Investigations on Tunnel-Structure MnO 2 for Utilization as a High-Voltage and Long-Life Cathode Material in Aqueous Ammonium-Ion and Hybrid-Ion Batteries
Recently, nonmetal NH ions have attracted extensive attention for use as charge carries in the field of energy storage due to their abundant resources, environmental friendliness, and low cost. However, the development of aqueous ammonium-ion batteries (AAIBs) is constrained by the absence of high-v...
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| Veröffentlicht in: | Small (Weinheim an der Bergstrasse, Germany) Germany), 2024-05, Vol.20 (20), p.e2308741 |
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| creator | Liu, Yang Xiang, Kaixiong Zhou, Wei Deng, Weina Zhu, Hai Chen, Han |
| description | Recently, nonmetal NH
ions have attracted extensive attention for use as charge carries in the field of energy storage due to their abundant resources, environmental friendliness, and low cost. However, the development of aqueous ammonium-ion batteries (AAIBs) is constrained by the absence of high-voltage and long-life materials. Herein, different tunnel-structure MnO
materials (α-, β-, and γ-MnO
) are utilized as cathodes for AAIBs and hybrid-ion batteries and compared, and α-MnO
is demonstrated to exhibit the most remarkable electrochemical performance. The α-MnO
cathode material delivers the highest discharge capacity of 219 mAh g
at a current density of 0.1 A g
and the best cyclability with a capacity retention of 95.4% after 10 000 cycles at 1.0 A g
. Moreover, aqueous ammonium-ion and hybrid-ion (ammonium/sodium ions) full batteries are successfully constructed using α-MnO
cathodes. This work provides a novel direction for the development of aqueous energy storage for practical applications. |
| doi_str_mv | 10.1002/smll.202308741 |
| format | Article |
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ions have attracted extensive attention for use as charge carries in the field of energy storage due to their abundant resources, environmental friendliness, and low cost. However, the development of aqueous ammonium-ion batteries (AAIBs) is constrained by the absence of high-voltage and long-life materials. Herein, different tunnel-structure MnO
materials (α-, β-, and γ-MnO
) are utilized as cathodes for AAIBs and hybrid-ion batteries and compared, and α-MnO
is demonstrated to exhibit the most remarkable electrochemical performance. The α-MnO
cathode material delivers the highest discharge capacity of 219 mAh g
at a current density of 0.1 A g
and the best cyclability with a capacity retention of 95.4% after 10 000 cycles at 1.0 A g
. Moreover, aqueous ammonium-ion and hybrid-ion (ammonium/sodium ions) full batteries are successfully constructed using α-MnO
cathodes. This work provides a novel direction for the development of aqueous energy storage for practical applications.</description><identifier>ISSN: 1613-6810</identifier><identifier>EISSN: 1613-6829</identifier><identifier>DOI: 10.1002/smll.202308741</identifier><identifier>PMID: 38112264</identifier><language>eng</language><publisher>Germany</publisher><ispartof>Small (Weinheim an der Bergstrasse, Germany), 2024-05, Vol.20 (20), p.e2308741</ispartof><rights>2023 Wiley‐VCH GmbH.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1074-7f47cfd4ec5c7b525afc90130e227762aaed474e4ad9929aed5aa4286898aa143</citedby><cites>FETCH-LOGICAL-c1074-7f47cfd4ec5c7b525afc90130e227762aaed474e4ad9929aed5aa4286898aa143</cites><orcidid>0000-0002-5812-8774</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/38112264$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Liu, Yang</creatorcontrib><creatorcontrib>Xiang, Kaixiong</creatorcontrib><creatorcontrib>Zhou, Wei</creatorcontrib><creatorcontrib>Deng, Weina</creatorcontrib><creatorcontrib>Zhu, Hai</creatorcontrib><creatorcontrib>Chen, Han</creatorcontrib><title>Investigations on Tunnel-Structure MnO 2 for Utilization as a High-Voltage and Long-Life Cathode Material in Aqueous Ammonium-Ion and Hybrid-Ion Batteries</title><title>Small (Weinheim an der Bergstrasse, Germany)</title><addtitle>Small</addtitle><description>Recently, nonmetal NH
ions have attracted extensive attention for use as charge carries in the field of energy storage due to their abundant resources, environmental friendliness, and low cost. However, the development of aqueous ammonium-ion batteries (AAIBs) is constrained by the absence of high-voltage and long-life materials. Herein, different tunnel-structure MnO
