Synthesis, characterization, and field-effect transistor performance of poly[2,6-bis(3-tridecanoxythiophen-2-yl)benzo[1,2-b;4,5-b′]dithiophene]
A new copolymer of benzo[1,2-b:4,5-b′]dithiophene and 3,3′-bis(tridecanoxy)-5,5′-bithiophene was synthesized through Stille copolymerization. The bis-(3-alkoxythiophene) monomer was synthesized through a silver fluoride mediated, palladium-catalyzed cross-coupling, in which bromide functional groups...
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| Veröffentlicht in: | Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 2010-05, Vol.48 (9), p.1973-1978 |
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| Format: | Artikel |
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| container_end_page | 1978 |
|---|---|
| container_issue | 9 |
| container_start_page | 1973 |
| container_title | Journal of polymer science. Part A, Polymer chemistry |
| container_volume | 48 |
| creator | Leenen, Mark A.M Meyer, Tim Cucinotta, Fabio Thiem, Heiko Anselmann, Ralf De Cola, Luisa |
| description | A new copolymer of benzo[1,2-b:4,5-b′]dithiophene and 3,3′-bis(tridecanoxy)-5,5′-bithiophene was synthesized through Stille copolymerization. The bis-(3-alkoxythiophene) monomer was synthesized through a silver fluoride mediated, palladium-catalyzed cross-coupling, in which bromide functional groups were preserved instead of consumed. The copolymer has been characterized and applied in field-effect transistors, giving a hole mobility of 2 x 10⁻³ cm²/Vs and an on/off ratio >10⁶, with negligible hysteresis, on standard silicon substrates. |
| doi_str_mv | 10.1002/pola.23964 |
| format | Article |
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The bis-(3-alkoxythiophene) monomer was synthesized through a silver fluoride mediated, palladium-catalyzed cross-coupling, in which bromide functional groups were preserved instead of consumed. 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Part A, Polymer chemistry</title><addtitle>J. Polym. Sci. A Polym. Chem</addtitle><description>A new copolymer of benzo[1,2-b:4,5-b′]dithiophene and 3,3′-bis(tridecanoxy)-5,5′-bithiophene was synthesized through Stille copolymerization. The bis-(3-alkoxythiophene) monomer was synthesized through a silver fluoride mediated, palladium-catalyzed cross-coupling, in which bromide functional groups were preserved instead of consumed. The copolymer has been characterized and applied in field-effect transistors, giving a hole mobility of 2 x 10⁻³ cm²/Vs and an on/off ratio >10⁶, with negligible hysteresis, on standard silicon substrates.</description><subject>Applied sciences</subject><subject>charge transport</subject><subject>conjugated polymers</subject><subject>copolymerization</subject><subject>Electronics</subject><subject>Exact sciences and technology</subject><subject>field-effect transistors</subject><subject>Organic polymers</subject><subject>photophysics</subject><subject>Physicochemistry of polymers</subject><subject>Polymers with particular properties</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>Semiconductor electronics. Microelectronics. Optoelectronics. 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| ispartof | Journal of polymer science. Part A, Polymer chemistry, 2010-05, Vol.48 (9), p.1973-1978 |
| issn | 0887-624X 1099-0518 |
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| subjects | Applied sciences charge transport conjugated polymers copolymerization Electronics Exact sciences and technology field-effect transistors Organic polymers photophysics Physicochemistry of polymers Polymers with particular properties Preparation, kinetics, thermodynamics, mechanism and catalysts Semiconductor electronics. Microelectronics. Optoelectronics. Solid state devices synthesis Transistors |
| title | Synthesis, characterization, and field-effect transistor performance of poly[2,6-bis(3-tridecanoxythiophen-2-yl)benzo[1,2-b;4,5-b′]dithiophene] |
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