Polypropylene/montmorillonite nanocomposites toughened with SEBS-g-MA: Structure-property relationship
Polypropylene (PP)/organo‐montmorillonite (Org‐MMT) nanocomposites toughened with maleated styrene‐ethylene‐butylene‐styrene (SEBS‐g‐MA) were prepared via melt compounding. The structure, mechanical properties, and dynamic mechanical properties of PP/SEBS‐g‐MA blends and their nanocomposites were in...
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Veröffentlicht in: | Journal of polymer science. Part B, Polymer physics Polymer physics, 2005-11, Vol.43 (21), p.3112-3126 |
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description | Polypropylene (PP)/organo‐montmorillonite (Org‐MMT) nanocomposites toughened with maleated styrene‐ethylene‐butylene‐styrene (SEBS‐g‐MA) were prepared via melt compounding. The structure, mechanical properties, and dynamic mechanical properties of PP/SEBS‐g‐MA blends and their nanocomposites were investigated by X‐ray diffraction (XRD), polarizing optical microscopy (POM), tensile, and impact tests. XRD traces showed that Org‐MMT promoted the formation of β‐phase PP. The degree of crystallinity of PP/SEBS‐g‐MA blends and their nanocomposites were determined from the wide angle X‐ray diffraction via profile fitting method. POM experiments revealed that Org‐MMT particles served as nucleating sites, resulting in a decrease of the spherulite size. The essential work of fracture approach was used to evaluate the tensile fracture toughness of the nanocomposites toughened with elastomer. © 2005 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 43: 3112–3126, 2005 |
doi_str_mv | 10.1002/polb.20596 |
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C. ; Bao, S. P. ; Liang, G. D.</creator><creatorcontrib>Tjong, S. C. ; Bao, S. P. ; Liang, G. D.</creatorcontrib><description>Polypropylene (PP)/organo‐montmorillonite (Org‐MMT) nanocomposites toughened with maleated styrene‐ethylene‐butylene‐styrene (SEBS‐g‐MA) were prepared via melt compounding. The structure, mechanical properties, and dynamic mechanical properties of PP/SEBS‐g‐MA blends and their nanocomposites were investigated by X‐ray diffraction (XRD), polarizing optical microscopy (POM), tensile, and impact tests. XRD traces showed that Org‐MMT promoted the formation of β‐phase PP. The degree of crystallinity of PP/SEBS‐g‐MA blends and their nanocomposites were determined from the wide angle X‐ray diffraction via profile fitting method. POM experiments revealed that Org‐MMT particles served as nucleating sites, resulting in a decrease of the spherulite size. 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C.</creatorcontrib><creatorcontrib>Bao, S. P.</creatorcontrib><creatorcontrib>Liang, G. D.</creatorcontrib><title>Polypropylene/montmorillonite nanocomposites toughened with SEBS-g-MA: Structure-property relationship</title><title>Journal of polymer science. Part B, Polymer physics</title><addtitle>J. Polym. Sci. B Polym. Phys</addtitle><description>Polypropylene (PP)/organo‐montmorillonite (Org‐MMT) nanocomposites toughened with maleated styrene‐ethylene‐butylene‐styrene (SEBS‐g‐MA) were prepared via melt compounding. The structure, mechanical properties, and dynamic mechanical properties of PP/SEBS‐g‐MA blends and their nanocomposites were investigated by X‐ray diffraction (XRD), polarizing optical microscopy (POM), tensile, and impact tests. XRD traces showed that Org‐MMT promoted the formation of β‐phase PP. The degree of crystallinity of PP/SEBS‐g‐MA blends and their nanocomposites were determined from the wide angle X‐ray diffraction via profile fitting method. POM experiments revealed that Org‐MMT particles served as nucleating sites, resulting in a decrease of the spherulite size. The essential work of fracture approach was used to evaluate the tensile fracture toughness of the nanocomposites toughened with elastomer. © 2005 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 43: 3112–3126, 2005</description><subject>Applied sciences</subject><subject>Composites</subject><subject>crystallinity</subject><subject>essential