Degradation of Triacetone Triperoxide (TATP) Using Mechanically Alloyed Mg/Pd

A heterogenous catalytic system consisting of mechanically alloyed Mg/Pd particles has been used to degrade the peroxide explosive, triacetone triperoxide (TATP). The degradation of the TATP with the Mg/Pd particles (half life of 1.2×101 min) was compared to the degradation with microscale Mg partic...

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Veröffentlicht in:	Propellants, explosives, pyrotechnics explosives, pyrotechnics, 2010-04, Vol.35 (2), p.100-104
Hauptverfasser:	Fidler Albo, Rebecca L., Legron, Tamra, Gittings, Michael J., Elie, Mark R., Holland Saitta, Erin, Sigman, Michael E., Geiger, Cherie L., Clausen, Christian
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Sprache:	eng
Schlagworte:	Degradation Mg/Pd TATP
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creator	Fidler Albo, Rebecca L. Legron, Tamra Gittings, Michael J. Elie, Mark R. Holland Saitta, Erin Sigman, Michael E. Geiger, Cherie L. Clausen, Christian
description	A heterogenous catalytic system consisting of mechanically alloyed Mg/Pd particles has been used to degrade the peroxide explosive, triacetone triperoxide (TATP). The degradation of the TATP with the Mg/Pd particles (half life of 1.2×101 min) was compared to the degradation with microscale Mg particles (half life of 1.7×103 min) and 10% Pd on activated carbon (half life of 8.7×102 min). Combining the Mg and Pd on carbon (Pd/C) through a mechanical alloying process is shown to produce reactive particles that can be used to degrade TATP. The major product of the degradation of TATP with mechanically alloyed Mg/Pd particles was acetone. A material balance for carbon was also calculated for the degradation reaction with 94±5% (mean±standard deviation) of the TATP carbons accounted for in the production of acetone.
doi_str_mv	10.1002/prep.200900011
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title	Degradation of Triacetone Triperoxide (TATP) Using Mechanically Alloyed Mg/Pd
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