Transition regions and surface melting in partially crystalline polyethylene: A raman spectroscopic study
Structures of semi crystalline high‐molecular weight polyethylene and their changes with temperature were studied by analysis of Raman spectra. Decomposition of spectra into contributions of an orthorhombic crystalline phase, a meltlike phase, and two kinds of transition regions yields the respectiv...
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| Veröffentlicht in: | Journal of polymer science. Part B, Polymer physics Polymer physics, 1993-01, Vol.31 (1), p.99-105 |
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| container_end_page | 105 |
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| container_issue | 1 |
| container_start_page | 99 |
| container_title | Journal of polymer science. Part B, Polymer physics |
| container_volume | 31 |
| creator | Mutter, R. Stille, W. Strobl, G. |
| description | Structures of semi crystalline high‐molecular weight polyethylene and their changes with temperature were studied by analysis of Raman spectra. Decomposition of spectra into contributions of an orthorhombic crystalline phase, a meltlike phase, and two kinds of transition regions yields the respective mass fractions. The results of temperature dependent measurements is indicative of a largely reversible surface melting process, the transition regions being located at the crystal surfaces. As‐polymerized samples show a large fraction of the intermediate phase. Annealing leads to a reduction of this phase. © 1993 John Wiley & Sons, Inc. |
| doi_str_mv | 10.1002/polb.1993.090310113 |
| format | Article |
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Decomposition of spectra into contributions of an orthorhombic crystalline phase, a meltlike phase, and two kinds of transition regions yields the respective mass fractions. The results of temperature dependent measurements is indicative of a largely reversible surface melting process, the transition regions being located at the crystal surfaces. As‐polymerized samples show a large fraction of the intermediate phase. Annealing leads to a reduction of this phase. © 1993 John Wiley & Sons, Inc.</description><identifier>ISSN: 0887-6266</identifier><identifier>EISSN: 1099-0488</identifier><identifier>DOI: 10.1002/polb.1993.090310113</identifier><identifier>CODEN: JPLPAY</identifier><language>eng</language><publisher>New York: John Wiley & Sons, Inc</publisher><subject>Applied sciences ; Exact sciences and technology ; Organic polymers ; Physicochemistry of polymers ; polyethylene ; polyethylene, semicrystalline HMW ; Properties and characterization ; Raman spectra of semicrystalline polyethylene ; Raman spectra of semicrystalline polyethylene, temperature dependence of ; semicrystalline HMW ; Structure, morphology and analysis ; temperature dependence of</subject><ispartof>Journal of polymer science. 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Part B, Polymer physics</title><addtitle>J. Polym. Sci. B Polym. Phys</addtitle><description>Structures of semi crystalline high‐molecular weight polyethylene and their changes with temperature were studied by analysis of Raman spectra. Decomposition of spectra into contributions of an orthorhombic crystalline phase, a meltlike phase, and two kinds of transition regions yields the respective mass fractions. The results of temperature dependent measurements is indicative of a largely reversible surface melting process, the transition regions being located at the crystal surfaces. As‐polymerized samples show a large fraction of the intermediate phase. Annealing leads to a reduction of this phase. © 1993 John Wiley & Sons, Inc.</description><subject>Applied sciences</subject><subject>Exact sciences and technology</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>polyethylene</subject><subject>polyethylene, semicrystalline HMW</subject><subject>Properties and characterization</subject><subject>Raman spectra of semicrystalline polyethylene</subject><subject>Raman spectra of semicrystalline polyethylene, temperature dependence of</subject><subject>semicrystalline HMW</subject><subject>Structure, morphology and analysis</subject><subject>temperature dependence of</subject><issn>0887-6266</issn><issn>1099-0488</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1993</creationdate><recordtype>article</recordtype><recordid>eNqNkDFPwzAQhS0EEqXwC1g8sKbYcezYDEgtgoKoaIciRstxrsWQppGdCvLvcRVUMTK9k-7ee7oPoUtKRpSQ9LrZVsWIKsVGRBFGCaXsCA0oUSohmZTHaECkzBORCnGKzkL4ICTuuBogt_SmDq512xp7WEcJ2NQlDju_MhbwBqrW1WvsatwY3zpTVR22vgttnFwNOFZ30L53FdRwg8fYm42pcWjAtn4b7LZxFod2V3bn6GRlqgAXvzpErw_3y7vHZDafPt2NZ4nNGGcJN2nOMmFlETXPSqlSbg1TXOSFLSwUoIARAoUsJZRKlpyoXFImhCqkEJYNEetzbewPHla68W5jfKcp0Xtaek9L72npA63ouupdjQnWVKtIxbpwsGaZkorzeHbbn325Crr_JOvFfDb525P0AS608H0IMP5Ti_gv128vU01ni-fJIuU6Yz9CCI6l</recordid><startdate>199301</startdate><enddate>199301</enddate><creator>Mutter, R.</creator><creator>Stille, W.</creator><creator>Strobl, G.</creator><general>John Wiley & Sons, Inc</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>199301</creationdate><title>Transition regions and surface melting in partially crystalline polyethylene: A raman spectroscopic study</title><author>Mutter, R. ; Stille, W. ; Strobl, G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4353-5a27346c8b27374d8925ca39567bcbcebe9e300eb8d8ed98d5097813669b866c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1993</creationdate><topic>Applied sciences</topic><topic>Exact sciences and technology</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>polyethylene</topic><topic>polyethylene, semicrystalline HMW</topic><topic>Properties and characterization</topic><topic>Raman spectra of semicrystalline polyethylene</topic><topic>Raman spectra of semicrystalline polyethylene, temperature dependence of</topic><topic>semicrystalline HMW</topic><topic>Structure, morphology and analysis</topic><topic>temperature dependence of</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mutter, R.</creatorcontrib><creatorcontrib>Stille, W.</creatorcontrib><creatorcontrib>Strobl, G.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Journal of polymer science. 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Decomposition of spectra into contributions of an orthorhombic crystalline phase, a meltlike phase, and two kinds of transition regions yields the respective mass fractions. The results of temperature dependent measurements is indicative of a largely reversible surface melting process, the transition regions being located at the crystal surfaces. As‐polymerized samples show a large fraction of the intermediate phase. Annealing leads to a reduction of this phase. © 1993 John Wiley & Sons, Inc.</abstract><cop>New York</cop><pub>John Wiley & Sons, Inc</pub><doi>10.1002/polb.1993.090310113</doi><tpages>7</tpages></addata></record> |
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| identifier | ISSN: 0887-6266 |
| ispartof | Journal of polymer science. Part B, Polymer physics, 1993-01, Vol.31 (1), p.99-105 |
| issn | 0887-6266 1099-0488 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_polb_1993_090310113 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers polyethylene polyethylene, semicrystalline HMW Properties and characterization Raman spectra of semicrystalline polyethylene Raman spectra of semicrystalline polyethylene, temperature dependence of semicrystalline HMW Structure, morphology and analysis temperature dependence of |
| title | Transition regions and surface melting in partially crystalline polyethylene: A raman spectroscopic study |
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