Effect of epoxydized carbon nanotube master batch on polypropylene film properties

Effect of epoxydized carbon nanotube master batch on polypropylene film properties

First, the surface of carbon nanotubes (CNTs) was modified by epoxidation reaction to create epoxidized CNTs (O

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Veröffentlicht in:Vietnam journal of chemistry 2021-04, Vol.59 (2), p.263-269
Hauptverfasser: Van Khoi, Nguyen, Thang, Trang Vu, Phuong, Hoang Thi
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carbon nanotubes
master batch
Polypropylene
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container_title Vietnam journal of chemistry
container_volume 59
creator Van Khoi, Nguyen
Thang, Trang Vu
Phuong, Hoang Thi
description First, the surface of carbon nanotubes (CNTs) was modified by epoxidation reaction to create epoxidized CNTs (O
doi_str_mv 10.1002/vjch.202000160
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Following step, master batches of O<CNTs (MB‐O<CNTs) with different O<CNTs contents (5‐12 wt%) were prepared by melt mixing in the presence of anhydride grafted polypropylene (PPgMAH). The CNTs content dispersed uniformly in master batch is 7 wt%. Finally, the effect of MB‐O<CNTs contents on some properties of polypropylene film (PP film) was studied. The PP film samples with different MB‐O<CNTs content (such that the O<CNTs content in the film varies from 0‐1.0 wt%) were prepared on film blowing extruder. The effects of O<CNTs contents on the mechanical, thermal and electrical properties of PP film samples were investigated. The study found that tensile strength of PP films increased significantly with increasing O<CNTs content while elongation at break decreased. In addition, the presence of O<CNTs slightly increased the degree of crystallization and crystallization temperature of PP films while the melting behavior did not change much. From FE‐SEM analysis, the good dispersion of O<CNTs in the PP films was obtained from PP films with O<CNTs content in the range of 0.2‐0.8 wt%. The presence of O<CNTs also changed the electrical properties of PP. The PP films were achieved the antistatic effect at O<CNTs content in the range of 0.2‐0.4 wt%. In addition, the results showed that the master batch processing helps O<CNTs to disperse more evenly in the PP film.]]></description><identifier>ISSN: 0866-7144</identifier><identifier>ISSN: 2572-8288</identifier><identifier>EISSN: 2572-8288</identifier><identifier>DOI: 10.1002/vjch.202000160</identifier><language>eng</language><publisher>Weinheim: WILEY‐VCH Verlag GmbH &amp; Co. KGaA</publisher><subject>carbon nanotubes ; master batch ; Polypropylene</subject><ispartof>Vietnam journal of chemistry, 2021-04, Vol.59 (2), p.263-269</ispartof><rights>2021 Vietnam Academy of Science and Technology, Hanoi &amp; Wiley‐VCH Verlag GmbH &amp; Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c2840-a320f212b8d610d95f46fa37d6780d6700c544d274ffcd32f2a437c70fac1c853</cites><orcidid>0000-0003-1387-5271 ; 0000-0003-1855-6181</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fvjch.202000160$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fvjch.202000160$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1416,27922,27923,45572,45573</link.rule.ids></links><search><creatorcontrib>Van Khoi, Nguyen</creatorcontrib><creatorcontrib>Thang, Trang Vu</creatorcontrib><creatorcontrib>Phuong, Hoang Thi</creatorcontrib><title>Effect of epoxydized carbon nanotube master batch on polypropylene film properties</title><title>Vietnam journal of chemistry</title><description><![CDATA[First, the surface of carbon nanotubes (CNTs) was modified by epoxidation reaction to create epoxidized CNTs (O<CNTs). Following step, master batches of O<CNTs (MB‐O<CNTs) with different O<CNTs contents (5‐12 wt%) were prepared by melt mixing in the presence of anhydride grafted polypropylene (PPgMAH). The CNTs content dispersed uniformly in master batch is 7 wt%. Finally, the effect of MB‐O<CNTs contents on some properties of polypropylene film (PP film) was studied. The PP film samples with different MB‐O<CNTs content (such that the O<CNTs content in the film varies from 0‐1.0 wt%) were prepared on film blowing extruder. The effects of O<CNTs contents on the mechanical, thermal and electrical properties of PP film samples were investigated. The study found that tensile strength of PP films increased significantly with increasing O<CNTs content while elongation at break decreased. In addition, the presence of O<CNTs slightly increased the degree of crystallization and crystallization temperature of PP films while the melting behavior did not change much. From FE‐SEM analysis, the good dispersion of O<CNTs in the PP films was obtained from PP films with O<CNTs content in the range of 0.2‐0.8 wt%. The presence of O<CNTs also changed the electrical properties of PP. The PP films were achieved the antistatic effect at O<CNTs content in the range of 0.2‐0.4 wt%. In addition, the results showed that the master batch processing helps O<CNTs to disperse more evenly in the PP film.]]></description><subject>carbon nanotubes</subject><subject>master batch</subject><subject>Polypropylene</subject><issn>0866-7144</issn><issn>2572-8288</issn><issn>2572-8288</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNqFkMtKw0AUhgdRsNRuXc8LJJ65ZGa6lFCtpSCIug2TudCUNBNm4iU-vQ0VXbo5h8P_f2fxIXRNICcA9OZ9b3Y5BQoARMAZmtFC0kxRpc7RDJQQmSScX6JFSvupowRjQGboaeW9MwMOHrs-fI62-XIWGx3r0OFOd2F4qx0-6DS4iGs9mB0-Bn1oxz6Gfmxd57Bv2gOeTheHxqUrdOF1m9ziZ8_Ry93quVxn28f7h_J2mxmqOGSaUfCU0FpZQcAuC8-F10xaIRUcB4ApOLdUcu-NZdRTzZk0Erw2xKiCzVF--mtiSCk6X_WxOeg4VgSqSUo1Sal-pRyB5Qn4aFo3_tOuXjfl-o_9BpvoZwY</recordid><startdate>202104</startdate><enddate>202104</enddate><creator>Van Khoi, Nguyen</creator><creator>Thang, Trang Vu</creator><creator>Phuong, Hoang Thi</creator><general>WILEY‐VCH Verlag GmbH &amp; Co. 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From FE‐SEM analysis, the good dispersion of O<CNTs in the PP films was obtained from PP films with O<CNTs content in the range of 0.2‐0.8 wt%. The presence of O<CNTs also changed the electrical properties of PP. The PP films were achieved the antistatic effect at O<CNTs content in the range of 0.2‐0.4 wt%. In addition, the results showed that the master batch processing helps O<CNTs to disperse more evenly in the PP film.]]></abstract><cop>Weinheim</cop><pub>WILEY‐VCH Verlag GmbH &amp; Co. KGaA</pub><doi>10.1002/vjch.202000160</doi><tpages>1</tpages><orcidid>https://orcid.org/0000-0003-1387-5271</orcidid><orcidid>https://orcid.org/0000-0003-1855-6181</orcidid><oa>free_for_read</oa></addata></record>
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subjects carbon nanotubes
master batch
Polypropylene
title Effect of epoxydized carbon nanotube master batch on polypropylene film properties
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