Modulated-temperature differential scanning calorimetry study of temperature-induced mixing and demixing in poly(vinylmethylether)/water

The heat capacity or reversing heat flow signal from modulated‐temperature differential scanning calorimetry can be used to measure the onset of phase separation in a poly(vinylmethylether)/water mixture, clearly showing the special type III lower critical solution temperature demixing behavior. Cha...

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Veröffentlicht in:	Journal of polymer science. Part B, Polymer physics Polymer physics, 2003-08, Vol.41 (15), p.1824-1836
Hauptverfasser:	Swier, Steven, Van Durme, Kurt, Van Mele, Bruno
Format:	Artikel
Sprache:	eng
Schlagworte:	apparent heat capacity Applied sciences Exact sciences and technology hydrophilic polymer kinetics modulated-temperature differential scanning calorimetry Organic polymers phase-separation Physicochemistry of polymers Properties and characterization Solution and gel properties
Online-Zugang:	Volltext
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