Patterned metallizations in perfluorosulphonate membranes by printing methods
Patterned thin film electrodes of platinum and silver have been obtained by printing techniques onto sodium perfluorosulphonate membranes to prepare ionic polymer–metal composite actuators. Metal adhesion has been improved by oxygen plasma activation of perfluorosulphonate. Plasma treatment produces...
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| Veröffentlicht in: | Surface and interface analysis 2012-08, Vol.44 (8), p.1171-1176 |
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| container_title | Surface and interface analysis |
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| creator | Scandurra, Antonino Indelli, Giuseppe Francesco Pignataro, Salvatore |
| description | Patterned thin film electrodes of platinum and silver have been obtained by printing techniques onto sodium perfluorosulphonate membranes to prepare ionic polymer–metal composite actuators. Metal adhesion has been improved by oxygen plasma activation of perfluorosulphonate. Plasma treatment produces oxygen‐containing functional groups at surfaces. Platinum‐patterned electrodes have been obtained by two methods: (i) ink‐jet printing solution of [Pt(NH3)4]++ 2Cl− followed by chemical reduction and (ii) carbon black complementary mask printing followed by platinum complex adsorption and reduction. Silver‐patterned electrodes have been obtained by ink‐jet printing of silver‐based nanoparticles ink sintered at 150 °C, ambient pressure for 1 h. The typical surface resistivity values of patterned electrodes are 5 Ω sq−1 for platinum and 0.5–1 Ω sq−1 for sintered silver, respectively. Perfluorosulphonate with platinum‐ and silver‐patterned electrodes shows electrical stimuli responsivity. Copyright © 2012 John Wiley & Sons, Ltd. |
| doi_str_mv | 10.1002/sia.4851 |
| format | Article |
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Metal adhesion has been improved by oxygen plasma activation of perfluorosulphonate. Plasma treatment produces oxygen‐containing functional groups at surfaces. Platinum‐patterned electrodes have been obtained by two methods: (i) ink‐jet printing solution of [Pt(NH3)4]++ 2Cl− followed by chemical reduction and (ii) carbon black complementary mask printing followed by platinum complex adsorption and reduction. Silver‐patterned electrodes have been obtained by ink‐jet printing of silver‐based nanoparticles ink sintered at 150 °C, ambient pressure for 1 h. The typical surface resistivity values of patterned electrodes are 5 Ω sq−1 for platinum and 0.5–1 Ω sq−1 for sintered silver, respectively. Perfluorosulphonate with platinum‐ and silver‐patterned electrodes shows electrical stimuli responsivity. 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Interface Anal</addtitle><description>Patterned thin film electrodes of platinum and silver have been obtained by printing techniques onto sodium perfluorosulphonate membranes to prepare ionic polymer–metal composite actuators. Metal adhesion has been improved by oxygen plasma activation of perfluorosulphonate. Plasma treatment produces oxygen‐containing functional groups at surfaces. Platinum‐patterned electrodes have been obtained by two methods: (i) ink‐jet printing solution of [Pt(NH3)4]++ 2Cl− followed by chemical reduction and (ii) carbon black complementary mask printing followed by platinum complex adsorption and reduction. Silver‐patterned electrodes have been obtained by ink‐jet printing of silver‐based nanoparticles ink sintered at 150 °C, ambient pressure for 1 h. The typical surface resistivity values of patterned electrodes are 5 Ω sq−1 for platinum and 0.5–1 Ω sq−1 for sintered silver, respectively. Perfluorosulphonate with platinum‐ and silver‐patterned electrodes shows electrical stimuli responsivity. Copyright © 2012 John Wiley & Sons, Ltd.</description><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>Exact sciences and technology</subject><subject>ink-jet printing</subject><subject>ionic polymer-metal composites</subject><subject>nanoparticles</subject><subject>Physics</subject><subject>plastic electronics</subject><subject>XPS</subject><issn>0142-2421</issn><issn>1096-9918</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNp10EtLw0AUBeBBFKxV8CdkI7hJnVcymWWttRbqi1YFN8PNZGJH0yTMpGj99Sa0dOfqbr57OByEzgkeEIzplbcw4ElEDlCPYBmHUpLkEPUw4TSknJJjdOL9J8Y4YUncQ_dP0DTGlSYLVqaBorC_0Niq9IEtg9q4vFhXrvLrol5WJTSmVavUQWl8kG6C2tmyseVH97usMn-KjnIovDnb3T56uR0vRnfh7HEyHQ1noWaCk1CmTGSGSyEw15jjmKUi50ZkEeAokwbiNBWaatARcMli0ARDmlPIARsAyfrocpur227emVy1TVbgNopg1c2g2hlUN0NLL7a0Bq-hyNvu2vq9pwnlEY87F27dty3M5t88NZ8Od7k7b31jfvYe3JeKBRORenuYqOf5_Hpx8zpT7-wPdMB9YQ</recordid><startdate>201208</startdate><enddate>201208</enddate><creator>Scandurra, Antonino</creator><creator>Indelli, Giuseppe Francesco</creator><creator>Pignataro, Salvatore</creator><general>John Wiley & Sons, Ltd</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>201208</creationdate><title>Patterned metallizations in perfluorosulphonate membranes by printing methods</title><author>Scandurra, Antonino ; Indelli, Giuseppe Francesco ; Pignataro, Salvatore</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3741-9b37de497704c04063b7f4e7d5a05d9ea6bb7c2cac5a4936ac10abf2afa0eaa93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Condensed matter: electronic structure, electrical, magnetic, and optical properties</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Cross-disciplinary physics: materials science; rheology</topic><topic>Exact sciences and technology</topic><topic>ink-jet printing</topic><topic>ionic polymer-metal composites</topic><topic>nanoparticles</topic><topic>Physics</topic><topic>plastic electronics</topic><topic>XPS</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Scandurra, Antonino</creatorcontrib><creatorcontrib>Indelli, Giuseppe Francesco</creatorcontrib><creatorcontrib>Pignataro, Salvatore</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Surface and interface analysis</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Scandurra, Antonino</au><au>Indelli, Giuseppe Francesco</au><au>Pignataro, Salvatore</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Patterned metallizations in perfluorosulphonate membranes by printing methods</atitle><jtitle>Surface and interface analysis</jtitle><addtitle>Surf. 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The typical surface resistivity values of patterned electrodes are 5 Ω sq−1 for platinum and 0.5–1 Ω sq−1 for sintered silver, respectively. Perfluorosulphonate with platinum‐ and silver‐patterned electrodes shows electrical stimuli responsivity. Copyright © 2012 John Wiley & Sons, Ltd.</abstract><cop>Chichester, UK</cop><pub>John Wiley & Sons, Ltd</pub><doi>10.1002/sia.4851</doi><tpages>6</tpages></addata></record> |
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| subjects | Condensed matter: electronic structure, electrical, magnetic, and optical properties Condensed matter: structure, mechanical and thermal properties Cross-disciplinary physics: materials science rheology Exact sciences and technology ink-jet printing ionic polymer-metal composites nanoparticles Physics plastic electronics XPS |
| title | Patterned metallizations in perfluorosulphonate membranes by printing methods |
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