Synthesis and properties of π-conjugated dithiafulvene oligomers by addition of a monofunctionalized compound

Dithiafulvene oligomers (3) were prepared by cycloaddition polymerization of aldothioketenes with their alkynethiol tautomers derived from 1,4‐diethynylbenzene (2) with the addition of 1‐ethynyl‐4‐methylbenzene (1) as a monofunctionalized compound. Different feed ratios of 2/1were used to control th...

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Veröffentlicht in:	Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 2003-03, Vol.41 (5), p.708-715
Hauptverfasser:	Naka, Kensuke, Gelover-Santiago, Adriana, Uemura, Takashi, Chujo, Yoshiki
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences conjugated polymers degree of polymerization (DP) Exact sciences and technology heteroatom-containing polymers oligomers Organic polymers Physicochemistry of polymers Polymers with particular properties Preparation, kinetics, thermodynamics, mechanism and catalysts redox polymers
Online-Zugang:	Volltext
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