P-V-T properties of alternating poly(ethylene-propylene) liquids
The pressure‐volume‐temperature (P‐V‐T) properties of monodisperse alternating poly(ethylene‐propylene) (hydrogenated polyisoprene) melts of varying molecular weights are measured at 0.1 MPa < P < 200.1 MPa, and 290 K < T < 510 K in a dilatometer‐type apparatus. The Flory‐Orwoll‐Vrij (FO...
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| Veröffentlicht in: | Journal of polymer science. Part B, Polymer physics Polymer physics, 1994-07, Vol.32 (10), p.1791-1798 |
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| container_end_page | 1798 |
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| container_issue | 10 |
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| container_title | Journal of polymer science. Part B, Polymer physics |
| container_volume | 32 |
| creator | Chen, S.-j. Chiew, Y. C. Gardecki, J. A. Nilsen, S. Radosz, M. |
| description | The pressure‐volume‐temperature (P‐V‐T) properties of monodisperse alternating poly(ethylene‐propylene) (hydrogenated polyisoprene) melts of varying molecular weights are measured at 0.1 MPa < P < 200.1 MPa, and 290 K < T < 510 K in a dilatometer‐type apparatus. The Flory‐Orwoll‐Vrij (FOV), Modified Cell Model (MCM), Sanchez‐Lacombe (SL), and the Statistical Associating Fluid Theory (SAFT) equations of state are found to correlate the experimental data with excellent accuracy, except either at low pressures and high temperatures, or at high pressures and low temperatures. On average, MCM and SAFT fit the data slightly better than FOV and SL. The equation‐of‐state parameters are found to be independent of molecular weight, especially for SAFT, as required by the theory. © 1994 John Wiley & Sons, Inc. |
| doi_str_mv | 10.1002/polb.1994.090321012 |
| format | Article |
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C. ; Gardecki, J. A. ; Nilsen, S. ; Radosz, M.</creator><creatorcontrib>Chen, S.-j. ; Chiew, Y. C. ; Gardecki, J. A. ; Nilsen, S. ; Radosz, M.</creatorcontrib><description>The pressure‐volume‐temperature (P‐V‐T) properties of monodisperse alternating poly(ethylene‐propylene) (hydrogenated polyisoprene) melts of varying molecular weights are measured at 0.1 MPa < P < 200.1 MPa, and 290 K < T < 510 K in a dilatometer‐type apparatus. The Flory‐Orwoll‐Vrij (FOV), Modified Cell Model (MCM), Sanchez‐Lacombe (SL), and the Statistical Associating Fluid Theory (SAFT) equations of state are found to correlate the experimental data with excellent accuracy, except either at low pressures and high temperatures, or at high pressures and low temperatures. On average, MCM and SAFT fit the data slightly better than FOV and SL. The equation‐of‐state parameters are found to be independent of molecular weight, especially for SAFT, as required by the theory. © 1994 John Wiley & Sons, Inc.</description><identifier>ISSN: 0887-6266</identifier><identifier>EISSN: 1099-0488</identifier><identifier>DOI: 10.1002/polb.1994.090321012</identifier><identifier>CODEN: JPLPAY</identifier><language>eng</language><publisher>New York: John Wiley & Sons, Inc</publisher><subject>alternating poly(ethylene-propylene) (hydrogenated polyisoprene) melts ; Applied sciences ; density ; equations of state ; Exact sciences and technology ; Flory-Orwoll-Vrij (FOV) ; Modified Cell Model (MCM) ; Organic polymers ; Physicochemistry of polymers ; pressure-volume-temperature (P-V-T) properties ; Properties and characterization ; Sanchez-Lacombe (SL) ; specific volume ; Statistical Associating Fluid Theory (SAFT) ; Thermal and thermodynamic properties</subject><ispartof>Journal of polymer science. Part B, Polymer physics, 1994-07, Vol.32 (10), p.1791-1798</ispartof><rights>Copyright © 1994 John Wiley & Sons, Inc.