3PX, (X: O, S, Se, N3Ph, NPh, CS2, 1/2 PtCl2). Die Strukturen der beschriebenen Verbindungen werden anhand ihrer 1H‐, 13C‐ und 31P‐NMR‐Daten diskutiert.</description><subject>Chemistry</subject><subject>Exact sciences and technology</subject><subject>Organic chemistry</subject><subject>Organometalloidal and organometallic compounds</subject><subject>P derivatives</subject><subject>Preparations and properties</subject><issn>0044-2313</issn><issn>1521-3749</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1989</creationdate><recordtype>article</recordtype><recordid>eNqFkMFLwzAUxoMoOKd3jz147UyapGkED2O46RhVUBG8hDR9YdFuHUnZnH-9HZXhTsKDB4_v972PD6FLggcE4-T6W2szIDKTXGSYYHmEeoQnJKaCyWPUw5ixOKGEnqKzED4wbjWc99A0h0305OvVvA6ruW68XkK4ifJ6DVXklg34BZRONxCipo6sW0Ns6tqXbtneogPqHJ1YXQW4-N199Dq-exndx7PHycNoOItNIqSMSVrwlElKMiONtMJmoIkpCl4mLE0LJmVBCbPtiEJYCVBknGIqBSk1gKG0j3Dna3wdggerVt4ttN8qgtWuC7XrQv3pokWuOmSlg9GVbfMaF_ZcmhGaENbKbjvZxlWw_ddWvQ-Ho8M3cce70MDXntf-U6WCCq7e8omaJvn4eYpTNaM_OzqBlw</recordid><startdate>1989</startdate><enddate>1989</enddate><creator>Schmidt, H.</creator><creator>Lensink, C.</creator><creator>Xi, S. K.</creator><creator>Verkade, J. G.</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley-VCH</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>1989</creationdate><title>New Prophosphatranes: Novel intermediates to five-coordinate phosphatranes</title><author>Schmidt, H. ; Lensink, C. ; Xi, S. K. ; Verkade, J. G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2799-16b5649318c9c9f7f8ea1cbb5d2466b499b314f14f7b7f9eeb85303971daeec33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1989</creationdate><topic>Chemistry</topic><topic>Exact sciences and technology</topic><topic>Organic chemistry</topic><topic>Organometalloidal and organometallic compounds</topic><topic>P derivatives</topic><topic>Preparations and properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Schmidt, H.</creatorcontrib><creatorcontrib>Lensink, C.</creatorcontrib><creatorcontrib>Xi, S. K.</creatorcontrib><creatorcontrib>Verkade, J. G.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Zeitschrift für anorganische und allgemeine Chemie (1950)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Schmidt, H.</au><au>Lensink, C.</au><au>Xi, S. K.</au><au>Verkade, J. G.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>New Prophosphatranes: Novel intermediates to five-coordinate phosphatranes</atitle><jtitle>Zeitschrift für anorganische und allgemeine Chemie (1950)</jtitle><addtitle>Z. anorg. allg. Chem</addtitle><date>1989</date><risdate>1989</risdate><volume>578</volume><issue>1</issue><spage>75</spage><epage>80</epage><pages>75-80</pages><issn>0044-2313</issn><eissn>1521-3749</eissn><coden>ZAACAB</coden><abstract>The reaction of N(CH2CH2NHMe)3 with P(NMe2)3 or P(NMe2)2Cl yields the phosphatrane precursor N(CH2CH2NMe)2P,4. With oxydizing agents or electrophiles 4 is converted to the untransannulated four‐coordinated derivatives N(CH2CH2NMe)3PX, (X: O, S, Se, N3Ph, NPh, I CS2, 1/2 PtCl2). The structures of the compounds described are discussed by 1H, 13C, and 31P n.m.r. data.
Neue Prophosphatrane: Neuartige Zwischenstufen auf dem Wege zu pentakoordinierten Phosphatranen
Die Reaktion von N(CH2CH2NHMe)3 mit P(NMe2)3 oder P(NMe2)2Cl ergibt die Phosphatranvorstufe N(CH2CH2NMe)3P. Dessen Umsetzung mit Oxydationsmitteln ode Elektrophilen führt zu nicht‐transannular‐stabilisierten, tetrakoordinierten Derivaten N(CH2CH2NMe)3PX, (X: O, S, Se, N3Ph, NPh, CS2, 1/2 PtCl2). Die Strukturen der beschriebenen Verbindungen werden anhand ihrer 1H‐, 13C‐ und 31P‐NMR‐Daten diskutiert.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/zaac.19895780109</doi><tpages>6</tpages></addata></record> |
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| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Chemistry Exact sciences and technology Organic chemistry Organometalloidal and organometallic compounds P derivatives Preparations and properties |
| title | New Prophosphatranes: Novel intermediates to five-coordinate phosphatranes |
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