Selective Electrochemical Benzylic C(sp3)−H Oxidations in Fluoroalcohols
A site‐selective electrochemical benzylic C(sp3)−H oxidation reaction of aryl alkanes has been reported for synthesis of the desired products. This method significantly expands the scope and enhances the selectivity of aryl aldehydes and fluorinated ethers. Electricity is used as a sustainable oxida...
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| Veröffentlicht in: | ChemistrySelect (Weinheim) 2023-07, Vol.8 (27), p.n/a |
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| creator | Shen, Haiwei Yang, Bo Lin, Jiusheng Zheng, Mingyue Jiang, Hualiang |
| description | A site‐selective electrochemical benzylic C(sp3)−H oxidation reaction of aryl alkanes has been reported for synthesis of the desired products. This method significantly expands the scope and enhances the selectivity of aryl aldehydes and fluorinated ethers. Electricity is used as a sustainable oxidant and promote H2 evolution. This protocol is eco‐friendly and easy to handle as it uses a simple undivided cell in mild conditions without employing any catalyst and oxidant.
An efficient electrochemical benzylic C(sp3)−H oxidation reaction of aryl alkanes has been developed to selectively generate significant aryl aldehydes and fluorinated ethers products using electric current as the oxidant, eliminating the requirement for catalysts or additional oxidizing agents. |
| doi_str_mv | 10.1002/slct.202302073 |
| format | Article |
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An efficient electrochemical benzylic C(sp3)−H oxidation reaction of aryl alkanes has been developed to selectively generate significant aryl aldehydes and fluorinated ethers products using electric current as the oxidant, eliminating the requirement for catalysts or additional oxidizing agents.</description><identifier>ISSN: 2365-6549</identifier><identifier>EISSN: 2365-6549</identifier><identifier>DOI: 10.1002/slct.202302073</identifier><language>eng</language><subject>aryl aldehydes ; C(sp3)−H oxidation ; electrochemical ; fluorinated ethers; eco-friendly</subject><ispartof>ChemistrySelect (Weinheim), 2023-07, Vol.8 (27), p.n/a</ispartof><rights>2023 Wiley‐VCH GmbH</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3293-27794bad61caa840483fb9504769d9a0101dd27818234b18075b585671724d33</citedby><cites>FETCH-LOGICAL-c3293-27794bad61caa840483fb9504769d9a0101dd27818234b18075b585671724d33</cites><orcidid>0009-0006-2971-5802</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fslct.202302073$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fslct.202302073$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Shen, Haiwei</creatorcontrib><creatorcontrib>Yang, Bo</creatorcontrib><creatorcontrib>Lin, Jiusheng</creatorcontrib><creatorcontrib>Zheng, Mingyue</creatorcontrib><creatorcontrib>Jiang, Hualiang</creatorcontrib><title>Selective Electrochemical Benzylic C(sp3)−H Oxidations in Fluoroalcohols</title><title>ChemistrySelect (Weinheim)</title><description>A site‐selective electrochemical benzylic C(sp3)−H oxidation reaction of aryl alkanes has been reported for synthesis of the desired products. This method significantly expands the scope and enhances the selectivity of aryl aldehydes and fluorinated ethers. Electricity is used as a sustainable oxidant and promote H2 evolution. This protocol is eco‐friendly and easy to handle as it uses a simple undivided cell in mild conditions without employing any catalyst and oxidant.
An efficient electrochemical benzylic C(sp3)−H oxidation reaction of aryl alkanes has been developed to selectively generate significant aryl aldehydes and fluorinated ethers products using electric current as the oxidant, eliminating the requirement for catalysts or additional oxidizing agents.</description><subject>aryl aldehydes</subject><subject>C(sp3)−H oxidation</subject><subject>electrochemical</subject><subject>fluorinated ethers; eco-friendly</subject><issn>2365-6549</issn><issn>2365-6549</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNqFkLtOwzAYhS0EElXpypwRhoTfd3uEqKWgSh3aPXIcRzVy6youl_IEzDwiTwJREbAxnTOc7wwfQucYCgxArlKwu4IAoUBA0iM0IFTwXHCmj__0UzRK6QEAsFCCcDlA9wsXnN35J5eN-9JFu3Jrb03IbtzmdR-8zcqLtKWXH2_v02z-4huz83GTMr_JJuExdtEEG1cxpDN00pqQ3Og7h2g5GS_LaT6b396V17PcUqJpTqTUrDaNwNYYxYAp2taaA5NCN9oABtw0RCqsCGU1ViB5zRUXEkvCGkqHqDjc2i6m1Lm22nZ-bbp9haHqXVS9i-rHxRegD8CzD27_z7pazMrlL_sJ1xNilw</recordid><startdate>20230720</startdate><enddate>20230720</enddate><creator>Shen, Haiwei</creator><creator>Yang, Bo</creator><creator>Lin, Jiusheng</creator><creator>Zheng, Mingyue</creator><creator>Jiang, Hualiang</creator><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0009-0006-2971-5802</orcidid></search><sort><creationdate>20230720</creationdate><title>Selective Electrochemical Benzylic C(sp3)−H Oxidations in Fluoroalcohols</title><author>Shen, Haiwei ; Yang, Bo ; Lin, Jiusheng ; Zheng, Mingyue ; Jiang, Hualiang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3293-27794bad61caa840483fb9504769d9a0101dd27818234b18075b585671724d33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>aryl aldehydes</topic><topic>C(sp3)−H oxidation</topic><topic>electrochemical</topic><topic>fluorinated ethers; eco-friendly</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shen, Haiwei</creatorcontrib><creatorcontrib>Yang, Bo</creatorcontrib><creatorcontrib>Lin, Jiusheng</creatorcontrib><creatorcontrib>Zheng, Mingyue</creatorcontrib><creatorcontrib>Jiang, Hualiang</creatorcontrib><collection>CrossRef</collection><jtitle>ChemistrySelect (Weinheim)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shen, Haiwei</au><au>Yang, Bo</au><au>Lin, Jiusheng</au><au>Zheng, Mingyue</au><au>Jiang, Hualiang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Selective Electrochemical Benzylic C(sp3)−H Oxidations in Fluoroalcohols</atitle><jtitle>ChemistrySelect (Weinheim)</jtitle><date>2023-07-20</date><risdate>2023</risdate><volume>8</volume><issue>27</issue><epage>n/a</epage><issn>2365-6549</issn><eissn>2365-6549</eissn><abstract>A site‐selective electrochemical benzylic C(sp3)−H oxidation reaction of aryl alkanes has been reported for synthesis of the desired products. This method significantly expands the scope and enhances the selectivity of aryl aldehydes and fluorinated ethers. Electricity is used as a sustainable oxidant and promote H2 evolution. This protocol is eco‐friendly and easy to handle as it uses a simple undivided cell in mild conditions without employing any catalyst and oxidant.
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| subjects | aryl aldehydes C(sp3)−H oxidation electrochemical fluorinated ethers eco-friendly |
| title | Selective Electrochemical Benzylic C(sp3)−H Oxidations in Fluoroalcohols |
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