Immobilization of gold nanoparticles on poly(methyl methacrylate) electrospun fibers exhibiting solid-state surface plasmon effect

In this study, the surface plasmon effect of Au nanoparticles was successfully realized in the solid state by embedding the Au nanoparticles on the surface of the transparent polymer fibers for the first time. Electrospinning a poly(methyl methacrylate) (PMMA) and HAuCl4 mixture followed by a wet ch...

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Veröffentlicht in:Surface and interface analysis 2012-03, Vol.44 (3), p.318-321
Hauptverfasser: Luong, Nguyen Dang, Oh, Joonsuk, Lee, Youngkwan, Yeon, Ji Hyun, Hur, Jaehuyn, Park, Jong Jin, Kim, Jong Min, Nam, Jae-Do
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container_end_page 321
container_issue 3
container_start_page 318
container_title Surface and interface analysis
container_volume 44
creator Luong, Nguyen Dang
Oh, Joonsuk
Lee, Youngkwan
Yeon, Ji Hyun
Hur, Jaehuyn
Park, Jong Jin
Kim, Jong Min
Nam, Jae-Do
description In this study, the surface plasmon effect of Au nanoparticles was successfully realized in the solid state by embedding the Au nanoparticles on the surface of the transparent polymer fibers for the first time. Electrospinning a poly(methyl methacrylate) (PMMA) and HAuCl4 mixture followed by a wet chemical reduction, the gold nanoparticles were formed on the PMMA nanocomposite electrospun fibers in a well‐distributed manner to give photostable purple color. The Au nanoparticles were all sphere shaped with an average diameter of 12 nm. Specifically, simply adjusting HAuCl4 salt concentration in the electrospinning solution, it is able to control the electrospun fiber diameter and gold nanoparticle content in the resulting PMMA/Au nanocomposite fibers. Therefore, the developed method described herein is simple and effective for the large volume production of PMMA/Au nanocomposite fibers. Copyright © 2011 John Wiley & Sons, Ltd.
doi_str_mv 10.1002/sia.3804
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source Wiley Online Library Journals Frontfile Complete
subjects Clusters, nanoparticles, and nanocrystalline materials
Collective excitations (including excitons, polarons, plasmons and other charge-density excitations)
Collective excitations (including plasmons and other charge-density excitations)
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Condensed matter: structure, mechanical and thermal properties
Electronic structure and electrical properties of surfaces, interfaces, thin films and low-dimensional structures
electrospinning
Exact sciences and technology
gold nanoparticles
Nanoscale materials: clusters, nanoparticles, nanotubes, and nanocrystals
Physics
poly(methyl methacrylate)
Structure of solids and liquids
crystallography
Surface and interface electron states
surface plasmon
title Immobilization of gold nanoparticles on poly(methyl methacrylate) electrospun fibers exhibiting solid-state surface plasmon effect
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