Homoepitaxial growth of high-quality nonpolar ZnO films by MOCVD and evaluation of the homoepitaxial ZnO films by XRD measurement for asymmetric planes

Characteristics of homoepitaxial high‐quality nonpolar ZnO (11$ \bar 2 $0) films and a useful measurement method for determining structures of those films are described. Homoepitaxial growth of high‐quality nonpolar ZnO (11$ \bar 2 $0) films could be achieved by atmospheric‐pressure metal organic ch...

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Veröffentlicht in:Physica status solidi. A, Applications and materials science Applications and materials science, 2009-05, Vol.206 (5), p.944-947
Hauptverfasser: Kashiwaba, Yasuhiro, Abe, Takami, Nakagawa, Akira, Endo, Haruyuki, Niikura, Ikuo, Kashiwaba, Yasube
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container_title Physica status solidi. A, Applications and materials science
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creator Kashiwaba, Yasuhiro
Abe, Takami
Nakagawa, Akira
Endo, Haruyuki
Niikura, Ikuo
Kashiwaba, Yasube
description Characteristics of homoepitaxial high‐quality nonpolar ZnO (11$ \bar 2 $0) films and a useful measurement method for determining structures of those films are described. Homoepitaxial growth of high‐quality nonpolar ZnO (11$ \bar 2 $0) films could be achieved by atmospheric‐pressure metal organic chemical vapor deposition using zinc acetylacetonate and oxygen gas. The value of full width at half‐maximum (FWHM) of X‐ray rocking curves (XRCs) of asymmetrical ZnO (20$ \bar 2 $0) and (11$ \bar 2 $2) planes increased with increase in oxygen gas flow rate, and the change in FWHM value corresponded to FWHM of near‐band‐edge emission of photoluminescence spectra. On the other hand, the FWHM value of the XRC of the symmetrical ZnO (11$ \bar 2 $0) plane did not change with change in oxygen gas flow rate, and the FWHM values of all samples were nearly equal to the FWHM value of a single crystal ZnO (11$ \bar 2 $0) substrate. The smallest FWHM values of XRCs of ZnO (11$ \bar 2 $0), (20$ \bar 2 $0) and (11$ \bar 2 $2) planes in the sample grown under the condition of an oxygen gas flow rate of 50 sccm were about 30 arcsec, 35 arcsec and 40 arcsec, respectively. These results indicate that the homoepitaxial ZnO (11$ \bar 2 $0) film has good crystallinity. XRC measurement for asymmetrical planes is useful for evaluating homoepitaxial ZnO (11$ \bar 2 $0) films. (© 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
doi_str_mv 10.1002/pssa.200881305
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(a)</addtitle><date>2009-05</date><risdate>2009</risdate><volume>206</volume><issue>5</issue><spage>944</spage><epage>947</epage><pages>944-947</pages><issn>1862-6300</issn><eissn>1862-6319</eissn><abstract>Characteristics of homoepitaxial high‐quality nonpolar ZnO (11$ \bar 2 $0) films and a useful measurement method for determining structures of those films are described. Homoepitaxial growth of high‐quality nonpolar ZnO (11$ \bar 2 $0) films could be achieved by atmospheric‐pressure metal organic chemical vapor deposition using zinc acetylacetonate and oxygen gas. The value of full width at half‐maximum (FWHM) of X‐ray rocking curves (XRCs) of asymmetrical ZnO (20$ \bar 2 $0) and (11$ \bar 2 $2) planes increased with increase in oxygen gas flow rate, and the change in FWHM value corresponded to FWHM of near‐band‐edge emission of photoluminescence spectra. On the other hand, the FWHM value of the XRC of the symmetrical ZnO (11$ \bar 2 $0) plane did not change with change in oxygen gas flow rate, and the FWHM values of all samples were nearly equal to the FWHM value of a single crystal ZnO (11$ \bar 2 $0) substrate. The smallest FWHM values of XRCs of ZnO (11$ \bar 2 $0), (20$ \bar 2 $0) and (11$ \bar 2 $2) planes in the sample grown under the condition of an oxygen gas flow rate of 50 sccm were about 30 arcsec, 35 arcsec and 40 arcsec, respectively. These results indicate that the homoepitaxial ZnO (11$ \bar 2 $0) film has good crystallinity. XRC measurement for asymmetrical planes is useful for evaluating homoepitaxial ZnO (11$ \bar 2 $0) films. (© 2009 WILEY‐VCH Verlag GmbH &amp; Co. KGaA, Weinheim)</abstract><cop>Berlin</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/pssa.200881305</doi><tpages>4</tpages></addata></record>
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source Wiley Blackwell Journals
subjects 61.05.cp
68.55.J
78.55.Et
81.15.Gh
Chemical vapor deposition (including plasma-enhanced cvd, mocvd, etc.)
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Condensed matter: structure, mechanical and thermal properties
Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
Ii-vi semiconductors
Materials science
Methods of deposition of films and coatings
film growth and epitaxy
Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation
Optical properties of specific thin films
Physics
Structure and morphology
thickness
Surfaces and interfaces
thin films and whiskers (structure and nonelectronic properties)
Thin film structure and morphology
title Homoepitaxial growth of high-quality nonpolar ZnO films by MOCVD and evaluation of the homoepitaxial ZnO films by XRD measurement for asymmetric planes
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