Two α-SiO 2 -Related Deep-Ultraviolet Phase-Matchable Optical Nonlinear Beryllium Silicate Crystals Na 2 BeSiO 4 and Li 2 BeSiO 4 with Enhanced SHG Effect

Two α-SiO 2 -Related Deep-Ultraviolet Phase-Matchable Optical Nonlinear Beryllium Silicate Crystals Na 2 BeSiO 4 and Li 2 BeSiO 4 with Enhanced SHG Effect

Deep-UV, (wavelength λ 

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Veröffentlicht in:Small (Weinheim an der Bergstrasse, Germany) Germany), 2024-10, p.e2408360
Hauptverfasser: Chen, Yi-Gang, Jiang, Xingxing, Lv, Hong-Xiao, Mei, Dajiang, Zhang, Xia, Guo, Yao, Lin, Zheshuai, Zhang, Xian-Ming
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container_title Small (Weinheim an der Bergstrasse, Germany)
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creator Chen, Yi-Gang
Jiang, Xingxing
Lv, Hong-Xiao
Mei, Dajiang
Zhang, Xia
Guo, Yao
Lin, Zheshuai
Zhang, Xian-Ming
description Deep-UV, (wavelength λ 
doi_str_mv 10.1002/smll.202408360
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Representative and simple α-SiO is an ideal structural prototype toward improving silicate NLO performance by exploring efficient strategies. Herein, through two-step structural modulations based on fundamental "distortion and superposition" principles of NLO response, two deep-UV NLO crystals taking α-SiO as a structural template, Na BeSiO and Li BeSiO , are synthesized successively. By providing flexible coordination BeO tetrahedra for rigid tetrahedral SiO that induces distortion of SiO , Na BeSiO achieves significant enhancement of phase-matchable SHG effect of 15 × α-SiO . Further, by introducing a low coordination number of Li cations that stimulates uniform orientation of SiO , Li BeSiO exhibits the strongest phase-matchable SHG effect as large as 40 × α-SiO among the universal SiO -governed NLO silicates. Also, computational investigations support the rationality of the structural modulations well. 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Representative and simple α-SiO is an ideal structural prototype toward improving silicate NLO performance by exploring efficient strategies. Herein, through two-step structural modulations based on fundamental "distortion and superposition" principles of NLO response, two deep-UV NLO crystals taking α-SiO as a structural template, Na BeSiO and Li BeSiO , are synthesized successively. By providing flexible coordination BeO tetrahedra for rigid tetrahedral SiO that induces distortion of SiO , Na BeSiO achieves significant enhancement of phase-matchable SHG effect of 15 × α-SiO . Further, by introducing a low coordination number of Li cations that stimulates uniform orientation of SiO , Li BeSiO exhibits the strongest phase-matchable SHG effect as large as 40 × α-SiO among the universal SiO -governed NLO silicates. Also, computational investigations support the rationality of the structural modulations well. 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Representative and simple α-SiO is an ideal structural prototype toward improving silicate NLO performance by exploring efficient strategies. Herein, through two-step structural modulations based on fundamental "distortion and superposition" principles of NLO response, two deep-UV NLO crystals taking α-SiO as a structural template, Na BeSiO and Li BeSiO , are synthesized successively. By providing flexible coordination BeO tetrahedra for rigid tetrahedral SiO that induces distortion of SiO , Na BeSiO achieves significant enhancement of phase-matchable SHG effect of 15 × α-SiO . Further, by introducing a low coordination number of Li cations that stimulates uniform orientation of SiO , Li BeSiO exhibits the strongest phase-matchable SHG effect as large as 40 × α-SiO among the universal SiO -governed NLO silicates. Also, computational investigations support the rationality of the structural modulations well. Such efficient structural modulations can greatly promote the exploration and rational design of NLO silicates.</abstract><cop>Germany</cop><pmid>39468900</pmid><doi>10.1002/smll.202408360</doi><orcidid>https://orcid.org/0000-0002-8809-3402</orcidid></addata></record>
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title Two α-SiO 2 -Related Deep-Ultraviolet Phase-Matchable Optical Nonlinear Beryllium Silicate Crystals Na 2 BeSiO 4 and Li 2 BeSiO 4 with Enhanced SHG Effect
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