The mechanism of butadiene polymerization with the catalytic system NdCl 3 · 3TBP(1C 4 H 9 ) 2 AIH

The polymerization of butadiene with the catalytic system NdCl 3 · 3TBP‐(1C 4 H 9 ) 2 AlH (TBP‐tributyl phosphate) was studied. With regard to the anti‐syn ‐isomerization of both free‐ and monomer‐complexed active centers, the kinetic scheme of the propagation reaction was shown to afford adequate d...

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Veröffentlicht in:Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 1993-09, Vol.31 (10), p.2419-2421
Hauptverfasser: Sabirov, Z. M., Minchenkova, N. Kh, Urazbaev, V. N., Monakov, Yu. B.
Format: Artikel
Sprache:eng
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