About the microstructure of PCVD prepared crystal mats of statistical oligo-vinylidene-fluoride-trifluoroethylene in relation to other fluorinated polymers
The room temperature phase of the physical/chemical vapor‐deposited statistical co‐oligomer VDF/TrFE(70/30) has been characterized by different experimental methods such as small‐angle x‐ray scattering, wide‐angle x‐ray diffraction, size‐exclusion chromatography, infrared absorption and optical refr...
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| Veröffentlicht in: | Journal of polymer science. Part B, Polymer physics Polymer physics, 1995-01, Vol.33 (2), p.237-246 |
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| container_title | Journal of polymer science. Part B, Polymer physics |
| container_volume | 33 |
| creator | Fischer, C. Krüger, J. K. Bohn, K.-P. Vogt, U. Schreiber, J. Jiménez, R. Wolf, D. Legrand, J. F. Alnot, P. Servet, B. |
| description | The room temperature phase of the physical/chemical vapor‐deposited statistical co‐oligomer VDF/TrFE(70/30) has been characterized by different experimental methods such as small‐angle x‐ray scattering, wide‐angle x‐ray diffraction, size‐exclusion chromatography, infrared absorption and optical refractometry. The characterization of the elastic properties was carried out using high‐performance Brillouin spectroscopy in connection with special scattering geometries. The co‐oligomer VDF/TrFE(70/30) was obtained by cracking the parent statistical copolymer and subsequently vapor depositing the shortened chains on highly oriented PTFE substrates (PIA‐technique). The room temperature phase of the resulting oriented waxy crystal mats of VDF/TrFE(70/30) is predominantly ferroelectric. The physical properties are very different to those of similarly PIA‐prepared n‐alkanes, perfluoroalkanes, and blockfluoroalkanes. The microstructure of VDF/TrFE(70/30) is interpreted in terms of partially crystalline nano‐sized structures giving rise to a marked freezing process below room temperature. © 1995 John wiley & Sons, Inc. |
| doi_str_mv | 10.1002/polb.1995.090330208 |
| format | Article |
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K. ; Bohn, K.-P. ; Vogt, U. ; Schreiber, J. ; Jiménez, R. ; Wolf, D. ; Legrand, J. F. ; Alnot, P. ; Servet, B.</creator><creatorcontrib>Fischer, C. ; Krüger, J. K. ; Bohn, K.-P. ; Vogt, U. ; Schreiber, J. ; Jiménez, R. ; Wolf, D. ; Legrand, J. F. ; Alnot, P. ; Servet, B.</creatorcontrib><description>The room temperature phase of the physical/chemical vapor‐deposited statistical co‐oligomer VDF/TrFE(70/30) has been characterized by different experimental methods such as small‐angle x‐ray scattering, wide‐angle x‐ray diffraction, size‐exclusion chromatography, infrared absorption and optical refractometry. The characterization of the elastic properties was carried out using high‐performance Brillouin spectroscopy in connection with special scattering geometries. The co‐oligomer VDF/TrFE(70/30) was obtained by cracking the parent statistical copolymer and subsequently vapor depositing the shortened chains on highly oriented PTFE substrates (PIA‐technique). The room temperature phase of the resulting oriented waxy crystal mats of VDF/TrFE(70/30) is predominantly ferroelectric. The physical properties are very different to those of similarly PIA‐prepared n‐alkanes, perfluoroalkanes, and blockfluoroalkanes. The microstructure of VDF/TrFE(70/30) is interpreted in terms of partially crystalline nano‐sized structures giving rise to a marked freezing process below room temperature. © 1995 John wiley & Sons, Inc.</description><identifier>ISSN: 0887-6266</identifier><identifier>EISSN: 1099-0488</identifier><identifier>DOI: 10.1002/polb.1995.090330208</identifier><identifier>CODEN: JPLPAY</identifier><language>eng</language><publisher>New York: John Wiley & Sons, Inc</publisher><subject>Applied sciences ; Brillouin spectroscopy ; chemical vapor deposition ; Exact sciences and technology ; ferroelectricity ; glass transition ; Organic polymers ; oriented fluoro-oligomers ; Physicochemistry of polymers ; Properties and characterization ; Structure, morphology and analysis ; trifluoroethylene ; vinylidene fluoride ; x-ray diffraction</subject><ispartof>Journal of polymer science. 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K.</creatorcontrib><creatorcontrib>Bohn, K.-P.</creatorcontrib><creatorcontrib>Vogt, U.</creatorcontrib><creatorcontrib>Schreiber, J.</creatorcontrib><creatorcontrib>Jiménez, R.</creatorcontrib><creatorcontrib>Wolf, D.</creatorcontrib><creatorcontrib>Legrand, J. F.</creatorcontrib><creatorcontrib>Alnot, P.</creatorcontrib><creatorcontrib>Servet, B.</creatorcontrib><title>About the microstructure of PCVD prepared crystal mats of statistical oligo-vinylidene-fluoride-trifluoroethylene in relation to other fluorinated polymers</title><title>Journal of polymer science. Part B, Polymer physics</title><addtitle>J. Polym. Sci. B Polym. Phys</addtitle><description>The room temperature phase of the physical/chemical vapor‐deposited statistical co‐oligomer VDF/TrFE(70/30) has been characterized by different experimental methods such as small‐angle x‐ray scattering, wide‐angle x‐ray diffraction, size‐exclusion chromatography, infrared absorption and optical refractometry. The characterization of the elastic properties was carried out using high‐performance Brillouin spectroscopy in connection with special scattering geometries. The co‐oligomer VDF/TrFE(70/30) was obtained by cracking the parent statistical copolymer and subsequently vapor depositing the shortened chains on highly oriented PTFE substrates (PIA‐technique). The room temperature phase of the resulting oriented waxy crystal mats of VDF/TrFE(70/30) is predominantly ferroelectric. The physical properties are very different to those of similarly PIA‐prepared n‐alkanes, perfluoroalkanes, and blockfluoroalkanes. The microstructure of VDF/TrFE(70/30) is interpreted in terms of partially crystalline nano‐sized structures giving rise to a marked freezing process below room temperature. © 1995 John wiley & Sons, Inc.</description><subject>Applied sciences</subject><subject>Brillouin spectroscopy</subject><subject>chemical vapor deposition</subject><subject>Exact sciences and technology</subject><subject>ferroelectricity</subject><subject>glass transition</subject><subject>Organic polymers</subject><subject>oriented fluoro-oligomers</subject><subject>Physicochemistry of polymers</subject><subject>Properties and characterization</subject><subject>Structure, morphology and analysis</subject><subject>trifluoroethylene</subject><subject>vinylidene fluoride</subject><subject>x-ray diffraction</subject><issn>0887-6266</issn><issn>1099-0488</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1995</creationdate><recordtype>article</recordtype><recordid>eNqNUMuOFCEUJUYT29EvcMPCLS0UBQUbk5lWZ0wqM5P43BGKBgeliwrQan2LPzuUZTouXXG555V7AHhO8JZg3LycYhi2REq2xRJTihssHoANwVIi3ArxEGywEB3iDeePwZOcv2FcMSY34Pf5EI8FljsLD96kmEs6mnJMFkYHb3efXsMp2Uknu4cmzbnoAA-65AWtn-Jz8abuYvBfI_rhxzn4vR0tcuEYUx1RSf7PHG25m0OFoB9hsqFq4whLhLFmJ7jyR11qUL1mPtiUn4JHTodsn_19z8DHt28-7K5Qf3P5bnfeI0O5FIhojfXAGomxsNJZwWzD2o7LRu6lMF1LGmpwR9qhdQ1mzlkzsMFqTYdhzwynZ4Cuvsv9OVmnpuQPOs2KYLX0q5Z-1dKvOvVbVS9W1aRzrcAlPRqfT1JKOSN8ob1aaT99sPP_OKvbm_7i3xy0GtSu7a-TgU7fFe9ox9Tn60vVv-f9tfzSqgt6D5aYouc</recordid><startdate>19950130</startdate><enddate>19950130</enddate><creator>Fischer, C.</creator><creator>Krüger, J. 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K.</creatorcontrib><creatorcontrib>Bohn, K.-P.</creatorcontrib><creatorcontrib>Vogt, U.</creatorcontrib><creatorcontrib>Schreiber, J.</creatorcontrib><creatorcontrib>Jiménez, R.</creatorcontrib><creatorcontrib>Wolf, D.</creatorcontrib><creatorcontrib>Legrand, J. F.</creatorcontrib><creatorcontrib>Alnot, P.</creatorcontrib><creatorcontrib>Servet, B.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Journal of polymer science. Part B, Polymer physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Fischer, C.</au><au>Krüger, J. K.</au><au>Bohn, K.-P.</au><au>Vogt, U.</au><au>Schreiber, J.</au><au>Jiménez, R.</au><au>Wolf, D.</au><au>Legrand, J. 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The characterization of the elastic properties was carried out using high‐performance Brillouin spectroscopy in connection with special scattering geometries. The co‐oligomer VDF/TrFE(70/30) was obtained by cracking the parent statistical copolymer and subsequently vapor depositing the shortened chains on highly oriented PTFE substrates (PIA‐technique). The room temperature phase of the resulting oriented waxy crystal mats of VDF/TrFE(70/30) is predominantly ferroelectric. The physical properties are very different to those of similarly PIA‐prepared n‐alkanes, perfluoroalkanes, and blockfluoroalkanes. The microstructure of VDF/TrFE(70/30) is interpreted in terms of partially crystalline nano‐sized structures giving rise to a marked freezing process below room temperature. © 1995 John wiley & Sons, Inc.</abstract><cop>New York</cop><pub>John Wiley & Sons, Inc</pub><doi>10.1002/polb.1995.090330208</doi><tpages>10</tpages></addata></record> |
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| ispartof | Journal of polymer science. Part B, Polymer physics, 1995-01, Vol.33 (2), p.237-246 |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Applied sciences Brillouin spectroscopy chemical vapor deposition Exact sciences and technology ferroelectricity glass transition Organic polymers oriented fluoro-oligomers Physicochemistry of polymers Properties and characterization Structure, morphology and analysis trifluoroethylene vinylidene fluoride x-ray diffraction |
| title | About the microstructure of PCVD prepared crystal mats of statistical oligo-vinylidene-fluoride-trifluoroethylene in relation to other fluorinated polymers |
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