Supramolecular Systems as an Alternative for Enzymatic Degradation of 1‐Naphthyl Methylcarbamate (Carbaryl) Pesticide
Reverse micelles (RMs) are considered as versatile nanoreactors because they can create a unique microenvironment, to carry out biochemical and chemical reactions of interest. Thus, in this contribution we propose them to be used as a new approach to hydrolyze a powerful and widely used pesticide: 1...
Gespeichert in:
| Veröffentlicht in: | ChemistrySelect (Weinheim) 2019-06, Vol.4 (24), p.7204-7210 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 7210 |
|---|---|
| container_issue | 24 |
| container_start_page | 7204 |
| container_title | ChemistrySelect (Weinheim) |
| container_volume | 4 |
| creator | Gomez Rodríguez, Esteban I. Falcone, R. Darío Beassoni, Paola R. Moyano, Fernando Correa, N. Mariano |
| description | Reverse micelles (RMs) are considered as versatile nanoreactors because they can create a unique microenvironment, to carry out biochemical and chemical reactions of interest. Thus, in this contribution we propose them to be used as a new approach to hydrolyze a powerful and widely used pesticide: 1‐naphthyl methylcarbamate (Carbaryl), using the enzyme α‐Chymotrypsin (α‐CT) encapsulated in the water pool.
In this contribution we show a novel approach to degrade a powerful pesticide, Carbaryl, using an enzymatic reaction in BHDC reverse micelles media, at different water content. It is observed an increase on the enzymatic catalytic efficiency value for α‐Chymotrypsin in comparison with the one observed in bulk water. |
| doi_str_mv | 10.1002/slct.201901735 |
| format | Article |
| fullrecord | <record><control><sourceid>wiley_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1002_slct_201901735</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>SLCT201901735</sourcerecordid><originalsourceid>FETCH-LOGICAL-c2895-ed6af0829340e6c394f9ecfd7c2f97b78d19e0c87fc83774975c856a31ee9d73</originalsourceid><addsrcrecordid>eNqFkEtLAzEUhYMoWLRb11nqYmqSeSRZlrE-oD6g3Q9p5saOZGZKMrWMK3-Cv9FfYoaKuhMunHPhfJfLQeiMkgklhF16q7sJI1QSyuP0AI1YnKVRliby8I8_RmPvXwghNBMZS_kI7RbbjVN1a0FvrXJ40fsOao9VmAZPbQeuUV31Cti0Ds-at74Oq8ZX8OxUGWzb4NZg-vn-8aA2627dW3wPg2jlViqEAZ_ng3W9vcBP4ANdlXCKjoyyHsbfeoKW17NlfhvNH2_u8uk80kzINIIyU4YIJuOEQKZjmRgJ2pRcMyP5iouSSiBacKNFzHkieapFmqmYAsiSxydosj-rXeu9A1NsXFWHXwpKiqG4Yiiu-CkuAHIP7CoL_T_pYjHPl7_sF-fDdbA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Supramolecular Systems as an Alternative for Enzymatic Degradation of 1‐Naphthyl Methylcarbamate (Carbaryl) Pesticide</title><source>Wiley Online Library All Journals</source><creator>Gomez Rodríguez, Esteban I. ; Falcone, R. Darío ; Beassoni, Paola R. ; Moyano, Fernando ; Correa, N. Mariano</creator><creatorcontrib>Gomez Rodríguez, Esteban I. ; Falcone, R. Darío ; Beassoni, Paola R. ; Moyano, Fernando ; Correa, N. Mariano</creatorcontrib><description>Reverse micelles (RMs) are considered as versatile nanoreactors because they can create a unique microenvironment, to carry out biochemical and chemical reactions of interest. Thus, in this contribution we propose them to be used as a new approach to hydrolyze a powerful and widely used pesticide: 1‐naphthyl methylcarbamate (Carbaryl), using the enzyme α‐Chymotrypsin (α‐CT) encapsulated in the water pool.