materials (α-, β-, and γ-MnO
) are utilized as cathodes for AAIBs and hybrid-ion batteries and compared, and α-MnO
is demonstrated to exhibit the most remarkable electrochemical performance. The α-MnO
cathode material delivers the highest discharge capacity of 219 mAh g
at a current density of 0.1 A g
and the best cyclability with a capacity retention of 95.4% after 10 000 cycles at 1.0 A g
. Moreover, aqueous ammonium-ion and hybrid-ion (ammonium/sodium ions) full batteries are successfully constructed using α-MnO
cathodes. This work provides a novel direction for the development of aqueous energy storage for practical applications.</description><issn>1613-6810</issn><issn>1613-6829</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNo9kLFOwzAURS0EolBYGZF_IMV2nDgZSwW0UlAHWtboNXFSo8QutoNUPoWvJWmh03tXuucOB6E7SiaUEPbg2qaZMMJCkghOz9AVjWkYxAlLz08_JSN07dwHISFlXFyiUZhQyljMr9DPQn9J51UNXhntsNF41Wktm-DN267wnZX4VS8xw5WxeO1Vo74PVQwOA56rehu8m8ZDLTHoEmdG10GmKoln4Lem7Gnw0iposNJ4-tlJ0zk8bVujVdcGi2Gox-b7jVXlIT6CHwDpbtBFBY2Tt393jNbPT6vZPMiWL4vZNAsKSgQPRMVFUZVcFlEhNhGLoCpSQkMiGRMiZgCy5IJLDmWasrRPEQBnSZykCQDl4RhNjruFNc5ZWeU7q1qw-5ySfJCcD5Lzk-QeuD8Cu27TyvJU_7ca_gKoSHoo</recordid><startdate>202405</startdate><enddate>202405</enddate><creator>Liu, Yang</creator><creator>Xiang, Kaixiong</creator><creator>Zhou, Wei</creator><creator>Deng, Weina</creator><creator>Zhu, Hai</creator><creator>Chen, Han</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-5812-8774</orcidid></search><sort><creationdate>202405</creationdate><title>Investigations on Tunnel-Structure MnO 2 for Utilization as a High-Voltage and Long-Life Cathode Material in Aqueous Ammonium-Ion and Hybrid-Ion Batteries</title><author>Liu, Yang ; Xiang, Kaixiong ; Zhou, Wei ; Deng, Weina ; Zhu, Hai ; Chen, Han</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1074-7f47cfd4ec5c7b525afc90130e227762aaed474e4ad9929aed5aa4286898aa143</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Yang</creatorcontrib><creatorcontrib>Xiang, Kaixiong</creatorcontrib><creatorcontrib>Zhou, Wei</creatorcontrib><creatorcontrib>Deng, Weina</creatorcontrib><creatorcontrib>Zhu, Hai</creatorcontrib><creatorcontrib>Chen, Han</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><jtitle>Small (Weinheim an der Bergstrasse, Germany)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Yang</au><au>Xiang, Kaixiong</au><au>Zhou, Wei</au><au>Deng, Weina</au><au>Zhu, Hai</au><au>Chen, Han</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Investigations on Tunnel-Structure MnO 2 for Utilization as a High-Voltage and Long-Life Cathode Material in Aqueous Ammonium-Ion and Hybrid-Ion Batteries</atitle><jtitle>Small (Weinheim an der Bergstrasse, Germany)</jtitle><addtitle>Small</addtitle><date>2024-05</date><risdate>2024</risdate><volume>20</volume><issue>20</issue><spage>e2308741</spage><pages>e2308741-</pages><issn>1613-6810</issn><eissn>1613-6829</eissn><abstract>Recently, nonmetal NH
ions have attracted extensive attention for use as charge carries in the field of energy storage due to their abundant resources, environmental friendliness, and low cost. However, the development of aqueous ammonium-ion batteries (AAIBs) is constrained by the absence of high-voltage and long-life materials. Herein, different tunnel-structure MnO
materials (α-, β-, and γ-MnO
) are utilized as cathodes for AAIBs and hybrid-ion batteries and compared, and α-MnO
is demonstrated to exhibit the most remarkable electrochemical performance. The α-MnO
cathode material delivers the highest discharge capacity of 219 mAh g
at a current density of 0.1 A g
and the best cyclability with a capacity retention of 95.4% after 10 000 cycles at 1.0 A g
. Moreover, aqueous ammonium-ion and hybrid-ion (ammonium/sodium ions) full batteries are successfully constructed using α-MnO
cathodes. This work provides a novel direction for the development of aqueous energy storage for practical applications.</abstract><cop>Germany</cop><pmid>38112264</pmid><doi>10.1002/smll.202308741</doi><orcidid>https://orcid.org/0000-0002-5812-8774</orcidid></addata></record> |
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| source | Wiley Online Library Journals Frontfile Complete |
| title | Investigations on Tunnel-Structure MnO 2 for Utilization as a High-Voltage and Long-Life Cathode Material in Aqueous Ammonium-Ion and Hybrid-Ion Batteries |
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