work of fracture</subject><subject>Exact sciences and technology</subject><subject>Forms of application and semi-finished materials</subject><subject>montmorillonite</subject><subject>nanocomposites</subject><subject>Polymer industry, paints, wood</subject><subject>polypropylene</subject><subject>Technology of polymers</subject><issn>0887-6266</issn><issn>1099-0488</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><recordid>eNp9kMtO6zAURS10kegFJnxBJkyQDMeOYyfMAPUCorxUEBITyzgONbhxZLvi5u9JKY8Zo6Ots_YabIR2COwTAHrQefe0T6Go-BoaEagqDKws_6ARlKXAnHK-gf7G-AIw_IpqhJob7_ou-K53pjUHc9-muQ_WOd_aZLJWtV77eefjkGKW_OJ5NnB19mbTLJuOj6f4GV8eHWbTFBY6LYLBS5kJqc-CcSpZ38aZ7bbQeqNcNNufdxPd_xvfnZzhyfXp-cnRBOucEY4pkIaLStCKaFGXjWaaPYGoFGE1LRkUlEPF6hw0cK4U0aQWXDScMqqg5Hm-ifZWXh18jME0sgt2rkIvCcjlQnK5kPxYaIB3V3CnolauCarVNv40xIAVohw4suLerDP9L0Z5cz05_nLjVcfGZP5_d1R4lVzkopAPV6fylrMJf7zIJcnfAdfAhl0</recordid><startdate>20051101</startdate><enddate>20051101</enddate><creator>Tjong, S. 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D.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3416-201f6797291c7d8fc4c4b079a14d2840526094d30c066aa1c1d767f6242a08633</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>Applied sciences</topic><topic>Composites</topic><topic>crystallinity</topic><topic>essential work of fracture</topic><topic>Exact sciences and technology</topic><topic>Forms of application and semi-finished materials</topic><topic>montmorillonite</topic><topic>nanocomposites</topic><topic>Polymer industry, paints, wood</topic><topic>polypropylene</topic><topic>Technology of polymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Tjong, S. C.</creatorcontrib><creatorcontrib>Bao, S. P.</creatorcontrib><creatorcontrib>Liang, G. D.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Journal of polymer science. Part B, Polymer physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tjong, S. C.</au><au>Bao, S. P.</au><au>Liang, G. D.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Polypropylene/montmorillonite nanocomposites toughened with SEBS-g-MA: Structure-property relationship</atitle><jtitle>Journal of polymer science. Part B, Polymer physics</jtitle><addtitle>J. Polym. Sci. B Polym. Phys</addtitle><date>2005-11-01</date><risdate>2005</risdate><volume>43</volume><issue>21</issue><spage>3112</spage><epage>3126</epage><pages>3112-3126</pages><issn>0887-6266</issn><eissn>1099-0488</eissn><coden>JPLPAY</coden><abstract>Polypropylene (PP)/organo‐montmorillonite (Org‐MMT) nanocomposites toughened with maleated styrene‐ethylene‐butylene‐styrene (SEBS‐g‐MA) were prepared via melt compounding. The structure, mechanical properties, and dynamic mechanical properties of PP/SEBS‐g‐MA blends and their nanocomposites were investigated by X‐ray diffraction (XRD), polarizing optical microscopy (POM), tensile, and impact tests. XRD traces showed that Org‐MMT promoted the formation of β‐phase PP. The degree of crystallinity of PP/SEBS‐g‐MA blends and their nanocomposites were determined from the wide angle X‐ray diffraction via profile fitting method. POM experiments revealed that Org‐MMT particles served as nucleating sites, resulting in a decrease of the spherulite size. The essential work of fracture approach was used to evaluate the tensile fracture toughness of the nanocomposites toughened with elastomer. © 2005 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 43: 3112–3126, 2005</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/polb.20596</doi><tpages>15</tpages></addata></record> |
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subjects | Applied sciences Composites crystallinity essential work of fracture Exact sciences and technology Forms of application and semi-finished materials montmorillonite nanocomposites Polymer industry, paints, wood polypropylene Technology of polymers |
title | Polypropylene/montmorillonite nanocomposites toughened with SEBS-g-MA: Structure-property relationship |
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