Electronic and Hydrophobic Constants of Azoxy Groups Containing Electron Withdrawing Functions

σ and π constants for azoxy groups containing electron withdrawing functions have been evaluated. The electrical influence of these groups was separated into an induction and a resonance parameter. A new scale of π substituent constants has been derived analysing log P values of phenyldiazenecarboni...

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Veröffentlicht in:Quantitative structure-activity relationships 1988, Vol.7 (1), p.26-30
Hauptverfasser: Calvino, Rosella, Fruttero, Roberta, Garrone, Adele, Gasco, Alberto
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creator Calvino, Rosella
Fruttero, Roberta
Garrone, Adele
Gasco, Alberto
description σ and π constants for azoxy groups containing electron withdrawing functions have been evaluated. The electrical influence of these groups was separated into an induction and a resonance parameter. A new scale of π substituent constants has been derived analysing log P values of phenyldiazenecarbonitrile 2‐oxide derivatives. It is closely parallel with the π scale obtained from the nitrophenyl substituted system.
doi_str_mv 10.1002/qsar.19880070106
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source Wiley Online Library Journals Frontfile Complete
subjects 19F
Azoxy compounds
electronic constants
hydrophobic constants
log P
title Electronic and Hydrophobic Constants of Azoxy Groups Containing Electron Withdrawing Functions
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