Electronic Effect on Catalytic Water Oxidation by Single Site [Ru(QCl–tpy)(bpy)(OH2)]2+ Catalyst

The mononuclear [Ru(QCl‐tpy)(bpy)(H2O)](PF6)2 was successfully synthesized and characterized by using several spectroscopic techniques (QCl‐tpy=2‐4′‐(2‐chloroquinolin‐3‐yl)‐2,2′:6′,2′′‐terpyridine). This complex shows only one pKa value at 10.2, due to the deprotonation from the bonded aqua ligand....

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Veröffentlicht in:	ChemistrySelect (Weinheim) 2017-01, Vol.2 (1), p.123-129
Hauptverfasser:	Patel, Jully, Majee, Karunamay, Ahmad, Ejaz, Vatsa, Aditi, Das, Babulal, Padhi, Sumanta Kumar
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Electronic effect Polypyridine ligands Ruthenium Water oxidation
Online-Zugang:	Volltext
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