In this contribution we show a novel approach to degrade a powerful pesticide, Carbaryl, using an enzymatic reaction in BHDC reverse micelles media, at different water content. It is observed an increase on the enzymatic catalytic efficiency value for α‐Chymotrypsin in comparison with the one observed in bulk water.</description><identifier>ISSN: 2365-6549</identifier><identifier>EISSN: 2365-6549</identifier><identifier>DOI: 10.1002/slct.201901735</identifier><language>eng</language><subject>BHDC ; Carbaryl ; Nanoreactor ; Pesticides ; Reverse Micelles ; α-Chymotrypsin</subject><ispartof>ChemistrySelect (Weinheim), 2019-06, Vol.4 (24), p.7204-7210</ispartof><rights>2019 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2895-ed6af0829340e6c394f9ecfd7c2f97b78d19e0c87fc83774975c856a31ee9d73</citedby><cites>FETCH-LOGICAL-c2895-ed6af0829340e6c394f9ecfd7c2f97b78d19e0c87fc83774975c856a31ee9d73</cites><orcidid>0000-0001-7429-8637</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fslct.201901735$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fslct.201901735$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1416,27923,27924,45573,45574</link.rule.ids></links><search><creatorcontrib>Gomez Rodríguez, Esteban I.</creatorcontrib><creatorcontrib>Falcone, R. Darío</creatorcontrib><creatorcontrib>Beassoni, Paola R.</creatorcontrib><creatorcontrib>Moyano, Fernando</creatorcontrib><creatorcontrib>Correa, N. Mariano</creatorcontrib><title>Supramolecular Systems as an Alternative for Enzymatic Degradation of 1‐Naphthyl Methylcarbamate (Carbaryl) Pesticide</title><title>ChemistrySelect (Weinheim)</title><description>Reverse micelles (RMs) are considered as versatile nanoreactors because they can create a unique microenvironment, to carry out biochemical and chemical reactions of interest. Thus, in this contribution we propose them to be used as a new approach to hydrolyze a powerful and widely used pesticide: 1‐naphthyl methylcarbamate (Carbaryl), using the enzyme α‐Chymotrypsin (α‐CT) encapsulated in the water pool.
In this contribution we show a novel approach to degrade a powerful pesticide, Carbaryl, using an enzymatic reaction in BHDC reverse micelles media, at different water content. It is observed an increase on the enzymatic catalytic efficiency value for α‐Chymotrypsin in comparison with the one observed in bulk water.</description><subject>BHDC</subject><subject>Carbaryl</subject><subject>Nanoreactor</subject><subject>Pesticides</subject><subject>Reverse Micelles</subject><subject>α-Chymotrypsin</subject><issn>2365-6549</issn><issn>2365-6549</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNqFkEtLAzEUhYMoWLRb11nqYmqSeSRZlrE-oD6g3Q9p5saOZGZKMrWMK3-Cv9FfYoaKuhMunHPhfJfLQeiMkgklhF16q7sJI1QSyuP0AI1YnKVRliby8I8_RmPvXwghNBMZS_kI7RbbjVN1a0FvrXJ40fsOao9VmAZPbQeuUV31Cti0Ds-at74Oq8ZX8OxUGWzb4NZg-vn-8aA2627dW3wPg2jlViqEAZ_ng3W9vcBP4ANdlXCKjoyyHsbfeoKW17NlfhvNH2_u8uk80kzINIIyU4YIJuOEQKZjmRgJ2pRcMyP5iouSSiBacKNFzHkieapFmqmYAsiSxydosj-rXeu9A1NsXFWHXwpKiqG4Yiiu-CkuAHIP7CoL_T_pYjHPl7_sF-fDdbA</recordid><startdate>20190628</startdate><enddate>20190628</enddate><creator>Gomez Rodríguez, Esteban I.</creator><creator>Falcone, R. Darío</creator><creator>Beassoni, Paola R.