</rights><rights>1994 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3692-fa2d690999aaf080c9159b596d7b749b94cec3bc2738bbe816c838c9ddba9f283</citedby><cites>FETCH-LOGICAL-c3692-fa2d690999aaf080c9159b596d7b749b94cec3bc2738bbe816c838c9ddba9f283</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fpolb.1994.090321012$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fpolb.1994.090321012$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=4182478$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Chen, S.-j.</creatorcontrib><creatorcontrib>Chiew, Y. C.</creatorcontrib><creatorcontrib>Gardecki, J. A.</creatorcontrib><creatorcontrib>Nilsen, S.</creatorcontrib><creatorcontrib>Radosz, M.</creatorcontrib><title>P-V-T properties of alternating poly(ethylene-propylene) liquids</title><title>Journal of polymer science. Part B, Polymer physics</title><addtitle>J. Polym. Sci. B Polym. Phys</addtitle><description>The pressure‐volume‐temperature (P‐V‐T) properties of monodisperse alternating poly(ethylene‐propylene) (hydrogenated polyisoprene) melts of varying molecular weights are measured at 0.1 MPa < P < 200.1 MPa, and 290 K < T < 510 K in a dilatometer‐type apparatus. The Flory‐Orwoll‐Vrij (FOV), Modified Cell Model (MCM), Sanchez‐Lacombe (SL), and the Statistical Associating Fluid Theory (SAFT) equations of state are found to correlate the experimental data with excellent accuracy, except either at low pressures and high temperatures, or at high pressures and low temperatures. On average, MCM and SAFT fit the data slightly better than FOV and SL. The equation‐of‐state parameters are found to be independent of molecular weight, especially for SAFT, as required by the theory. © 1994 John Wiley & Sons, Inc.</description><subject>alternating poly(ethylene-propylene) (hydrogenated polyisoprene) melts</subject><subject>Applied sciences</subject><subject>density</subject><subject>equations of state</subject><subject>Exact sciences and technology</subject><subject>Flory-Orwoll-Vrij (FOV)</subject><subject>Modified Cell Model (MCM)</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>pressure-volume-temperature (P-V-T) properties</subject><subject>Properties and characterization</subject><subject>Sanchez-Lacombe (SL)</subject><subject>specific volume</subject><subject>Statistical Associating Fluid Theory (SAFT)</subject><subject>Thermal and thermodynamic properties</subject><issn>0887-6266</issn><issn>1099-0488</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1994</creationdate><recordtype>article</recordtype><recordid>eNqNkLtOwzAUhi0EEqXwBCwZGGBw8SXxZUFARVukQjuUy2Y5jgOG0AQ7CPL2JARVjEznSOf_vyN9ABxiNMIIkdOqLNIRljIeIYkowQiTLTDASEqIYiG2wQAJwSEjjO2CvRBeEGpviRyA8yW8h6uo8mVlfe1siMo80kVt_VrXbv0Utejm2NbPTWHXFna5n-0kKtz7h8vCPtjJdRHswe8cgrvJ1Wo8g_PF9Hp8MYeGMklgrknGZPtUap0jgYzEiUwTyTKe8limMjbW0NQQTkWaWoGZEVQYmWWpljkRdAhozzW-DMHbXFXevWnfKIxUJ0F1ElQnQW0ktK2jvlXpYHSRe702LmyqMRYk5h38rI99usI2_yGr5WJ--fcP7AEu1PZrA9D-VTFOeaIebqcKP97MCJ9M1JJ-A4tVfxk</recordid><startdate>19940730</startdate><enddate>19940730</enddate><creator>Chen, S.-j.</creator><creator>Chiew, Y. C.</creator><creator>Gardecki, J. A.</creator><creator>Nilsen, S.</creator><creator>Radosz, M.</creator><general>John Wiley & Sons, Inc</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19940730</creationdate><title>P-V-T properties of alternating poly(ethylene-propylene) liquids</title><author>Chen, S.-j. ; Chiew, Y. C. ; Gardecki, J. A. ; Nilsen, S. ; Radosz, M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3692-fa2d690999aaf080c9159b596d7b749b94cec3bc2738bbe816c838c9ddba9f283</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1994</creationdate><topic>alternating poly(ethylene-propylene) (hydrogenated polyisoprene) melts</topic><topic>Applied sciences</topic><topic>density</topic><topic>equations of state</topic><topic>Exact sciences and technology</topic><topic>Flory-Orwoll-Vrij (FOV)</topic><topic>Modified Cell Model (MCM)</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>pressure-volume-temperature (P-V-T) properties</topic><topic>Properties and characterization</topic><topic>Sanchez-Lacombe (SL)</topic><topic>specific volume</topic><topic>Statistical Associating Fluid Theory (SAFT)</topic><topic>Thermal and thermodynamic properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chen, S.-j.</creatorcontrib><creatorcontrib>Chiew, Y. C.</creatorcontrib><creatorcontrib>Gardecki, J. A.</creatorcontrib><creatorcontrib>Nilsen, S.</creatorcontrib><creatorcontrib>Radosz, M.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Journal of polymer science. Part B, Polymer physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chen, S.-j.</au><au>Chiew, Y. C.</au><au>Gardecki, J. A.</au><au>Nilsen, S.</au><au>Radosz, M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>P-V-T properties of alternating poly(ethylene-propylene) liquids</atitle><jtitle>Journal of polymer science. Part B, Polymer physics</jtitle><addtitle>J. Polym. Sci. B Polym. Phys</addtitle><date>1994-07-30</date><risdate>1994</risdate><volume>32</volume><issue>10</issue><spage>1791</spage><epage>1798</epage><pages>1791-1798</pages><issn>0887-6266</issn><eissn>1099-0488</eissn><coden>JPLPAY</coden><abstract>The pressure‐volume‐temperature (P‐V‐T) properties of monodisperse alternating poly(ethylene‐propylene) (hydrogenated polyisoprene) melts of varying molecular weights are measured at 0.1 MPa < P < 200.1 MPa, and 290 K < T < 510 K in a dilatometer‐type apparatus. The Flory‐Orwoll‐Vrij (FOV), Modified Cell Model (MCM), Sanchez‐Lacombe (SL), and the Statistical Associating Fluid Theory (SAFT) equations of state are found to correlate the experimental data with excellent accuracy, except either at low pressures and high temperatures, or at high pressures and low temperatures. On average, MCM and SAFT fit the data slightly better than FOV and SL. The equation‐of‐state parameters are found to be independent of molecular weight, especially for SAFT, as required by the theory. © 1994 John Wiley & Sons, Inc.</abstract><cop>New York</cop><pub>John Wiley & Sons, Inc</pub><doi>10.1002/polb.1994.090321012</doi><tpages>8</tpages></addata></record> |
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| identifier | ISSN: 0887-6266 |
| ispartof | Journal of polymer science. Part B, Polymer physics, 1994-07, Vol.32 (10), p.1791-1798 |
| issn | 0887-6266 1099-0488 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_polb_1994_090321012 |
| source | Wiley Online Library - AutoHoldings Journals |
| subjects | alternating poly(ethylene-propylene) (hydrogenated polyisoprene) melts Applied sciences density equations of state Exact sciences and technology Flory-Orwoll-Vrij (FOV) Modified Cell Model (MCM) Organic polymers Physicochemistry of polymers pressure-volume-temperature (P-V-T) properties Properties and characterization Sanchez-Lacombe (SL) specific volume Statistical Associating Fluid Theory (SAFT) Thermal and thermodynamic properties |
| title | P-V-T properties of alternating poly(ethylene-propylene) liquids |
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