Asymmetric Transfer Hydrogenation of Cyclic Imines in Water with a Versatile Hydrogen Donor Formic Acid/N‐Methylpiperidine: Rapid Access to Highly Enantioselective Amines

Asymmetric transfer hydrogenation (ATH) of cyclic imines in water has been investigated for the first time by using HCOOH in combination with bases other than triethylamine as H donor. Effect of FA/Base ratio has shown significant impact on activity and enantioselectivity for ATH reaction in water....

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Veröffentlicht in:ChemistrySelect (Weinheim) 2016-07, Vol.1 (10), p.2221-2224
Hauptverfasser: Shende, Vaishali S., Shingote, Savita K., Deshpande, Sudhindra H., Kelkar, Ashutosh. A.
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Sprache:eng
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