Improved Bonding and Conductivity of Polypyrrole on Polyester by Gaseous Plasma Treatment
A systematic study was conducted using argon, oxygen, and nitrogen plasma to improve the adhesion of polypyrrole coating to polyester (PET) fabric for improving conductivity and to understand the mechanisms involved. PET thin film was used as a reference sample. The changes in wettability, surface c...
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| Veröffentlicht in: | Plasma processes and polymers 2012-10, Vol.9 (10), p.1006-1014 |
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| creator | Mehmood, Tariq Dai, Xiujuan J. Kaynak, Akif Kouzani, Abbas |
| description | A systematic study was conducted using argon, oxygen, and nitrogen plasma to improve the adhesion of polypyrrole coating to polyester (PET) fabric for improving conductivity and to understand the mechanisms involved. PET thin film was used as a reference sample. The changes in wettability, surface chemistry and morphology were studied by water contact angle, X‐ray photoelectron spectroscopy, and atomic force and scanning electron microscopy. It was found that both the highest conductivity and the strongest interfacial bonding were achieved by oxygen plasma treatment. The increase in hydrophilicity, surface functionalization, and suitable nano‐scale roughness gave improved adhesion.
Electrical conductivity and interfacial bonding of polypyrrole coatings on polyester were significantly improved by plasma treatment using Ar, N2 or O2 gases. The highest level of COOH groups and most uniform nano‐scale surface roughness were achieved by O2 plasma treatment that gave the highest interfacial bonding and highest conductivity. After 2000 abrasion cycles the O2 plasma treated sample had lost only ∼7% conductivity while the control had lost ∼36%. |
| doi_str_mv | 10.1002/ppap.201200046 |
| format | Article |
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Electrical conductivity and interfacial bonding of polypyrrole coatings on polyester were significantly improved by plasma treatment using Ar, N2 or O2 gases. The highest level of COOH groups and most uniform nano‐scale surface roughness were achieved by O2 plasma treatment that gave the highest interfacial bonding and highest conductivity. After 2000 abrasion cycles the O2 plasma treated sample had lost only ∼7% conductivity while the control had lost ∼36%.</description><identifier>ISSN: 1612-8850</identifier><identifier>EISSN: 1612-8869</identifier><identifier>DOI: 10.1002/ppap.201200046</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Applied sciences ; conductive coatings ; Exact sciences and technology ; Fibers and threads ; Forms of application and semi-finished materials ; interfacial bonding ; plasma treatment ; Polymer industry, paints, wood ; polypyrrole ; surface modification ; Technology of polymers</subject><ispartof>Plasma processes and polymers, 2012-10, Vol.9 (10), p.1006-1014</ispartof><rights>Copyright © 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3576-161a267f276913212b1cc7ab47adbe88ddfb7e43876d6848deec46bb3c0f9dab3</citedby><cites>FETCH-LOGICAL-c3576-161a267f276913212b1cc7ab47adbe88ddfb7e43876d6848deec46bb3c0f9dab3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fppap.201200046$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fppap.201200046$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=26507864$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Mehmood, Tariq</creatorcontrib><creatorcontrib>Dai, Xiujuan J.</creatorcontrib><creatorcontrib>Kaynak, Akif</creatorcontrib><creatorcontrib>Kouzani, Abbas</creatorcontrib><title>Improved Bonding and Conductivity of Polypyrrole on Polyester by Gaseous Plasma Treatment</title><title>Plasma processes and polymers</title><addtitle>Plasma Processes Polym</addtitle><description>A systematic study was conducted using argon, oxygen, and nitrogen plasma to improve the adhesion of polypyrrole coating to polyester (PET) fabric for improving conductivity and to understand the mechanisms involved. PET thin film was used as a reference sample. The changes in wettability, surface chemistry and morphology were studied by water contact angle, X‐ray photoelectron spectroscopy, and atomic force and scanning electron microscopy. It was found that both the highest conductivity and the strongest interfacial bonding were achieved by oxygen plasma treatment. The increase in hydrophilicity, surface functionalization, and suitable nano‐scale roughness gave improved adhesion.
