Mechanistic studies of carbonate macrocyclization

The kinetics of phenylchloroformate (PCF) reactions have been used to model some of the key chemical events in carbonate macrocyclization. Three reactions have been studied using stopped‐flow FT‐IR spectroscopy: formation of acyl ammonium salt from PCF and three different trialkylamines, the convers...

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Veröffentlicht in:	Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 1994-03, Vol.32 (4), p.741-746
Hauptverfasser:	Aquino, Eugene C., Brittain, William J., Brunelle, Daniel J.
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences carbonate macrocyclization Exact sciences and technology Organic polymers Physicochemistry of polymers polycarbonate Polycondensation polymerization kinetics polymerization mechanism Preparation, kinetics, thermodynamics, mechanism and catalysts stopped-flow spectroscopy
Online-Zugang:	Volltext
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