Preparation and properties of 1-ethoxy-2,2,2-trifluoroethyl esters of acrylic and methacrylic acids and of their polymers
1‐Ethoxy‐2,2,2‐trifluoroethyl esters of acrylic (I) and methacrylic (II) acids were synthesized from 1‐ethoxy‐2,2,2‐trifluoroethanol and acryloyl‐ and methacryloylchloride, respectively, and their densities, mass, 1H‐ and 13C‐NMR spectra were measured and the rate constants of hydrolysis were determ...
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| Veröffentlicht in: | Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 1988-01, Vol.26 (1), p.267-274 |
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| container_end_page | 274 |
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| container_issue | 1 |
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| container_title | Journal of polymer science. Part A, Polymer chemistry |
| container_volume | 26 |
| creator | Hrabáak, F. Lokaj, J. Bílá, J. Pivcová, H. Tkaczyk, M. Biroš, J. |
| description | 1‐Ethoxy‐2,2,2‐trifluoroethyl esters of acrylic (I) and methacrylic (II) acids were synthesized from 1‐ethoxy‐2,2,2‐trifluoroethanol and acryloyl‐ and methacryloylchloride, respectively, and their densities, mass, 1H‐ and 13C‐NMR spectra were measured and the rate constants of hydrolysis were determined. Poly(I) and poly(II) were prepared by radical homopolymerization; the rates of polymerization, specific volume contractions in polymerization, limiting viscosity numbers, average number degrees of polymerization, temperature dependences of the heat capacities both in glass and liquid state, glass transition temperatures, and the initial temperature of the spontaneous thermal decomposition of homopolymers were determined. The monomer reactivity ratios of the styrene (S) copolymerizations, SI and SII, and the Alfrey–Price copolymerization constants e and Q for I and II were calculated from the composition of copolymers of I and II with styrene. |
| doi_str_mv | 10.1002/pola.1988.080260126 |
| format | Article |
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Poly(I) and poly(II) were prepared by radical homopolymerization; the rates of polymerization, specific volume contractions in polymerization, limiting viscosity numbers, average number degrees of polymerization, temperature dependences of the heat capacities both in glass and liquid state, glass transition temperatures, and the initial temperature of the spontaneous thermal decomposition of homopolymers were determined. The monomer reactivity ratios of the styrene (S) copolymerizations, SI and SII, and the Alfrey–Price copolymerization constants e and Q for I and II were calculated from the composition of copolymers of I and II with styrene.</description><identifier>ISSN: 0887-624X</identifier><identifier>EISSN: 1099-0518</identifier><identifier>DOI: 10.1002/pola.1988.080260126</identifier><identifier>CODEN: JPLCAT</identifier><language>eng</language><publisher>New York: John Wiley & Sons, Inc</publisher><subject>Applied sciences ; Exact sciences and technology ; Organic polymers ; Physicochemistry of polymers ; Polymerization ; Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><ispartof>Journal of polymer science. 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Part A, Polymer chemistry</title><addtitle>J. Polym. Sci. A Polym. Chem</addtitle><description>1‐Ethoxy‐2,2,2‐trifluoroethyl esters of acrylic (I) and methacrylic (II) acids were synthesized from 1‐ethoxy‐2,2,2‐trifluoroethanol and acryloyl‐ and methacryloylchloride, respectively, and their densities, mass, 1H‐ and 13C‐NMR spectra were measured and the rate constants of hydrolysis were determined. Poly(I) and poly(II) were prepared by radical homopolymerization; the rates of polymerization, specific volume contractions in polymerization, limiting viscosity numbers, average number degrees of polymerization, temperature dependences of the heat capacities both in glass and liquid state, glass transition temperatures, and the initial temperature of the spontaneous thermal decomposition of homopolymers were determined. The monomer reactivity ratios of the styrene (S) copolymerizations, SI and SII, and the Alfrey–Price copolymerization constants e and Q for I and II were calculated from the composition of copolymers of I and II with styrene.</description><subject>Applied sciences</subject><subject>Exact sciences and technology</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polymerization</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><issn>0887-624X</issn><issn>1099-0518</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1988</creationdate><recordtype>article</recordtype><recordid>eNqNkD9PwzAQxS0EEqXwCVgyMOJix45jL0gVf1pEoR2AslmO46iGtInsIJpvj9ugiBHdYN3de7-zHgDnGI0wQvFVXZVqhAXnI8RRzBCO2QEYYCQERAnmh2CAOE8hi-n7MTjx_gOhsEv4ALQLZ2rlVGOrTaQ2eVS7qjauscZHVRFhaJpVtW1hfBkKNs4W5VflqjBty8j4xri9TmnXllbvCeuw7Httc7-fBlGzMtZF4a_tOthOwVGhSm_Oft8heL2_e7mZwtl88nAznkFNmGAwFSbNFaVZLDBiWmSMFpziRHCiWYEJTzQxJBMMkTTHLC8QY5miiTYozrTSZAhIx9Wu8t6ZQtbOrpVrJUZyl57cpSd36ck-veC66Fy18lqVhVMbbX1vTRkmVNAgu-5k37Y07X_IcjGfjf_egR3Ahiy3PUC5T8lSkiZy-TyRbwl9mt4-LmVMfgDj4ZNo</recordid><startdate>198801</startdate><enddate>198801</enddate><creator>Hrabáak, F.</creator><creator>Lokaj, J.</creator><creator>Bílá, J.</creator><creator>Pivcová, H.</creator><creator>Tkaczyk, M.</creator><creator>Biroš, J.</creator><general>John Wiley & Sons, Inc</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>198801</creationdate><title>Preparation and properties of 1-ethoxy-2,2,2-trifluoroethyl esters of acrylic and methacrylic acids and of their polymers</title><author>Hrabáak, F. ; Lokaj, J. ; Bílá, J. ; Pivcová, H. ; Tkaczyk, M. ; Biroš, J.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3696-79e7da44b29106c9b64f8415983c6f1385c3e3b96037d16df066ba45ce02bcac3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1988</creationdate><topic>Applied sciences</topic><topic>Exact sciences and technology</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polymerization</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><toplevel>online_resources</toplevel><creatorcontrib>Hrabáak, F.</creatorcontrib><creatorcontrib>Lokaj, J.</creatorcontrib><creatorcontrib>Bílá, J.</creatorcontrib><creatorcontrib>Pivcová, H.</creatorcontrib><creatorcontrib>Tkaczyk, M.</creatorcontrib><creatorcontrib>Biroš, J.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Journal of polymer science. Part A, Polymer chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hrabáak, F.</au><au>Lokaj, J.</au><au>Bílá, J.</au><au>Pivcová, H.</au><au>Tkaczyk, M.</au><au>Biroš, J.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation and properties of 1-ethoxy-2,2,2-trifluoroethyl esters of acrylic and methacrylic acids and of their polymers</atitle><jtitle>Journal of polymer science. Part A, Polymer chemistry</jtitle><addtitle>J. Polym. Sci. A Polym. Chem</addtitle><date>1988-01</date><risdate>1988</risdate><volume>26</volume><issue>1</issue><spage>267</spage><epage>274</epage><pages>267-274</pages><issn>0887-624X</issn><eissn>1099-0518</eissn><coden>JPLCAT</coden><abstract>1‐Ethoxy‐2,2,2‐trifluoroethyl esters of acrylic (I) and methacrylic (II) acids were synthesized from 1‐ethoxy‐2,2,2‐trifluoroethanol and acryloyl‐ and methacryloylchloride, respectively, and their densities, mass, 1H‐ and 13C‐NMR spectra were measured and the rate constants of hydrolysis were determined. Poly(I) and poly(II) were prepared by radical homopolymerization; the rates of polymerization, specific volume contractions in polymerization, limiting viscosity numbers, average number degrees of polymerization, temperature dependences of the heat capacities both in glass and liquid state, glass transition temperatures, and the initial temperature of the spontaneous thermal decomposition of homopolymers were determined. 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| identifier | ISSN: 0887-624X |
| ispartof | Journal of polymer science. Part A, Polymer chemistry, 1988-01, Vol.26 (1), p.267-274 |
| issn | 0887-624X 1099-0518 |
| language | eng |
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| source | Wiley Online Library All Journals |
| subjects | Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts |
| title | Preparation and properties of 1-ethoxy-2,2,2-trifluoroethyl esters of acrylic and methacrylic acids and of their polymers |
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