</creator><creator>Moyano, Fernando</creator><creator>Correa, N. Mariano</creator><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0001-7429-8637</orcidid></search><sort><creationdate>20190628</creationdate><title>Supramolecular Systems as an Alternative for Enzymatic Degradation of 1‐Naphthyl Methylcarbamate (Carbaryl) Pesticide</title><author>Gomez Rodríguez, Esteban I. ; Falcone, R. Darío ; Beassoni, Paola R. ; Moyano, Fernando ; Correa, N. Mariano</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2895-ed6af0829340e6c394f9ecfd7c2f97b78d19e0c87fc83774975c856a31ee9d73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>BHDC</topic><topic>Carbaryl</topic><topic>Nanoreactor</topic><topic>Pesticides</topic><topic>Reverse Micelles</topic><topic>α-Chymotrypsin</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gomez Rodríguez, Esteban I.</creatorcontrib><creatorcontrib>Falcone, R. Darío</creatorcontrib><creatorcontrib>Beassoni, Paola R.</creatorcontrib><creatorcontrib>Moyano, Fernando</creatorcontrib><creatorcontrib>Correa, N. Mariano</creatorcontrib><collection>CrossRef</collection><jtitle>ChemistrySelect (Weinheim)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gomez Rodríguez, Esteban I.</au><au>Falcone, R. Darío</au><au>Beassoni, Paola R.</au><au>Moyano, Fernando</au><au>Correa, N. Mariano</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Supramolecular Systems as an Alternative for Enzymatic Degradation of 1‐Naphthyl Methylcarbamate (Carbaryl) Pesticide</atitle><jtitle>ChemistrySelect (Weinheim)</jtitle><date>2019-06-28</date><risdate>2019</risdate><volume>4</volume><issue>24</issue><spage>7204</spage><epage>7210</epage><pages>7204-7210</pages><issn>2365-6549</issn><eissn>2365-6549</eissn><abstract>Reverse micelles (RMs) are considered as versatile nanoreactors because they can create a unique microenvironment, to carry out biochemical and chemical reactions of interest. Thus, in this contribution we propose them to be used as a new approach to hydrolyze a powerful and widely used pesticide: 1‐naphthyl methylcarbamate (Carbaryl), using the enzyme α‐Chymotrypsin (α‐CT) encapsulated in the water pool.
In this contribution we show a novel approach to degrade a powerful pesticide, Carbaryl, using an enzymatic reaction in BHDC reverse micelles media, at different water content. It is observed an increase on the enzymatic catalytic efficiency value for α‐Chymotrypsin in comparison with the one observed in bulk water.</abstract><doi>10.1002/slct.201901735</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0001-7429-8637</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2365-6549 |
| ispartof | ChemistrySelect (Weinheim), 2019-06, Vol.4 (24), p.7204-7210 |
| issn | 2365-6549 2365-6549 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_slct_201901735 |
| source | Wiley Online Library All Journals |
| subjects | BHDC Carbaryl Nanoreactor Pesticides Reverse Micelles α-Chymotrypsin |
| title | Supramolecular Systems as an Alternative for Enzymatic Degradation of 1‐Naphthyl Methylcarbamate (Carbaryl) Pesticide |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-11T23%3A31%3A28IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-wiley_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Supramolecular%20Systems%20as%20an%20Alternative%20for%20Enzymatic%20Degradation%20of%201%E2%80%90Naphthyl%20Methylcarbamate%20(Carbaryl)%20Pesticide&rft.jtitle=ChemistrySelect%20(Weinheim)&rft.au=Gomez%E2%80%85Rodr%C3%ADguez,%20Esteban%20I.&rft.date=2019-06-28&rft.volume=4&rft.issue=24&rft.spage=7204&rft.epage=7210&rft.pages=7204-7210&rft.issn=2365-6549&rft.eissn=2365-6549&rft_id=info:doi/10.1002/slct.201901735&rft_dat=%3Cwiley_cross%3ESLCT201901735%3C/wiley_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |