The photo‐induced phase transition in Et 2 Me 2 Sb[Pd(dmit) 2 ] 2

The large photo‐induced change of reflectivity has been observed in the unique charge separated phase of the Et 2 Me 2 Sb[Pd(dmit) 2 ] 2 crystal. We observe a clear spectral change due to the disappearance of the charge separated phase by femtosecond photo‐excitation in the [Pd(dmit) 2 ] dimer. The...

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Hauptverfasser: Ishikawa, Tadahiko, Fukazawa, Naoto, Matsubara, Yoshitaka, Nakajima, Ryohei, Onda, Ken, Okimoto, Yoichi, Koshihara, Shin‐ya, Tamura, Masafumi, Kato, Reizo, Lorenc, Maciej, Collet, Eric
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creator Ishikawa, Tadahiko
Fukazawa, Naoto
Matsubara, Yoshitaka
Nakajima, Ryohei
Onda, Ken
Okimoto, Yoichi
Koshihara, Shin‐ya
Tamura, Masafumi
Kato, Reizo
Lorenc, Maciej
Collet, Eric
description The large photo‐induced change of reflectivity has been observed in the unique charge separated phase of the Et 2 Me 2 Sb[Pd(dmit) 2 ] 2 crystal. We observe a clear spectral change due to the disappearance of the charge separated phase by femtosecond photo‐excitation in the [Pd(dmit) 2 ] dimer. The dynamics of the photo‐excited state depends on the excitation intensity. Obtained results strongly suggest that cooperative effect plays a key role in the photo‐excited state of this system. We tentatively classify the observed phenomena as a photo‐induced phase transition due to the melting of the charge separation. (© 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
doi_str_mv 10.1002/pssc.200879835
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title The photo‐induced phase transition in Et 2 Me 2 Sb[Pd(dmit) 2 ] 2
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