Electrical conductivity and interfacial bonding of polypyrrole coatings on polyester were significantly improved by plasma treatment using Ar, N2 or O2 gases. The highest level of COOH groups and most uniform nano‐scale surface roughness were achieved by O2 plasma treatment that gave the highest interfacial bonding and highest conductivity. After 2000 abrasion cycles the O2 plasma treated sample had lost only ∼7% conductivity while the control had lost ∼36%.</description><subject>Applied sciences</subject><subject>conductive coatings</subject><subject>Exact sciences and technology</subject><subject>Fibers and threads</subject><subject>Forms of application and semi-finished materials</subject><subject>interfacial bonding</subject><subject>plasma treatment</subject><subject>Polymer industry, paints, wood</subject><subject>polypyrrole</subject><subject>surface modification</subject><subject>Technology of polymers</subject><issn>1612-8850</issn><issn>1612-8869</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNqFkEtPwzAQhC0EEqVw5ewLxxQ_Ets5lgpKpQoiUag4WY7toEBestNC_j0pQRE3TjsrzTe7GgAuMZphhMh106hmRhAmCKGQHYEJZpgEQrD4eNQROgVn3r8jRFEk0AS8rsrG1Xtr4E1dmbx6g6oycNHrnW7zfd52sM5gUhdd0zlXFxbW1c9qfWsdTDu4VN7WOw-TQvlSwY2zqi1t1Z6Dk0wV3l78zil4vrvdLO6D9eNytZivA00jzoL-MUUYzwhnMaYEkxRrzVUacmVSK4QxWcptSAVnholQGGt1yNKUapTFRqV0CmZDrna1985msnF5qVwnMZKHYuShGDkW0wNXA9Aor1WROVXp3I8UYRHigoW9Lx58n3lhu39SZZLMk783goHN-5q-Rla5D8k45ZHcPizly-JpS9dYSEK_AcZDhW4</recordid><startdate>201210</startdate><enddate>201210</enddate><creator>Mehmood, Tariq</creator><creator>Dai, Xiujuan J.</creator><creator>Kaynak, Akif</creator><creator>Kouzani, Abbas</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley-VCH</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>201210</creationdate><title>Improved Bonding and Conductivity of Polypyrrole on Polyester by Gaseous Plasma Treatment</title><author>Mehmood, Tariq ; Dai, Xiujuan J. ; Kaynak, Akif ; Kouzani, Abbas</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3576-161a267f276913212b1cc7ab47adbe88ddfb7e43876d6848deec46bb3c0f9dab3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Applied sciences</topic><topic>conductive coatings</topic><topic>Exact sciences and technology</topic><topic>Fibers and threads</topic><topic>Forms of application and semi-finished materials</topic><topic>interfacial bonding</topic><topic>plasma treatment</topic><topic>Polymer industry, paints, wood</topic><topic>polypyrrole</topic><topic>surface modification</topic><topic>Technology of polymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mehmood, Tariq</creatorcontrib><creatorcontrib>Dai, Xiujuan J.</creatorcontrib><creatorcontrib>Kaynak, Akif</creatorcontrib><creatorcontrib>Kouzani, Abbas</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Plasma processes and polymers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mehmood, Tariq</au><au>Dai, Xiujuan J.</au><au>Kaynak, Akif</au><au>Kouzani, Abbas</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Improved Bonding and Conductivity of Polypyrrole on Polyester by Gaseous Plasma Treatment</atitle><jtitle>Plasma processes and polymers</jtitle><addtitle>Plasma Processes Polym</addtitle><date>2012-10</date><risdate>2012</risdate><volume>9</volume><issue>10</issue><spage>1006</spage><epage>1014</epage><pages>1006-1014</pages><issn>1612-8850</issn><eissn>1612-8869</eissn><abstract>A systematic study was conducted using argon, oxygen, and nitrogen plasma to improve the adhesion of polypyrrole coating to polyester (PET) fabric for improving conductivity and to understand the mechanisms involved. PET thin film was used as a reference sample. The changes in wettability, surface chemistry and morphology were studied by water contact angle, X‐ray photoelectron spectroscopy, and atomic force and scanning electron microscopy. It was found that both the highest conductivity and the strongest interfacial bonding were achieved by oxygen plasma treatment. The increase in hydrophilicity, surface functionalization, and suitable nano‐scale roughness gave improved adhesion.
Electrical conductivity and interfacial bonding of polypyrrole coatings on polyester were significantly improved by plasma treatment using Ar, N2 or O2 gases. The highest level of COOH groups and most uniform nano‐scale surface roughness were achieved by O2 plasma treatment that gave the highest interfacial bonding and highest conductivity. After 2000 abrasion cycles the O2 plasma treated sample had lost only ∼7% conductivity while the control had lost ∼36%.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/ppap.201200046</doi><tpages>9</tpages></addata></record> |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Applied sciences conductive coatings Exact sciences and technology Fibers and threads Forms of application and semi-finished materials interfacial bonding plasma treatment Polymer industry, paints, wood polypyrrole surface modification Technology of polymers |
| title | Improved Bonding and Conductivity of Polypyrrole on Polyester by Gaseous Plasma Treatment |
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